Combustion of Flat Shaped Char Particles with Oxygen

2021 ◽  
pp. 1-17
Author(s):  
Henry Molintas ◽  
Ashwani K. Gupta

Abstract Thin flat-shaped carbon black particles of 1.5 mm thickness by 22.5 mm diameter were combusted in pure oxygen at atmospheric pressures and temperatures in the range of 500 to 650 °C. One film kinetic-diffusion model was derived to characterize the kinetic and energy parameters for particles arranged in the form of a thin flat-shaped configuration. The kinetic and energy parameters, and operating regimes of thin flat-shaped char particles were characterized during the non-isothermal combustion process. The gasification regimes during preheating were also analyzed. Steady-state energy processes were considered to derive an energy conservation equation used for calculating the evolution of char surface temperatures as well as released peak energy rates and the specific energy, which are considered key engineering design parameters. The one-film kinetic-diffusion model showed that combustion of such particles was purely kinetic controlled under these conditions. The activation energy obtained varied between 50 to 74 kJ/mol using discrete time and linear fits to the Arrhenius equation. The total energies released per weight of char converted varied between 32.8 and 40.6 kJ/g. The highest peak energy rate released was 134 J/s when combusting char in O2 at a reactor temperature of 504 °C.

2017 ◽  
Vol 16 (1) ◽  
pp. 89
Author(s):  
F. B. Teixeira ◽  
M. S. Pereira ◽  
B. C. Feijó ◽  
L. A. O. Rocha ◽  
L. A. Isoldi ◽  
...  

In this work, the influence of geometry on the behavior of the temperature field in a square plate with T and H-shaped cavities is studied. The ratio between the cavity area and the plate area will be kept constant and its geometry will be varied in order to find the optimum geometry (the one that results in the temperature field with the lowest maximum temperature). The cavity will occupy 10% of the area of the plate and will be varied from the T-shaped configuration to the H-shaped one. According to the Constructal Design principles, the degrees of freedom of the problem and its restrictions will be defined. The height of the initial T was selected as H1, where H1/L1 is one of the degrees of freedom for the problem. The second degree of freedom is the ratio H2/L2, the ratio of height by the width of the first bifurcation, and the other geometric ratio (H3/L3) is the ratio of height by the width of the second bifurcation and is a function of H1. For the simulations, a code based on the Finite Element Method (FEM) was used to solve the energy conservation equation. The results showed that it is possible to minimize the maximum excess temperature by 54.4% when an H-shaped geometry with irregular legs is used compared with the T-shaped cavity. In order to reach the optimum geometry, H1/L1 was reduced by 68.37%, and H2/L2 was increased in 64.71% when compared to the initially proposed T-shaped cavity.


Author(s):  
I. Hischier ◽  
D. Hess ◽  
W. Lipiński ◽  
M. Modest ◽  
A. Steinfeld

A novel design of a high-temperature pressurized solar air receiver for power generation via combined Brayton–Rankine cycles is proposed. It consists of an annular reticulate porous ceramic (RPC) bounded by two concentric cylinders. The inner cylinder, which serves as the solar absorber, has a cavity-type configuration and a small aperture for the access of concentrated solar radiation. Absorbed heat is transferred by conduction, radiation, and convection to the pressurized air flowing across the RPC. A 2D steady-state energy conservation equation coupling the three modes of heat transfer is formulated and solved by the finite volume technique and by applying the Rosseland diffusion, P1, and Monte Carlo radiation methods. Key results include the temperature distribution and thermal efficiency as a function of the geometrical and operational parameters. For a solar concentration ratio of 3000 suns, the outlet air temperature reaches 1000°C at 10 bars, yielding a thermal efficiency of 78%.


2001 ◽  
Vol 431 ◽  
pp. 223-237 ◽  
Author(s):  
WILLI MÖHRING

A sound wave propagating in an inhomogeneous duct consisting of two semi-infinite uniform ducts with a smooth transition region in between and which carries a steady flow is considered. The duct walls may be rigid or compliant. For an irrotational sound wave it is shown that the three properties of the title are closely related, such that the validity of any two implies the validity of the third. Furthermore it is shown that the three properties are fulfilled for lossless locally reacting duct walls provided the impedance varies at most continuously. For piecewise-continuous wall properties edge conditions are essential. By an analytic continuation argument it is shown that reciprocity remains true for walls with loss. For rotational flow, energy conservation theorems have been derived only with the help of additional potential-like variables. The inter-relation between the three properties remains valid if one considers these additional variables to be known. If only the basic gasdynamic variables in both half-ducts are known, one cannot formulate an energy conservation equation; however, reciprocity is fulfilled.


2021 ◽  
Vol 6 ◽  
pp. 35-38
Author(s):  
Rashid Kafiatullin

Oil reservoir pressure maintenance pumps are often pushed to operate significantly outside of their original design parameters. This can cause operating problems which impact their reliability and efficiency. The author offers the evaluation methodology for energy parameters and energy saving potential of oil reservoir pressure maintenance pumps in order to develop major pump parameters like efficiency, pressure, and specific electric power. The methodology was tested on 42 pump units. The values of variations of basic parameters indicate the energy saving potential of pump units.


Author(s):  
George A. Adebiyi ◽  
Kalyan K. Srinivasan ◽  
Charles M. Gibson

Reciprocating IC engines are traditionally modeled as operating on air standard cycles that approximate indicator diagrams obtained in experiments on real engines. These indicator diagrams can best be approximated by the dual cycle for both gasoline and diesel engines. Analysis of air standard cycles unfortunately fails to capture second law effects such as exergy destruction due to the irreversibility of combustion. Indeed, a complete thermodynamic study of any process requires application of both the first and second laws of thermodynamics. This article gives a combined first and second law analysis of reciprocating IC engines in general with optimization of performance as primary goal. A practical dual-like cycle is assumed for the operation of a typical reciprocating IC engine and process efficiencies are assigned to allow for irreversibilities in the compression and expansion processes. The combustion process is modeled instead of being replaced simply by a heat input process to air as is common in air standard cycle analysis. The study shows that performance of the engine can indeed be optimized on the basis of geometrical design parameters such as the compression ratio as well as the air-fuel ratio used for the combustion.


1860 ◽  
Vol 10 ◽  
pp. 427-428 ◽  

This paper contains the full details of the authors’ experiments on the volumetric changes which occur in the formation of ozone. From three distinct series of experiments, performed by different methods, they show that when ozone is formed from pure oxygen by the action of the electrical discharge, a condensation takes place, as had already been announced in a former Note published in the 'Proceedings.’ But the condensation is much greater than the earlier experiments of the authors on the expansion by heat of electrolytic ozone had indicated. It is, in fact, so great, that if the allotropic view of the constitution of ozone be correct, the density of that body, as compared with oxygen, would be represented by a number corresponding to the density of a solid or liquid rather than that of a gaseous substance. This conclusion follows necessarily from the authors’ experiments, unless it be assumed that when ozone comes into contact with such substances as iodine, or a solution of iodide of potassium, one portion of it is changed back into common oxygen, while the remainder enters into combination, and that these portions are so related to one another, that the expansion due to the one is exactly equal to the contraction arising from the other. For the details of the experiments and of the methods of investigation employed, reference must be made to the original paper. The second part of the communication is devoted to the action of the silent discharge and of the electrical spark on other gases. Hydrogen and nitrogen undergo no change of volume when exposed to the action of either form of discharge. Cyanogen is readily decomposed by the spark, but presents so great a resistance to the passage of electricity, that the action of the silent discharge can scarcely be observed. Protoxide of nitrogen is readily attacked by both forms of discharge, with increase of volume and formation of nitrogen and hyponitric acid. Deutoxide of nitrogen exhibits the remarkable example of a gas which, under the action either of the silent discharge or of the spark, undergoes, like oxygen, a diminution of volume. It also is resolved into nitrogen and hyponitric acid. Carbonic oxide has given results of great interest; but the nature of the reaction has been only partially investigated. The silent discharge decomposes this gas with production of a substance of a bronze colour on the positive wire. The spark acts differently, destroying, as in the case of oxygen, the greater part of the contraction produced by the silent discharge. The authors are engaged in the further prosecution of this inquiry.


Author(s):  
M. Yılmaz ◽  
M. Zafer Gul ◽  
Y. Yukselenturk ◽  
B. Akay ◽  
H. Koten

It is estimated by the experts in the automotive industry that diesel engines on the transport market should increase within the years to come due to their high thermal efficiency coupled with low carbon dioxide (CO2) emissions, provided their nitrogen oxides (NOx) and particulate emissions are reduced. At present, adequate after-treatments, NOx and particulates matter (PM) traps are developed and industrialized with still concerns about fuel economy, robustness, sensitivity to fuel sulfur and cost because of their complex and sophisticated control strategy. New combustion processes focused on clean diesel combustion are investigated for their potential to achieve near zero particulate and NOx emissions. Their main drawbacks are increased level of unburned hydrocarbons (HC) and carbon monoxide (CO) emissions, combustion control at high load and limited operating range and power output. In this work, cold flow simulations for a single cylinder of a nine-liter (6 cylinder × 1.5 lt.) diesel engine have been performed to find out flow development and turbulence generation in the piston-cylinder assembly. In this study, the goal is to understand the flow field and the combustion process in order to be able to suggest some improvements on the in-cylinder design of an engine. Therefore combustion simulations of the engine have been performed to find out flow development and emission generation in the cylinder. Moreover, the interaction of air motion with high-pressure fuel spray injected directly into the cylinder has also been carried out. A Lagrangian multiphase model has been applied to the in-cylinder spray-air motion interaction in a heavy-duty CI engine under direct injection conditions. A comprehensive model for atomization of liquid sprays under high injection pressures has been employed. The combustion is modeled via a new combustion model ECFM-3Z (Extended Coherent Flame Model) developed at IFP. Finally, a calculation on an engine configuration with compression, spray injection and combustion in a direct injection Diesel engine is presented. Further investigation has also been performed in-cylinder design parameters in a DI diesel engine that result in low emissions by effect of high turbulence level. The results are widely in agreement qualitatively with the previous experimental and computational studies in the literature.


2003 ◽  
Vol 2 (1) ◽  
Author(s):  
A. T. Franco ◽  
C. O. R. Negrão

The current paper presents a model to predict indoor air temperature distribution. The approach is based on the energy conservation equation which is written for a certain number of finite volumes within the flow domain. The magnitude of the flow is estimated from a scale analysis of the momentum conservation equation. Discretized two or three-dimensional domains provide a set of algebraic equations. The resulting set of non-linear equations is iteratively solved using the line-by-line Thomas Algorithm. As long as the only equation to be solved is the conservation of energy and its coefficients are not strongly dependent on the temperature field, the solution is considerably fast. Therefore, the application of such model to a whole building system is quite reasonable. Two case studies involving buoyancy driven flows were carried out and comparisons with CFD solutions were performed. The results are quite promising for cases involving relatively strong couplings between heat and airflow.


2018 ◽  
Vol 75 (7) ◽  
pp. 2199-2216 ◽  
Author(s):  
A. A. M. Sayed ◽  
L. J. Campbell

Abstract A two-dimensional two-layer mathematical model is described representing internal gravity waves and convection generated by a thermal forcing in the lower atmosphere. The model consists of an upper layer with stable stratification, a lower layer with unstable stratification, and a thermal forcing in the form of a nonhomogeneous term in the energy conservation equation. Exact analytical solutions are derived for some simple configurations. Depending on the vertical location and depth of the thermal forcing, the model can be used to represent different configurations in which gravity waves are generated by diabatic heating. When the thermal forcing is centered in the lower layer, convective cells are generated in the lower layer, and gravity waves are forced and propagate upward from the interface between the two layers. When the thermal forcing is centered at the interface, the convection in the lower layer is weaker, and gravity waves are forced by the direct effect of the thermal forcing in the upper layer and the influence of the convective cells below. Steady-amplitude solutions for the vertical profile of the gravity waves and convection are derived and generalized to include cases where there is a spectrum of horizontal wavenumbers or vertical wavenumbers or frequencies present.


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