Investigation of the power generation performance of a stack by reverse electrodialysis and its influencing factors
Abstract This paper presents an experimental study on the performance of a RED stack for SELEMION, ASTOM and FUJI membranes with the cell pair number from 3 to 15 and flow rate from 5 to 60 L/h over a wide solution concentration range from 1 to 120 g/L. DC and AC measurements are employed to identify quantatively the contribution of ohmic and non-ohmic resistances to the stack resistance and then, the power output is predicted theoretically. The results show that the ohmic resistance dominates in the stack resistance and accounts for about 90%. The factors such as the membrane type, cell pair, solution concentration and flow rate have a considerable impact on power generation process of RED. Especially, simultaneous increasing the HC and LC solution concentrations is more conducive to suppressing the concentration polarization when compared with increasing LC solution concentration alone. Although the concentration polarization maintains declining with the increase in flow rate, the flow rate should not be too large in order to harvest the highest power output by reason of serious tangential flow at higher flow rates. The optimal performance of RED stack is obtained when SELEMION membranes are used with cell pairs of 5, HC-LC solution concentration of 120-4 g/L and feed flow rate of 20 L/h.