A Novel Indirect Visualization Method for Studying the Melting Heat Transfer of Nano-Enhanced Phase Change Materials Using Thermochromic Liquid Crystal Thermography

2020 ◽  
Vol 142 (4) ◽  
Author(s):  
Nan Hu ◽  
Zi-Rui Li ◽  
Run-Hui Zhang ◽  
Li-Wu Fan

Abstract In order to give more sights into the melting (and solidification) heat transfer processes of nano-enhanced phase change material (NePCM) with invisible phase interfaces, a novel indirect method for tracking the phase interface by thermochromic liquid crystal (TLC) thermography is proposed. As an example case to demonstrate the applicability of the proposed method, the classical problem of melting heat transfer in a differentially heated rectangular cavity was revisited in the presence of NePCM of various loadings. A narrowband TLC was selected and calibrated carefully to build the hue–temperature relationship prior to being applied in the melting experiments. For validation purpose, the case of an unloaded NePCM, with a clear visible phase interface, was tested via combined direct and indirect observations. It was shown that this TLC method can easily and accurately capture the dynamic motions of the phase interface during melting. Based on the shape evolutions of the phase interface, it was concluded that for the NePCM sample with a higher loading (and hence a much greater viscosity), heat conduction becomes the dominant mode of heat transfer during melting as a result of the significantly deteriorated natural convection effect. This gives an intuitive confirmation of the hypothesis made in previous studies that were conducted using volume-average-based indirect methods.

2020 ◽  
Vol 143 (1) ◽  
Author(s):  
Nan Hu ◽  
Zi-Rui Li ◽  
Run-Hui Zhang ◽  
Jia Liu ◽  
Li-Wu Fan

Abstract The constrained melting of nano-enhanced phase change materials (NePCM) in a horizontal cylindrical capsule was investigated via the utilization of thermochromic liquid crystal (TLC) technique for tracking the invisible phase interfaces. A parametric study was carried out by varying both the loading of NePCM (i.e., 0 wt %, 1 wt %, and 3 wt %) and the wall superheat (at 10 °C and 30 °C), leading to a total of six cases. Numerical simulations, based on the enthalpy-porosity method, were also performed to reveal the evolutions of temperature and convective flow fields during melting. It was first shown that the numerically predicted melting front evolutions are in good agreement with the TLC imaging results. A comparison among the six cases indicated that there is a similar melting pattern that heat conduction dominates the initial stage of melting and natural convection then takes over to play a more important role when melting proceeds. With the TLC-assisted reconstruction of the melting fronts, the instantaneous melting and heat storage rates were estimated, and melting was clearly found to slow down with increasing the loading of NePCM, as a result of the dramatically increased viscosity that deteriorates the contribution of natural convection to melting heat transfer.


2016 ◽  
Vol 138 (12) ◽  
Author(s):  
Li-Wu Fan ◽  
Zi-Qin Zhu ◽  
Min-Jie Liu ◽  
Can-Ling Xu ◽  
Yi Zeng ◽  
...  

The classical problem of constrained melting heat transfer of a phase change material (PCM) inside a spherical capsule was revisited experimentally in the presence of nanoscale thermal conductivity fillers. The model nano-enhanced PCM (NePCM) samples were prepared by dispersing self-synthesized graphite nanosheets (GNSs) into 1-dodecanol at various loadings up to 1% by mass. The melting experiments were carried out using an indirect method by measuring the instantaneous volume expansion upon melting. The data analysis was performed based on the homogeneous, single-component assumption for NePCM with modified thermophysical properties. It was shown that the introduction of nanofillers increases the effective thermal conductivity of NePCM, in accompaniment with an undesirable rise in viscosity. The dramatic viscosity growth, up to over 100-fold at the highest loading, deteriorates significantly the intensity of natural convection, which was identified as the dominant mode of heat transfer during constrained melting. The loss in natural convection was found to overweigh the decent enhancement in heat conduction, thus resulting in decelerated melting in the presence of nanofillers. Except for the case with the lowest heating boundary temperature, a monotonous slowing trend of melting was observed with increasing the loading.


Author(s):  
Yannan Liang ◽  
Jiemin Zhou ◽  
Ying Yang ◽  
Ye Wu ◽  
Yanyan He

The use of phase-change materials for latent heat storage is a new type of environmentally-friendly energy-saving technologies. Molten salts, one kind of phase-change materials, which have high latent heats, and whose phase transition temperatures match the high temperatures of heat engines, are the most widely used high-temperature phase-change heat storage materials. However, the heat transfer at solid/liquid phase interface belongs to Micro/Nanoscale Heat transfer, lots of the thermal properties of molten salt at melting point is difficult to test. In this investigation, based on the theory that the thermal conductivity can be determined by measuring the speed of the propagation of the solid/liquid phase interface during phase change, a set of system is developed to investigate the thermal conductivity of molten salts at liquid/solid phase transformation point. Meanwhile, mathematical calculation is applied to intuitively simulate the melting and solidifying process in the phase change chamber, by which the error could be analyzed and partly corrected and the result precision could also be increased. And a series of verification experiments have been performed to estimate the precision and the applicability of the measuring system to evaluate the feasibility of the method and measuring system. This research will pave the way to the follow-on research on heat storage at high temperature in industry.


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