Calculation of Dynamical Phase Diagram in U-Zr Binary System Under Irradiation

2020 ◽  
Vol 7 (1) ◽  
Author(s):  
Yong Lu ◽  
Zheng Jiang ◽  
Linyang Li ◽  
Cuiping Wang ◽  
Yihui Guo ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Free Energy ◽  
Binary System ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram ◽  
Dynamical Phase ◽  
Free Energy Model ◽  
Induced Defects ◽  
Irradiation Induced Defects ◽  
Zr Alloy

Abstract By taking into account the ballistic mixing caused by recoil implantation and cascade collision, a model that describing effective free energy for alloys under irradiation from the perspective of diffusion equilibrium was used to study the effect of irradiation-induced defects on phase stability in U-Zr binary system. Based on the effective free energy model and the thermodynamic model, dynamical phase diagrams of U-Zr alloy under different irradiation intensities were calculated, and the differences between the dynamical phase diagram and thermodynamic equilibrium phase diagram (TEPD) were discussed. The obtained results indicate that, under irradiation, the high-temperature stable γ(U, Zr) phase can be stabilized resulting in two invariant reactions at low temperature, which could be ascribed to the domination of irradiation-induced ballistic mixing.

Steady-State Dynamic Phase Diagram Calculation of U-Ti and U-V Binary System under Irradiation

2020 ◽  
Vol 993 ◽  
pp. 996-1003
Author(s):  
Yong Lu ◽  
Zheng Jiang ◽  
Qiao Qiao Tang ◽  
Cui Ping Wang ◽  
Xing Jun Liu
Keyword(s):  
Phase Diagram ◽  
Steady State ◽  
Binary System ◽  
Low Temperature ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram ◽  
Enhanced Diffusion ◽  
Dynamical Phase ◽  
Irradiation Intensity ◽  
Phase Relationships

In this paper, by considering the irradiation-enhanced diffusion, a combination of effective free energy model and the thermodynamic model was used for studying the phase relationships in the U-Ti and U-V binary system under irradiation. The steady-state dynamical phase diagrams of U-Ti and U-V binary alloys under different irradiation intensities were calculated and compared with the conventional thermodynamic equilibrium phase diagram. The calculated results show that under irradiation the high-temperature stable (βTi, γU) and (γU,V) phases were stabilized at relatively low temperature resulting in invariant reactions at relatively low temperature. In addition, with the increase of the irradiation intensity, the temperature of the invariant reactions increased, and the phase regions of the (βTi, γU) and (γU,V) also increased.

Intermetallic Formation in the Aluminum–Copper System

2003 ◽  
Vol 10 (04) ◽  
pp. 677-683 ◽  
Author(s):  
E. B. Hannech ◽  
N. Lamoudi ◽  
N. Benslim ◽  
B. Makhloufi
Keyword(s):  
Electron Microscopy ◽  
Phase Diagram ◽  
Solid Solution ◽  
Intermetallic Layer ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram ◽  
Diffusion Couples ◽  
Intermetallic Formation ◽  
Parabolic Law ◽  
Scanning Electron

Intermetallic formation at 425°C in the aluminum–copper system has been studied by scanning electron microscopy using welded diffusion couples. Several Al–Cu phases predicted by the equilibrium phase diagram of the elements and voids taking place in the diffusion zone have been detected in the couples. The predominant phases were found to be Al 2 Cu 3 and the solid solution of Al in Cu, α. The growth of the intermetallic layer obeyed the parabolic law.

Equilibrium phase diagram of polystyrene and 8CB

1999 ◽  
Vol 37 (15) ◽  
pp. 1841-1848 ◽  
Author(s):  
Farida Benmouna ◽  
Abdelylah Daoudi ◽  
Fr�d�rick Roussel ◽  
Jean-Marc Buisine ◽  
Xavier Coqueret ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram

scholarly journals Formation of Intermediate Phases and Supersaturated Solid Solution in Al-Cu System during Diffusion

2018 ◽  
Vol 383 ◽  
pp. 31-35 ◽  
Author(s):  
Alexey Rodin ◽  
Nataliya Goreslavets
Keyword(s):  
Phase Diagram ◽  
Solid Solution ◽  
High Temperature ◽  
Chemical Composition ◽  
Low Temperature ◽  
Supersaturated Solid Solution ◽  
Diffusion Processes ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram ◽  
Intermediate Phases

The study of diffusion processes in the aluminum - copper system was carried out at the temperature 350 and 520 °C. Special attention was paid on the chemical composition of the system near Al/Cu interface. It was determined that the intermediate phases in the system, corresponding to the equilibrium phase diagram, were not formed at low temperature. At high temperature the intermediate phases forms starting with Cu - rich phases. In both cases supersaturated solid solution of copper in aluminum could be observed near the interface.

scholarly journals Equilibrium Phase Diagram of the Zn–Ag Alloy

2018 ◽  
Vol 20 (3) ◽  
pp. 72-84
Author(s):  
Alexey Korolev ◽  
◽  
Gennagy Maltsev ◽  
Konstantin Timofeev ◽  
Vladimir Lobanov ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram

Equilibrium Phase Diagram of Li＋,Na＋∥,CO32－,B4O72－-H2O Quaternary System at 288 K

2002 ◽  
Vol 18 (09) ◽  
pp. 835-837 ◽  
Author(s):  
Sang Shi-Hua ◽  
◽  
Yin Hui-An ◽  
Tang Ming-Lin ◽  
Zhang Yun-Xiang
Keyword(s):  
Phase Diagram ◽  
Quaternary System ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram
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