An Experimental Study on Thermal Runaway Behavior for High-Capacity Li(Ni0.8Co0.1Mn0.1)O2 Pouch Cells at Different State of Charges

2020 ◽  
Vol 18 (2) ◽  
Author(s):  
Cheng Li ◽  
Hewu Wang ◽  
Xuebing Han ◽  
Yan Wang ◽  
Yu Wang ◽  
...  
Keyword(s):  
Surface Temperature ◽  
Ambient Pressure ◽  
Specific Capacity ◽  
High Capacity ◽  
Lithium Ion ◽  
Thermal Runaway ◽  
Structure Design ◽  
Maximum Surface ◽  
The Impact ◽  
Maximum Surface Temperature

Abstract Lithium-ion cells normally operate during 0% and 100% state of charge (SOC), therefore thermal runaway can occur at any SOC. In this paper, the 74 Ah lithium-ion pouch cells with the Li(Ni0.8Co0.1Mn0.1)O2 cathode were thermally abused by lateral heating in a semi-open chamber. The differences of thermal runaway behavior were investigated under six SOCs. Characteristic parameters such as triggering time and triggering temperature for thermal runaway show a negative correlation with SOCs, while maximum surface temperature and maximum surface temperature rise rate show a strongly positive correlation. Besides, mass loss ratio increases exponentially with equivalent specific capacity statistically, which implies that the pouch cells with high specific energy density and high capacity may eject more violently. Furthermore, the impact on the surroundings caused by high-temperature ejections was studied, and maximum ambient temperature and maximum ambient pressure in the chamber reached a plateau at middle SOCs. Based on the thermal impact on the surroundings, a theoretical method is proposed to evaluate the deterioration of heat dissipation by venting, and simplified to quantitatively calculate the deterioration under above SOCs. The results can provide guidance for battery safety management strategies and structure design of the battery pack.

Thermal Characteristic Analysis of Rectangular and Large-Capacity Lithium-Ion Power Batteries

2014 ◽  
Vol 1044-1045 ◽  
pp. 448-456
Author(s):  
Chun Jing Lin ◽  
Si Chuan Xu ◽  
Guo Feng Chang ◽  
Zhao Li
Keyword(s):  
Surface Temperature ◽  
Temperature Difference ◽  
Lithium Ion ◽  
Maximum Temperature ◽  
Characteristic Analysis ◽  
Large Capacity ◽  
Surface Temperature Change ◽  
Ambient Temperatures ◽  
Maximum Surface ◽  
Maximum Surface Temperature

Operating temperature and thermal uniformity have great effect on the performance, cycle life and safety of lithium-ion power batteries. In order to investigate the surface temperature change and distribution of a large-capacity and rectangular LiFePO4/C power battery, this paper conducts experiments on charging and discharging a battery module and cell at different current rates and various ambient temperatures. Results of thermalcouple-measurement show that temperature rising rates at different temperatures during charge and discharge change in accordance with the variation tendency of the resistance at different state of charge (SOC) and oprating temperatures. Under elevated ambient temperatures, the temperature excurtion and maximum temperature difference of the module are all smaller. Under the same ambient temperature, battery temperature at the end moment of discharge increases and the temperature uniformity of the module deteriorate at higher discharging rate. Temperature excurtion over the same time period is in a relationship of a standard quadratic function with the discharge current. Results of the thermal infrared imaging tests show that the maximum surface temperature differences at different discharging currents of 20A, 40A, and 80A are all above 5°C under natral convection heat transfer. The temperature of the lower part is higher than that of the upper part, while that of the central area is the highest. In a comprehensive charging and discharging scheme, the tendency of maximum surface temperature difference changes in accordance with that of the average surface temperature.

FACTORS INFLUENCING THE DETERMINATION OF MAXIMUM SURFACE TEMPERATURE FOR EXPLOSION-PROOF LUMINAIRES

2017 ◽  
Vol 16 (6) ◽  
pp. 1309-1316 ◽  
Author(s):  
Lucian Moldovan ◽  
Sorin Burian ◽  
Mihai Magyari ◽  
Marius Darie ◽  
Dragos Fotau
Keyword(s):  
Surface Temperature ◽  
Maximum Surface ◽  
Factors Influencing ◽  
Maximum Surface Temperature

scholarly journals Improvement of long-term cycling performance of high-nickel cathode materials by ZnO coating

2021 ◽  
Vol 10 (1) ◽  
pp. 210-220
Author(s):  
Fangfang Wang ◽  
Ruoyu Hong ◽  
Xuesong Lu ◽  
Huiyong Liu ◽  
Yuan Zhu ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Solid Phase ◽  
Low Cost ◽  
Specific Capacity ◽  
High Capacity ◽  
Lithium Ion ◽  
Side Reaction ◽  
Chemical Route ◽  
High Nickel

Abstract The high-nickel cathode material of LiNi0.8Co0.15Al0.05O2 (LNCA) has a prospective application for lithium-ion batteries due to the high capacity and low cost. However, the side reaction between the electrolyte and the electrode seriously affects the cycling stability of lithium-ion batteries. In this work, Ni2+ preoxidation and the optimization of calcination temperature were carried out to reduce the cation mixing of LNCA, and solid-phase Al-doping improved the uniformity of element distribution and the orderliness of the layered structure. In addition, the surface of LNCA was homogeneously modified with ZnO coating by a facile wet-chemical route. Compared to the pristine LNCA, the optimized ZnO-coated LNCA showed excellent electrochemical performance with the first discharge-specific capacity of 187.5 mA h g−1, and the capacity retention of 91.3% at 0.2C after 100 cycles. The experiment demonstrated that the improved electrochemical performance of ZnO-coated LNCA is assigned to the surface coating of ZnO which protects LNCA from being corroded by the electrolyte during cycling.

Novel melamine-based porous organic polymers: synthesis, characterizations, morphology modifications, and their applications in lithium-sulfur batteries

2021 ◽  
Author(s):  
Haiyang Liu ◽  
Jiaxing Wang ◽  
Miao SUN ◽  
Yu Wang ◽  
Runing Zhao ◽  
...  
Keyword(s):  
High Performance ◽  
Rational Design ◽  
Specific Capacity ◽  
High Capacity ◽  
Lithium Ion ◽  
Organic Polymer ◽  
Energy Storage Devices ◽  
Shuttle Effect ◽  
Physical Constraints ◽  
Lithium Sulfur

Abstract Lithium-sulfur (Li-S) batteries have been considered to be one of the most promising energy storage devices in the next generation. However, the insulating properties of sulfur and the shuttle effect of soluble lithium polysulfides (LiPSs) seriously hinder the practical application of Li-S batteries. In this paper, a novel porous organic polymer (HUT3) was prepared based on the polycondensation between melamine and 1,4-phenylene diisocyanate. The micro morphology of HUT3 was improved by in-situ growth on different mass fractions of rGO (5%, 10%, 15%), and the obtained HUT3-rGO composites were employed as sulfur carriers in Li-S batteries with promoted the sulfur loading ratio and lithium ion mobility. Attributed to the synergistic effect of the chemisorption of polar groups and the physical constraints of HUT3 structure, HUT3-rGO/S electrodes exhibits excellent capacity and cyclability performance. For instance, HUT3-10rGO/S electrode exhibits a high initial specific capacity of 950 mAh g-1 at 0.2 C and retains a high capacity of 707 mAh g-1 after 500 cycles at 1 C. This work emphasizes the importance of the rational design of the chemical structure and opens up a simple way for the development of cathode materials suitable for high-performance Li-S batteries.

Constructing zigzag-like hollow mesoporous nanospheres MoO2/C with superior lithium storage performance

2021 ◽  
Author(s):  
Wencai Zhao ◽  
Y.F. Yuan ◽  
S.M. Yin ◽  
Gaoshen Cai ◽  
S.Y. Guo
Keyword(s):  
Reaction Kinetics ◽  
Discharge Capacity ◽  
Amorphous Carbon ◽  
Electronic Conductivity ◽  
Specific Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
Structure Design ◽  
Structure Stability ◽  
Lithium Storage

Abstract Hollow mesoporous nanospheres MoO2/C are successfully constructed through metal chelating reaction between molybdenum acetylacetone and glycerol as well as the Kirkendall effect induced by diammonium hydrogen phosphate. MoO2 nanoparticles coupled by amorphous carbon are assembled to unique zigzag-like hollow mesoporous nanosphere with large specific surface area of 147.7 m2 g-1 and main pore size of 8.7 nm. The content of carbon is 9.1%. As anode material for lithium-ion batteries, the composite shows high specific capacity and excellent cycling performance. At 0.2 A g-1, average discharge capacity stabilizes at 1092 mAh g-1. At 1 A g-1 after 700 cycles, the discharge capacity still reaches 512 mAh g-1. Impressively, the composite preserves intact after 700 cycles. Even at 5 A g-1, the discharge capacity can reach 321 mAh g-1, exhibiting superior rate capability. Various kinetics analyses demonstrate that in electrochemical reaction, the proportion of the surface capacitive effect is higher, and the composite has relatively high diffusion coefficient of Li ions and fast faradic reaction kinetics. Excellent lithium storge performance is attributed to the synergistic effect of zigzag-like hollow mesoporous nanosphere and amorphous carbon, which improves reaction kinetics, structure stability and electronic conductivity of MoO2. The present work provides a new useful structure design strategy for advanced energy storage application of MoO2.

An artificial sea urchin with hollow spines: improved mechanical and electrochemical stability in high-capacity Li–Ge batteries

Nanoscale ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 5812-5816 ◽  
Author(s):  
Jinyun Liu ◽  
Xirong Lin ◽  
Tianli Han ◽  
Qianqian Lu ◽  
Jiawei Long ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Sea Urchin ◽  
Specific Capacity ◽  
High Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
Electrochemical Stability ◽  
High Rate ◽  
High Rate Capability ◽  
High Specific Capacity

Metallic germanium (Ge) as the anode can deliver a high specific capacity and high rate capability in lithium ion batteries.

Modification of High Potential, High Capacity Li2FeP2O7 Cathode Material for Lithium Ion Batteries

2012 ◽  
Vol 1440 ◽  
Author(s):  
Jiajia Tan ◽  
Ashutosh Tiwari
Keyword(s):  
Cathode Material ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Electrochemical Impedance ◽  
Specific Capacity ◽  
High Capacity ◽  
Lithium Ion ◽  
Discharge Rates ◽  
Electronic Conductivities ◽  
Fast Discharge

ABSTRACTLi2FeP2O7 is a newly developed polyanionic cathode material for high performance lithium ion batteries. It is considered very attractive due to its large specific capacity, good thermal and chemical stability, and environmental benignity. However, the application of Li2FeP2O7 is limited by its low ionic and electronic conductivities. To overcome the above problem, a solution-based technique was successfully developed to synthesize Li2FeP2O7 powders with very fine and uniform particle size (< 1 μm), achieving much faster kinetics. The obtained Li2FeP2O7 powders were tested in lithium ion batteries by measurements of cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge/discharge cycling. We found that the modified Li2FeP2O7 cathode could maintain a relatively high capacity even at fast discharge rates.

Thermal Non-Newtonian Elastohydrodynamic Lubrication of Line Contacts Under Simple Sliding Conditions

1992 ◽  
Vol 114 (2) ◽  
pp. 317-327 ◽  
Author(s):  
Shao Wang ◽  
T. F. Conry ◽  
C. Cusano
Keyword(s):  
Film Thickness ◽  
Surface Temperature ◽  
Thermal Effects ◽  
Elastohydrodynamic Lubrication ◽  
Reduction Factor ◽  
Simple Formulation ◽  
Maximum Surface ◽  
Line Contacts ◽  
Traction Coefficient ◽  
Maximum Surface Temperature

A computationally simple formulation for the stationary surface temperature is developed to examine the thermal non-Newtonian EHD problem for line contacts under simple sliding conditions. Numerical results obtained are used to develop a formula for a thermal and non-Newtonian (Ree-Eyring) film thickness reduction factor. Results for the maximum surface temperature and traction coefficient are also presented. The thermal effects on film thickness and traction are found to be more pronounced for simple sliding than for combined sliding and rolling conditions.

scholarly journals Determining the maximum surface temperature for non-electrical equipment aiming at explosion prevention at protection

2020 ◽  
Vol 305 ◽  
pp. 00026
Author(s):  
Adrian Marius Jurca ◽  
Niculina Vătavu ◽  
Leonard Lupu ◽  
Mihai Popa
Keyword(s):  
Surface Temperature ◽  
Hazard Assessment ◽  
Electrical Equipment ◽  
Operating Conditions ◽  
Laboratory Research ◽  
Safety Level ◽  
Protective Measures ◽  
Protection Measures ◽  
Maximum Surface ◽  
Maximum Surface Temperature

Non-electrical equipment has been used for over 150 years in industries with potentially explosive atmospheres and great experience has been gained with regard to the application of protective measures to reduce the risk of ignition down to an acceptable safety level. The use of non-electrical equipment in explosive atmospheres required the development of specific requirements with regard to the concept of protection against the ignition of explosive atmospheres, which to clearly define protection measures and to include the experience gained and extended over the years. The practical studies, laboratory research and methods for assessing and testing the hazard of ignition by hot surfaces presented within the paper have as main purpose the improvement of ignition hazard assessment in different operating conditions.

Sign in / Sign up

Export Citation Format

Share Document