One-step Synthesis of O-self-doped Honeycomb-like Hierachically Porous Carbons for Supercapacitors

2021 ◽  
pp. 1-19
Author(s):  
Shiying Lin ◽  
Lanlan Mo ◽  
Feijun Wang
Keyword(s):  
Electrode Material ◽  
Porous Carbon ◽  
High Performance ◽  
Rate Capability ◽  
High Specific Capacitance ◽  
Electrode System ◽  
Porous Carbon Material ◽  
Hierarchical Porous ◽  
One Step ◽  
Porous Carbon Electrode

Abstract A facile and environmentally friendly approach to produce self-doped hierachically porous carbon as electrode material for high-performance supercapacitor was demonstrated. 3D honeycomb-like hierarchically porous carbon was successfully obtained by one-step carbonization and activation of sodium carboxymethyl cellulose (CMC) via K2CO3. With the optimized temperature of carbonization and activation, the porous carbon material achieved well-shaped hierarchically pores (micro-, meso and macropores) like a honeycomb, ultrahigh specific surface area (1666 m2·g-1), as well as highly O-self-doping (3.6 at.%), endowing an excellent electrochemical properties for the electrode in three-electrode system. The porous carbon electrode material delivered a high specific capacitance of 300.8 F·g-1 at 1 A·g-1, an eminent rate capability of 228.4 F·g-1 at the current density up to 20 A·g-1 and outstanding cycle stability of 94.3% retention after 10000 cycles. Therefore, the CMC derived hierarchical porous carbon activated by K2CO3 would have promising foreground in application of supercapacitors.

scholarly journals Facile fabrication of hierarchical porous carbon for a high-performance electrochemical capacitor

RSC Advances ◽  
2017 ◽  
Vol 7 (73) ◽  
pp. 46329-46335 ◽  
Author(s):  
Guixiang Du ◽  
Qiuxiao Bian ◽  
Jingbo Zhang ◽  
Xinhui Yang
Keyword(s):  
Porous Carbon ◽  
High Performance ◽  
Rate Capability ◽  
Electrochemical Capacitor ◽  
High Specific Capacitance ◽  
Cycling Performance ◽  
Hierarchical Porous Carbon ◽  
Hierarchical Porous ◽  
Facile Fabrication ◽  
Rapid Pyrolysis

A facile and rapid pyrolysis method is developed for the synthesis of 3D hierarchical porous carbon, which exhibits a high specific capacitance, good rate capability and good cycling performance.

Hierarchical porous NiCo2O4 nanograss arrays grown on Ni foam as electrode material for high-performance supercapacitors

RSC Advances ◽  
2014 ◽  
Vol 4 (39) ◽  
pp. 20234-20238 ◽  
Author(s):  
Zhenyu Wang ◽  
Yuefei Zhang ◽  
Yonghe Li ◽  
Haoyu Fu
Keyword(s):  
Electrochemical Performance ◽  
Hydrothermal Method ◽  
Electrode Material ◽  
High Performance ◽  
Ni Foam ◽  
Hierarchical Porous ◽  
One Step ◽  
Calcination Treatment

A novel hierarchical porous NiCo2O4 nanograss array directly grown on Ni foam has been constructed via a simple one-step hydrothermal method combined with a calcination treatment, and possessed high electrochemical performance.

Biowaste-derived 3D honeycomb-like porous carbon with binary-heteroatom doping for high-performance flexible solid-state supercapacitors

2018 ◽  
Vol 6 (1) ◽  
pp. 160-166 ◽  
Author(s):  
Yuxi Liu ◽  
Zechuan Xiao ◽  
Yongchang Liu ◽  
Li-Zhen Fan
Keyword(s):  
Solid State ◽  
Electrode Material ◽  
Porous Carbon ◽  
High Performance ◽  
High Specific Capacitance ◽  
High Energy ◽  
Cyclic Stability ◽  
Large Specific Surface Area ◽  
Heteroatom Doping ◽  
Co Doped

N and S-co-doped activated corncob sponge of honeycomb-like porous carbon with the interconnected micro-meso-macropores and the large specific surface area was evaluated as an electrode material for flexible solid-state supercapacitors, exhibiting high specific capacitance, high energy–power density, and great cyclic stability.

scholarly journals Digested sludge-derived three-dimensional hierarchical porous carbon for high-performance supercapacitor electrode

2018 ◽  
Vol 5 (4) ◽  
pp. 172456 ◽  
Author(s):  
Jia-Jia Zhang ◽  
Hao-Xiang Fan ◽  
Xiao-Hu Dai ◽  
Shi-Jie Yuan
Keyword(s):  
Porous Carbon ◽  
Carbon Material ◽  
High Performance ◽  
Three Dimensional ◽  
Value Added ◽  
Porous Carbon Material ◽  
Activation Process ◽  
Hierarchical Porous Carbon ◽  
Digested Sludge ◽  
Hierarchical Porous

Digested sludge, as the main by-product of the sewage sludge anaerobic digestion process, still contains considerable organic compounds. In this protocol, we report a facile method for preparing digested sludge-derived self-doped porous carbon material for high-performance supercapacitor electrodes via a sustainable pyrolysis/activation process. The obtained digested sludge-derived carbon material (HPDSC) exhibits versatile O-, N-doped hierarchical porous framework, high specific surface area (2103.6 m 2  g −1 ) and partial graphitization phase, which can facilitate ion transport, provide more storage sites for electrolyte ions and enhance the conductivity of active electrode materials. The HPDSC-based supercapacitor electrodes show favourable energy storage performance, with a specific capacitance of 245 F g −1 at 1.0 A g −1 in 0.5 M Na 2 SO 4 ; outstanding cycling stability, with 98.4% capacitance retention after 2000 cycles; and good rate performance (211 F g −1 at 11 A g −1 ). This work provides a unique self-doped three-dimensional hierarchical porous carbon material with a favourable charge storage capacity and at the same time finds a high value-added and environment-friendly strategy for disposal and recycling of digested sludge.

Green and tunable fabrication of graphene-like N-doped carbon on a 3D metal substrate as a binder-free anode for high-performance potassium-ion batteries

2019 ◽  
Vol 7 (38) ◽  
pp. 21966-21975 ◽  
Author(s):  
Yongling An ◽  
Yuan Tian ◽  
Yuan Li ◽  
Shenglin Xiong ◽  
Guoqun Zhao ◽  
...  
Keyword(s):  
Porous Carbon ◽  
High Performance ◽  
Metal Substrate ◽  
Potassium Ion ◽  
Hierarchical Porous Carbon ◽  
Carbonization Process ◽  
Hierarchical Porous ◽  
One Step ◽  
Binder Free

A graphene-like N-doped hierarchical porous carbon array on a 3D metal substrate is obtained by a green and one-step vacuum de-metal assisted carbonization process for high performance potassium-ion batteries.

Oxygen-enriched hierarchical porous carbon derived from biowaste sunflower heads for high-performance supercapacitors

RSC Advances ◽  
2015 ◽  
Vol 5 (130) ◽  
pp. 107785-107792 ◽  
Author(s):  
Di Ma ◽  
Guang Wu ◽  
Jiafeng Wan ◽  
Fangwei Ma ◽  
Weidan Geng ◽  
...  
Keyword(s):  
Electrode Material ◽  
Porous Carbon ◽  
High Performance ◽  
Hierarchical Porous Carbon ◽  
Supercapacitor Electrode ◽  
Hierarchical Porous ◽  
Sunflower Crop

Sunflower heads, a biowaste from sunflower crop, was first explored as a sustainable precursor to synthesize porous carbon (PC) as a supercapacitor electrode material.

Hierarchical porous structure carbon nanosheets derived from sodium lignosulfonate for high-performance supercapacitors

2020 ◽  
Vol 44 (48) ◽  
pp. 21271-21278
Author(s):  
Dichao Wu ◽  
Changzhou Chen ◽  
Jihui Li ◽  
Xiaopeng Jian ◽  
Ao Wang ◽  
...  
Keyword(s):  
Porous Carbon ◽  
Carbon Material ◽  
Lamellar Structure ◽  
High Performance ◽  
Porous Carbon Material ◽  
Two Dimensional ◽  
Hierarchical Porous Structure ◽  
Sodium Lignosulfonate ◽  
Carbon Nanosheets ◽  
Hierarchical Porous

Because of the special lamellar structure, numerous pores, and large effective specific surface area, the two-dimensional porous carbon material is very beneficial for the storage and transmission of energy.

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