Examination of Predictive Flame Extinction Boundaries for Bluff Body Stabilized Flames at Elevated Temperature and Pressure Conditions

2020 ◽  
Vol 142 (10) ◽  
Author(s):  
Candy Hernandez ◽  
Vincent McDonell
Keyword(s):  
Bluff Body ◽  
Elevated Temperatures ◽  
Premixed Combustion ◽  
Flame Stability ◽  
Flame Extinction ◽  
Stability Studies ◽  
Fuel Type ◽  
Wide Range ◽  
Hydrogen Mixtures ◽  
Temperature And Pressure

Abstract A correlation for the prediction of flame lean extinction limits for premixed combustion systems by Sullivan-Lewis and McDonell is examined. The correlation was developed with the data collected from Sullivan-Lewis' experiments of methane and hydrogen mixtures at elevated temperatures and pressures, similar to gas turbine conditions. Recent flame stability studies have since appeared in literature and has allowed for inspection of the validity of the predictive flame extinction boundary correlation with new data. The blow-off boundary correlation is also examined with previous flame blow off studies with significant variances of parameters compared to the original study used to build the correlation. The data used for comparison differ with fuel type, equivalence ratios, pressures, temperatures, turbulence intensities, and flameholder geometries. The analysis concludes that the predictive flame extinction correlation developed is able to accurately predict a wide range of extinction conditions reported in the literature. However, it is observed that the correlation is not able to fully capture the behavior of the data for conditions in which turbulence intensities are above 5%.

scholarly journals Emissions and Stability Characteristics of Flameholders for Lean-Premixed Combustion

1992 ◽  
Author(s):  
Jeffrey A. Lovett ◽  
Nesim Abuaf
Keyword(s):  
Bluff Body ◽  
Flame Temperature ◽  
Perforated Plate ◽  
Premixed Combustion ◽  
Flame Stability ◽  
Nox Emissions ◽  
Lean Premixed Combustion ◽  
Lean Premixed ◽  
The Stability ◽  
Lean Conditions

An experimental study was conducted to determine the NOx emissions and flame stability associated with various flameholders used to support lean-premixed combustion of natural gas at gas turbine conditions. Data were obtained for velocities of 6 to 24 m/s, initial temperatures of 533 to 650 K, and pressures of 3.4 to 13.6 atm. Bluff-body, perforated-plate, and swirl-stabilized flameholders were tested and compared. The results confirm that NOx emissions at ultra-lean conditions scale with the flame temperature and are essentially independent of flameholder geometry for typical combustor residence times. The stability behavior, however, was strongly affected by flameholder type, illustrating the influence of fluid mechanics on flame stability. The flame stability was related also to the dynamics produced by combustion instability. A swirl-stabilized flameholder demonstrated the best stability characteristics at the expense of flameholder pressure drop.

scholarly journals Thermodynamic Properties of Aqueous Species Calculated Using the HKF Model: How Do Different Thermodynamic and Electrostatic Models for Solvent Water Affect Calculated Aqueous Properties?

Geofluids ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-24 ◽  
Author(s):  
George D. Miron ◽  
Allan M. M. Leal ◽  
Alina Yapparova
Keyword(s):  
Experimental Data ◽  
Dielectric Properties ◽  
Thermodynamic Properties ◽  
Elevated Temperatures ◽  
Rock Interaction ◽  
Water Solvent ◽  
Wide Range ◽  
Temperature And Pressure ◽  
The Impact ◽  
Aqueous Species

Thermodynamic properties of aqueous species are essential for modeling of fluid-rock interaction processes. The Helgeson-Kirkham-Flowers (HKF) model is widely used for calculating standard state thermodynamic properties of ions and complexes over a wide range of temperatures and pressures. To do this, the HKF model requires thermodynamic and electrostatic models of water solvent. In this study, we investigate and quantify the impact of choosing different models for calculating water solvent volumetric and dielectric properties, on the properties of aqueous species calculated using the HKF model. We identify temperature and pressure conditions at which the choice of different models can have a considerable effect on the properties of aqueous species and on fluid mineral equilibrium calculations. The investigated temperature and pressure intervals are 25–1000°C and 1–5 kbar, representative of upper to middle crustal levels, and of interest for modeling ore-forming processes. The thermodynamic and electrostatic models for water solvent considered are: Haar, Gallagher and Kell (1984), Wagner and Pruß (2002), and Zhang and Duan (2005), to calculate water volumetric properties, and Johnson and Norton (1991), Fernandez and others (1997), and Sverjensky and others (2014), to calculate water dielectric properties. We observe only small discrepancies in the calculated standard partial molal properties of aqueous species resulting from using different water thermodynamic models. However, large differences in the properties of charged species can be observed at higher temperatures (above 500°C) as a result of using different electrostatic models. Depending on the aqueous speciation and the reactions that control the chemical composition, the observed differences can vary. The discrepancy between various electrostatic models is attributed to the scarcity of experimental data at high temperatures. These discrepancies restrict the reliability of the geochemical modeling of hydrothermal and ore formation processes, and the retrieval of thermodynamic parameters from experimental data at elevated temperatures and pressures.

Effect of Fuel Dilution on the Stability Characteristics of Syngas Diffusion Flames

2008 ◽  
Author(s):  
Kejin Mo ◽  
Yongsheng Zhang ◽  
Zhedian Zhang ◽  
Yue Wang ◽  
Yunhan Xiao ◽  
...  
Keyword(s):  
Bluff Body ◽  
Diffusion Flames ◽  
Maximum Flow ◽  
Operating Conditions ◽  
Flame Stability ◽  
Oh Radical ◽  
Flame Extinction ◽  
Reaction Zones ◽  
Fuel Dilution ◽  
Dilution Effects

In order to investigate the effects of fuel dilution on flame stability characteristics, open syngas diffusion flames are established and H2O, N2 and CO2 are employed respectively as diluents. The burner configuration used in this study consists of a bluff body with a central jet flow of the fuel and a surrounding coflow of the air. The syngas is composed of 50% of H2 and 50% of CO (by volume). The experiments are conducted at 1 atmospheric pressure, and the temperatures of the fuel and the air are kept constant at about 400 K. The results show that the flame tapers inward and becomes more cylindrical in the shape as after the dilution, the flame becomes unstable due to dilution effects. It has been found that there is a maximum flow rate of diluents responsible for the flame extinction. Among these three dilutions, H2O diluted flames exhibit a highest stability, while CO2 diluted flames have the lowest one due to its large specific heat. Planar Laser-Induced Fluorescence (PLIF) measurements of the OH radical are applied to study the behavior of the OH radical in the flames. The results show that as the diluents introduced into the flame increases, the overall OH mole fraction significantly decreases, and the flame width also decreases. The structures of flame bases are also studied to obtain a better understanding of fuel dilution effects on the flame stability. The radial stabilization distance is decreased and the local flame extinctions in the reaction zones are found as dilution increases. For operating conditions close to the flame extinction limit, the flame reaction zones in the flame bases take on a more intermittent, shredded appearance.

Mechanical Properties and Dislocation Structure of Single Crystal Cdte Deformed in Compression at 300°C

1976 ◽  
Vol 34 ◽  
pp. 592-593
Author(s):  
Ernest L. Hall ◽  
J. B. Vander Sande
Keyword(s):  
Mechanical Properties ◽  
Single Crystal ◽  
Dislocation Structure ◽  
Room Temperature ◽  
Elevated Temperatures ◽  
Strain Curve ◽  
Optical Devices ◽  
Semiconductor Compound ◽  
Wide Range ◽  
Sample Orientation

The present paper describes research on the mechanical properties and related dislocation structure of CdTe, a II-VI semiconductor compound with a wide range of uses in electrical and optical devices. At room temperature CdTe exhibits little plasticity and at the same time relatively low strength and hardness. The mechanical behavior of CdTe was examined at elevated temperatures with the goal of understanding plastic flow in this material and eventually improving the room temperature properties. Several samples of single crystal CdTe of identical size and crystallographic orientation were deformed in compression at 300°C to various levels of total strain. A resolved shear stress vs. compressive glide strain curve (Figure la) was derived from the results of the tests and the knowledge of the sample orientation.

USS TENELON

Alloy Digest ◽  
1975 ◽  
Vol 24 (5) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Elevated Temperatures ◽  
Stress Rupture ◽  
High Strength ◽  
Heat Treating ◽  
Creep Properties ◽  
United States Steel Corporation ◽  
Excellent Corrosion Resistance ◽  
Wide Range ◽  
Mild Acid

Abstract USS TENELON is a completely austenitic, nickel-free stainless steel with exceptionally high strength which is retained at elevated temperatures. It has excellent corrosion resistance in atmospheric and mild acid exposures and maintains nonmagnetic characteristics even when 60% cold reduced. It also has good stress-rupture and creep properties in the range 1200-1500 F. It has a wide range of applications. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as fracture toughness, creep, and fatigue. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: SS-311. Producer or source: United States Steel Corporation.

Structural and Magneto-Electric Properties of Pulsed Laser Deposited Ferroelectric/Ferromagnetic Heterostructure

2009 ◽  
Vol 1199 ◽  
Author(s):  
Ricardo Martinez ◽  
Ashok Kumar ◽  
Ratnakar Palai ◽  
Ram S. Katiyar
Keyword(s):  
Elevated Temperatures ◽  
High Strain ◽  
Ferroelectric Properties ◽  
Pulsed Laser ◽  
Ferromagnetic Behavior ◽  
Asymmetric Behavior ◽  
Normal Behavior ◽  
Wide Range ◽  
Capacitance Voltage ◽  
Voltage Relationship

AbstractAsymmetric superlattices (SLs) with ferromagnetic La0.7Sr0.3MnO3 (LSMO) and ferroelectric Ba0.7Sr0.3TiO3 (BST) as constitutive layers were fabricated on conducting LaNiO3 (LNO) coated (001) oriented MgO substrates using pulsed laser deposition (PLD). The crystallinity, ferroelectric and magnetic properties of the SLs were studied over a wide range of temperatures and frequencies. The structure exhibited ferromagnetic behavior at 300K, and ferroelectric behavior over a range of temperatures between 100K and 300K. The dielectric response as a function of frequency obeys normal behavior below 300 K, whereas it follows Maxwell–Wagner model at elevated temperatures. The effect of ferromagnetic LSMO layers on ferroelectric properties of the SL indicated strong influence of the interfaces. The asymmetric behavior of ferroelectric loop and the capacitance-voltage relationship suggest development of a built field in the SLs due to high strain across the interfaces.

scholarly journals Pressure gradient tailoring effects on the mechanisms of bluff-body flame extinction

2020 ◽  
Vol 215 ◽  
pp. 224-237 ◽  
Author(s):  
Anthony J. Morales ◽  
Jonathan Reyes ◽  
Peter H. Joo ◽  
Isaac Boxx ◽  
Kareem A. Ahmed
Keyword(s):  
Pressure Gradient ◽  
Bluff Body ◽  
Flame Extinction

scholarly journals Deformation of Ordered Mesoporous Silica Structures on Exposure to High Temperatures

2014 ◽  
Vol 2014 ◽  
pp. 1-13 ◽  
Author(s):  
John B. Lowe ◽  
Richard T. Baker
Keyword(s):  
Mesoporous Silica ◽  
Pore Structure ◽  
High Temperatures ◽  
Elevated Temperatures ◽  
Ordered Mesoporous Silica ◽  
Large Cage ◽  
Pore Structures ◽  
Ordered Mesoporous ◽  
Pore Size Distributions ◽  
Wide Range

Ordered mesoporous silica materials are of interest for a wide range of applications. In many of these, elevated temperatures are used either in the preparation of the material or during its use. Therefore, an understanding of the effect of high temperature treatments on these materials is desirable. In this work, a detailed structural study is performed on silicas with three representative pore structures: a 2-D hexagonal pore arrangement (SBA-15), a continuous 3D cubic bimodal pore structure (KIT-6), and a 3D large cage pore structure (FDU-12). Each silica is studied as prepared and after treatment at a series of temperatures between 300 and 900°C. Pore structures are imaged using Transmission Electron Microscopy. This technique is used in conjunction with Small-Angle X-ray Diffraction, gas physisorption, and29Si solid state Nuclear Magnetic Resonance. Using these techniques, the pore size distributions, the unit cell dimensions of the mesoporous structures, and the relative occupancy of the distinct chemical environments of Si within them are cross correlated for the three silicas and their evolution with treatment temperature is elucidated. The physical and chemical properties before, during, and after collapse of these structures at high temperatures are described as are the differences in behavior between the three silica structures.

Spectrophotometry of Aqueous HNO3, H2SO4, and DCIO4 from 25° to 250°C

1968 ◽  
Vol 22 (5) ◽  
pp. 545-548 ◽  
Author(s):  
W. C. Waggener ◽  
A. J. Weinberger ◽  
R. W. Stoughton
Keyword(s):  
Cell Wall ◽  
Corrosion Products ◽  
Spectral Measurements ◽  
Wide Range ◽  
General Program ◽  
Cell Window ◽  
Temperature And Pressure

Dilute nitric, sulfuric, and perchloric acids are applicable as solvents for spectrophotometry up to 250°C over the following ranges: 0 to 1.0 f HNO3 from 0.6 to 1.2 μ; 0 to 0.2 f H2SO4 from 0.25 to 1.2 μ; and 0 to 1.0 f DClO4 from 0.25 to 1.8 μ. Each of these acids reacts measurably with the titanium cell wall and the sapphire windows at rates which increase with acidity and temperature. This corrosion affects the spectral measurements as a function of time and is associated with deterioration of cell window surfaces and the presence in the sample of dissolved and suspended corrosion products. These results are part of our more general program for the development of equipment and technique for routine spectrophotometry of pure liquids and solutions over a wide range of temperature and pressure.

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