Multifunctional Three-Dimensional Curvilinear Self-Folding of Glassy Polymers

2020 ◽  
Vol 8 (3) ◽  
Author(s):  
Jae Gyeong Lee ◽  
Sukyoung Won ◽  
Jeong Eun Park ◽  
Jeong Jae Wie
Keyword(s):  
Light Absorption ◽  
Three Dimensional ◽  
Strain Engineering ◽  
Local Deformation ◽  
Glassy Polymers ◽  
Polymeric Films ◽  
Stimuli Responsive ◽  
Shape Morphing ◽  
Curvilinear Structures ◽  
External Stimuli

Abstract The selective light absorption of prestretched thermoplastic polymeric films enables wireless photothermal shape morphing from two-dimensional Euclidean geometry of films to three-dimensional (3D) curvilinear architectures. For a facile origami-inspired programming of 3D folding, black inks are printed on glassy polymers that are used as hinges to generate light-absorption patterns. However, the deformation of unpatterned areas and/or stress convolution of patterned areas hinder the creation of accurate curvilinear structures. In addition, black inks remain in the film, prohibiting the construction of transparent 3D architectures. In this study, we demonstrate the facile preparation of transparent 3D curvilinear structures with the selection of the curvature sign and chirality via the selective light absorption of detachable tapes. The sequential removal of adhesive patterns allowed sequential folding and the control of strain responsivity in a single transparent architecture. The introduction of multiple heterogeneous nonresponsive materials increased the complexity of strain engineering and functionality. External stimuli responsive kirigami-based bridge triggered the multimaterial frame to build the Gaussian curvature. Conductive material casted on the film in a pattern retained the conductivity, despite local deformation. This type of tape patterning system, adopting various materials, can achieve multifunction including transparency and conductivity.

Multi-Functional 3D Curvilinear Self-Folding of Glassy Polymers

2020 ◽  
Author(s):  
Jae Gyeong Lee ◽  
Sukyoung Won ◽  
Jeong Eun Park ◽  
Jeong Jae Wie
Keyword(s):  
Light Absorption ◽  
Three Dimensional ◽  
Strain Engineering ◽  
Local Deformation ◽  
Glassy Polymers ◽  
Stimuli Responsive ◽  
Responsive Materials ◽  
Shape Morphing ◽  
Curvilinear Structures ◽  
External Stimuli

Abstract The selective light absorption of pre-stretched thermoplastic polymeric films enables wireless photothermal shape morphing from two-dimensional Euclidean geometry of films to three-dimensional (3D) curvilinear architectures. For a facile origami-inspired programming of 3D folding, black inks are printed on glassy polymers that are used as hinges to generate light-absorption patterns. However, the deformation of unpatterned areas and/or stress convolution of patterned areas hinder the creation of accurate curvilinear structures. In addition, black inks remain in the film, prohibiting the construction of transparent 3D architectures. In this study, we demonstrate the facile preparation of transparent 3D curvilinear structures with the selection of the curvature sign and chirality via the selective light absorption of detachable tapes. The sequential removal of adhesive patterns allowed sequential folding and the control of strain responsivity in a single transparent architecture. The introduction of multiple heterogeneous non-responsive materials increased the complexity of strain engineering and functionality. External stimuli responsive kirigami-based bridge triggered the multi-material frame to build the Gaussian curvature. Conductive material casted on the film in a pattern retained the conductivity, despite local deformation. This type of tape patterning system, adopting various materials, can achieve multifunction including transparency and conductivity.

scholarly journals Gaussian-preserved, non-volatile shape morphing in three-dimensional microstructures for dual-functional electronic devices

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Ziao Tian ◽  
Borui Xu ◽  
Guangchao Wan ◽  
Xiaomin Han ◽  
Zengfeng Di ◽  
...  
Keyword(s):  
Electronic Devices ◽  
Three Dimensional ◽  
Functional Diversification ◽  
Impatiens Glandulifera ◽  
Shape Morphing ◽  
Dual Functional ◽  
Dionaea Muscipula ◽  
External Stimuli ◽  
Thermal Stimuli ◽  
Mechanical Movement

AbstractMotile plant structures such as Mimosa pudica leaves, Impatiens glandulifera seedpods, and Dionaea muscipula leaves exhibit fast nastic movements in a few seconds or less. This motion is stimuli-independent mechanical movement following theorema egregium rules. Artificial analogs of tropistic motion in plants are exemplified by shape-morphing systems, which are characterized by high functional robustness and resilience for creating 3D structures. However, all shape-morphing systems developed so far rely exclusively on continuous external stimuli and result in slow response. Here, we report a Gaussian-preserved shape-morphing system to realize ultrafast shape morphing and non-volatile reconfiguration. Relying on the Gaussian-preserved rules, the transformation can be triggered by mechanical or thermal stimuli within a microsecond. Moreover, as localized energy minima are encountered during shape morphing, non-volatile configuration is preserved by geometrically enhanced rigidity. Using this system, we demonstrate a suite of electronic devices that are reconfigurable, and therefore, expand functional diversification.

Smart Polymers and their Applications: A Review

2017 ◽  
Vol 8 (03) ◽  
Author(s):  
Gore S. A. ◽  
Gholve S. B. ◽  
Savalsure S. M. ◽  
Ghodake K. B. ◽  
Bhusnure O. G. ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Water Soluble ◽  
Solution Temperature ◽  
Smart Polymers ◽  
Stimuli Responsive ◽  
Responsive Materials ◽  
Water Soluble Polymers ◽  
Commercial Applications ◽  
Stimuli Sensitive ◽  
External Stimuli

Smart polymers are materials that respond to small external stimuli. These are also referred as stimuli responsive materials or intelligent materials. Smart polymers that can exhibit stimuli-sensitive properties are becoming important in many commercial applications. These polymers can change shape, strength and pore size based on external factors such as temperature, pH and stress. The stimuli include salt, UV irradiation, temperature, pH, magnetic or electric field, ionic factors etc. Smart polymers are very promising applicants in drug delivery, tissue engineering, cell culture, gene carriers, textile engineering, oil recovery, radioactive wastage and protein purification. The study is focused on the entire features of smart polymers and their most recent and relevant applications. Water soluble polymers with tunable lower critical solution temperature (LCST) are of increasing interest for biological applications such as cell patterning, smart drug release, DNA sequencing etc.

scholarly journals Dynamic Manipulation of THz Waves Enabled by Phase-Transition VO2 Thin Film

Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 114
Author(s):  
Chang Lu ◽  
Qingjian Lu ◽  
Min Gao ◽  
Yuan Lin
Keyword(s):  
Optical Methods ◽  
Stimuli Responsive ◽  
Device Structure ◽  
Current State ◽  
Insulator Metal Transition ◽  
Potential Applications ◽  
Fs Laser ◽  
External Stimuli ◽  
Thz Applications ◽  
Thz Waves

The reversible and multi-stimuli responsive insulator-metal transition of VO2, which enables dynamic modulation over the terahertz (THz) regime, has attracted plenty of attention for its potential applications in versatile active THz devices. Moreover, the investigation into the growth mechanism of VO2 films has led to improved film processing, more capable modulation and enhanced device compatibility into diverse THz applications. THz devices with VO2 as the key components exhibit remarkable response to external stimuli, which is not only applicable in THz modulators but also in rewritable optical memories by virtue of the intrinsic hysteresis behaviour of VO2. Depending on the predesigned device structure, the insulator-metal transition (IMT) of VO2 component can be controlled through thermal, electrical or optical methods. Recent research has paid special attention to the ultrafast modulation phenomenon observed in the photoinduced IMT, enabled by an intense femtosecond laser (fs laser) which supports “quasi-simultaneous” IMT within 1 ps. This progress report reviews the current state of the field, focusing on the material nature that gives rise to the modulation-allowed IMT for THz applications. An overview is presented of numerous IMT stimuli approaches with special emphasis on the underlying physical mechanisms. Subsequently, active manipulation of THz waves through pure VO2 film and VO2 hybrid metamaterials is surveyed, highlighting that VO2 can provide active modulation for a wide variety of applications. Finally, the common characteristics and future development directions of VO2-based tuneable THz devices are discussed.

Three-dimensional Graphene Coated Shape Memory Polyurethane Foam with Fast Responsive Performance

2021 ◽  
Author(s):  
Tianjiao Wang ◽  
Jun Zhao ◽  
Chuanxin Weng ◽  
Tong Wang ◽  
Yayun Liu ◽  
...  
Keyword(s):  
Shape Memory ◽  
Polyurethane Foam ◽  
Three Dimensional ◽  
Shape Memory Polymers ◽  
Practical Applications ◽  
External Stimuli ◽  
Shape Memory Polyurethane

Shape memory polymers (SMPs) that change shapes as designed by external stimuli have become one of the most promising materials as actuators, sensors, and deployable devices. However, their practical applications...

scholarly journals Applications of Biomaterials in 3D Cell Culture and Contributions of 3D Cell Culture to Drug Development and Basic Biomedical Research

2021 ◽  
Vol 22 (5) ◽  
pp. 2491
Author(s):  
Yujin Park ◽  
Kang Moo Huh ◽  
Sun-Woong Kang
Keyword(s):  
Cell Culture ◽  
Three Dimensional ◽  
3D Culture ◽  
3D Cell Culture ◽  
Accurate Method ◽  
New Drugs ◽  
Toxicity Screening ◽  
Cellular Functions ◽  
Toxicity Of Drugs ◽  
External Stimuli

The process of evaluating the efficacy and toxicity of drugs is important in the production of new drugs to treat diseases. Testing in humans is the most accurate method, but there are technical and ethical limitations. To overcome these limitations, various models have been developed in which responses to various external stimuli can be observed to help guide future trials. In particular, three-dimensional (3D) cell culture has a great advantage in simulating the physical and biological functions of tissues in the human body. This article reviews the biomaterials currently used to improve cellular functions in 3D culture and the contributions of 3D culture to cancer research, stem cell culture and drug and toxicity screening.

scholarly journals Metal-Organic Framework-Based Stimuli-Responsive Polymers

2021 ◽  
Vol 5 (4) ◽  
pp. 101
Author(s):  
Menglian Wei ◽  
Yu Wan ◽  
Xueji Zhang
Keyword(s):  
Metal Organic Framework ◽  
Chemical Properties ◽  
Stimuli Responsive ◽  
Guest Molecules ◽  
Stimuli Responsive Polymers ◽  
Responsive Polymers ◽  
Reversible Phase Transition ◽  
Metal Organic ◽  
External Stimuli ◽  
Organic Framework

Metal-organic framework (MOF) based stimuli-responsive polymers (coordination polymers) exhibit reversible phase-transition behavior and demonstrate attractive properties that are capable of altering physical and/or chemical properties upon exposure to external stimuli, including pH, temperature, ions, etc., in a dynamic fashion. Thus, their conformational change can be imitated by the adsorption/desorption of target analytes (guest molecules), temperature or pressure changes, and electromagnetic field manipulation. MOF-based stimuli responsive polymers have received great attention due to their advanced optical properties and variety of applications. Herein, we summarized some recent progress on MOF-based stimuli-responsive polymers (SRPs) classified by physical and chemical responsiveness, including temperature, pressure, electricity, pH, metal ions, gases, alcohol and multi-targets.

scholarly journals Increase in Total Elongation Caused by Pure Shear Deformation in Ultra-Fine-Grained Cu Processed by Equal-Channel Angular Pressing

Metals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 654
Author(s):  
Ryosuke Matsutani ◽  
Nobuo Nakada ◽  
Susumu Onaka
Keyword(s):  
Shear Deformation ◽  
Equal Channel Angular Pressing ◽  
Pure Shear ◽  
Three Dimensional ◽  
Tensile Tests ◽  
Total Elongation ◽  
Local Deformation ◽  
Image Correlation ◽  
Fine Grained ◽  
Angular Pressing

Ultra-fine-grained (UFG) Cu shows little total elongation in tensile tests because simple shear deformation is concentrated in narrow regions during the initial stage of plastic deformation. Here, we attempted to improve the total elongation of UFG Cu obtained by equal-channel angular pressing. By making shallow dents on the side surfaces of the plate-like specimens, this induced pure shear deformation and increased their total elongation. During the tensile tests, we observed the overall and local deformation of the dented and undented UFG Cu specimens. Using three-dimensional digital image correlation, we found that the dented specimens showed suppression of thickness reduction and delay in fracture by enhancement of pure shear deformation. However, the dented and undented specimens had the same ultimate tensile strength. These results provide us a new concept to increase total elongation of UFG materials.

scholarly journals Numerical Analysis of the Perforated Steel Sheets Under Uni-Axial Tensile Force

Metals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 632 ◽  
Author(s):  
Ahmed M. Sayed
Keyword(s):  
Load Capacity ◽  
Tensile Force ◽  
Three Dimensional ◽  
Tensile Load ◽  
Experimental Tests ◽  
Strain Engineering ◽  
Uniaxial Tensile ◽  
Fe Model ◽  
Stress Strain ◽  
Steel Sheets

The perforated steel sheets have many uses, so they should be studied under the influence of the uniaxial tensile load. The presence of these holes in the steel sheets certainly affects the mechanical properties. This paper aims at studying the behavior of the stress-strain engineering relationships of the perforated steel sheets. To achieve this, the three-dimensional finite element (FE) model is mainly designed to investigate the effect of this condition. Experimental tests were carried out on solid specimens to be used in the test of model accuracy of the FE simulation. Simulation testing shows that the FE modeling revealed the ability to calculate the stress-strain engineering relationships of perforated steel sheets. It can be concluded that the effect of a perforated rhombus shape is greater than the others, and perforated square shape has no effect on the stress-strain engineering relationships. The efficiency of the perforated staggered or linearly distribution shapes with the actual net area on the applied loads has the opposite effect, as it reduces the load capacity for all types of perforated shapes. Despite the decrease in load capacity, it improves the properties of the steel sheets.

A Method for Measuring Deformation Rates in Hydrogel Structures: Multi-Plane Imaging and Measurement Limitations

2000 ◽  
Author(s):  
Joseph M. Bauer ◽  
David J. Beebe
Keyword(s):  
Cross Sections ◽  
Particle Image ◽  
Three Dimensional ◽  
Local Deformation ◽  
Dimensional Representation ◽  
Volume Changes ◽  
Mechanical Constraints ◽  
Seed Particles ◽  
Three Dimensional Representation ◽  
Image Velocimetry

Abstract A technique for determining the three dimensional motions of hydrogel structures in microchannels is introduced. In developing this technique, we have adapted microscopic particle image velocimetry (μPIV), a method for measuring velocity fields in microfluidic devices. The motions of 1 μm fluorescent seed particles that are incorporated into a hydrogel microstructure (200 μm tall × 400 μm diameter) are tracked over several expansion cycles using microscopy. Combining measurements taken in different planes produces a three-dimensional representation of the motions present during volume changes can be reconstructed. By providing cross sections of the local deformation rates in hydrogel microstructures, this technique allows for the optimization of device designs as well as providing a better understanding of the processes by which hydrogels change volume under mechanical constraints.

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