scholarly journals Random Fiber Networks With Superior Properties Through Network Topology Control

2019 ◽  
Vol 86 (8) ◽  
Author(s):  
S. Deogekar ◽  
Z. Yan ◽  
R. C. Picu
Keyword(s):  
Network Architecture ◽  
Elastic Behavior ◽  
Fiber Networks ◽  
Linear Elastic ◽  
New Class ◽  
Link Density ◽  
Cross Link Density ◽  
Random Fiber Networks ◽  
Nonlinear Elastic ◽  
Poisson Contraction

In this work, we study the effect of network architecture on the nonlinear elastic behavior and strength of athermal random fiber networks of cellular type. We introduce a topology modification of Poisson–Voronoi (PV) networks with convex cells, leading to networks with stochastic nonconvex cells. Geometric measures are developed to characterize this new class of nonconvex Voronoi (NCV) networks. These are softer than the reference PV networks at the same nominal network parameters such as density, cross-link density, fiber diameter, and connectivity number. Their response is linear elastic over a broad range of strains, unlike PV networks that exhibit a gradual increase of the tangent stiffness starting from small strains. NCV networks exhibit much smaller Poisson contraction than any network of same nominal parameters. Interestingly, the strength of NCV networks increases continuously with an increasing degree of nonconvexity of the cells. These exceptional properties render this class of networks of interest in a variety of applications, such as tissue scaffolds, nonwovens, and protective clothing.

Influence of Elastic Nonlinearity on Arterial Anastomotic Compliance

1996 ◽  
Vol 118 (4) ◽  
pp. 445-451 ◽  
Author(s):  
G. S. Schajer ◽  
S. I. Green ◽  
A. P. Davis ◽  
Y. N.-H. Hsiang
Keyword(s):  
Structural Characteristics ◽  
Strain Curve ◽  
Elastic Compliance ◽  
Elastic Behavior ◽  
Wall Material ◽  
Arterial Diameter ◽  
Linear Elastic ◽  
Lower Strain ◽  
Highly Nonlinear ◽  
Nonlinear Elastic

This study illustrates how the highly nonlinear elastic behavior of artery wall material can cause unusual structural characteristics that do not occur with a linear-elastic material. An example mathematical model of an end-to-end anastomosis successfully predicts the experimentally observed area of elevated elastic compliance, called the “Para-anastomotic Hypercompliant Zone” (PHZ). The elastic hypercompliance is shown to occur because the anastomosis locally restricts the arterial diameter, thus forcing the adjacent material to remain in a lower strain, and correspondingly a lower stiffness, part of its non-linear stress-strain curve. Elevated elastic compliance can be avoided by locally matching both the arterial diameter and the elastic compliance within the physiological pressure range.

Effect of Network Architecture on the Mechanical Behavior of Random Fiber Networks

2018 ◽  
Vol 85 (8) ◽  
Author(s):  
M. R. Islam ◽  
R. C. Picu
Keyword(s):  
Network Architecture ◽  
Large Strain ◽  
Small Strain ◽  
Structural Disorder ◽  
Global Parameter ◽  
Fiber Networks ◽  
Tension And Compression ◽  
Cross Links ◽  
Random Fiber Networks

Fiber-based materials are prevalent around us. While microscopically these systems resemble a discrete assembly of randomly interconnected fibers, the network architecture varies from one system to another. To identify the role of the network architecture, we study here cellular and fibrous random networks in tension and compression, and in the context of large strain elasticity. We observe that, compared to cellular networks of same global parameter set, fibrous networks exhibit in tension reduced strain stiffening, reduced fiber alignment, and reduced Poisson's contraction in uniaxial tension. These effects are due to the larger number of kinematic constraints in the form of cross-links per fiber in the fibrous case. The dependence of the small strain modulus on network density is cubic in the fibrous case and quadratic in the cellular case. This difference persists when the number of cross-links per fiber in the fibrous case is rendered equal to that of the cellular case, which indicates that the different scaling is due to the higher structural disorder of the fibrous networks. The behavior of the two network types in compression is similar, although softening induced by fiber buckling and strain localization is less pronounced in the fibrous case. The contribution of transient interfiber contacts is weak in tension and important in compression.

Boron nitride for modification of rubber based on isoprene elastomer

2020 ◽  
pp. 105-112
Author(s):  
K. S. Zhansakova ◽  
E. N. Eremin ◽  
G. S. Russkikh ◽  
O. V. Kropotin
Keyword(s):  
Mechanical Properties ◽  
Boron Nitride ◽  
Gradual Increase ◽  
Physical And Mechanical Properties ◽  
Curing Time ◽  
Cross Link ◽  
Start Time ◽  
Link Density ◽  
Cross Link Density ◽  
Isoprene Rubber

The work studies vulcanization characteristics of elastomers based on isoprene rubber filled with carbon black N330 and boron nitride (BN). The influence of the boron nitride (BN) concentration on technological, dynamic, physical and mechanical properties of elastomers has been researched. The application of boron nitride for producing rubber with good properties has been considered. With a gradual increase of the inert filler BN concentration up to 35%, a decrease in the curing rate by 33% and polymer cross-link density by 26% is observed. Moreover, the start time of vulcanization increases by almost 300%, the optimal curing time by 200%.

Mechanical and structural consequences of associative dynamic cross-linking in acrylic diblock copolymers

2021 ◽  
Author(s):  
Jacob Ishibashi ◽  
Ian Pierce ◽  
Alice Chang ◽  
Aristotelis Zografos ◽  
Bassil El-Zaatari ◽  
...  
Keyword(s):  
Viscoelastic Properties ◽  
Diblock Copolymers ◽  
Microphase Separation ◽  
Network Connectivity ◽  
Ethyl Acrylate ◽  
Cross Linking ◽  
Cross Link ◽  
Block Polymers ◽  
Link Density ◽  
Cross Link Density

<p>The composition of low-T<sub>g</sub> <i>n</i>-butylacrylate-<i>block</i>-(acetoxyaceto)ethyl acrylate block polymers is investigated as a strategy to tune the properties of dynamically cross-linked vinylogous urethane vitrimers. As the proportion of the cross-linkable block is increased, the thermorheological properties, structure, and stress relaxation evolve in ways that cannot be explained by increasing cross-link density alone. Evidence is presented that network connectivity defects such as loops and dangling ends are increased by microphase separation. The thermomechanical and viscoelastic properties of block copolymer-derived vitrimers arise from the subtle interplay of microphase separation and network defects.</p><div><br></div><p></p>

Performance Based Evaluation of Bridge Substructure in North Mississippi Using Nonlinear FEM and Field Vibration Measurement

2000 ◽  
Author(s):  
Chris L. Mullen ◽  
Prabin R. Tuladhar
Keyword(s):  
Finite Element ◽  
Transfer Functions ◽  
Response Spectrum ◽  
Three Dimensional ◽  
Vibration Measurement ◽  
Elastic Behavior ◽  
Evaluation Procedure ◽  
Vibration Measurements ◽  
Linear Elastic ◽  
Performance Based Evaluation

Abstract Discussion of a Performance - Based Engineering evaluation procedure for an existing interstate highway bridge in north Mississippi. The bridge is in a highly trafficked location near the Memphis Metropolitan area and is reflective of modern design practices in Mississippi. Results are presented of nonlinear damage response and displacement ductility performance of the reinforced concrete bents and their foundations predicted using static finite element (FE) computations. The model considers the composite action of the concrete and the reinforcing steel materials under axial force, shear, torsion and flexure. The performance-based evaluation includes three-dimensional computational simulations of the nonlinear bridge system, including substructures and superstructure. The response spectrum dynamic analysis method will also be carried out on the linear elastic three-dimensional model to predict the linear elastic behavior. Field vibration measurements, including ambient and hammer-impact, were performed to calibrate the models. The computed transfer functions are currently being evaluated to correlate vibration measurements and the Finite element models.

Mechanical behavior of poly(methyl methacrylate)-based ionogels

Soft Matter ◽  
2014 ◽  
Vol 10 (40) ◽  
pp. 7993-8000 ◽  
Author(s):  
Mingyu Li ◽  
Jianyu Li ◽  
Hui Na ◽  
Joost J. Vlassak
Keyword(s):  
Methyl Methacrylate ◽  
Mechanical Behavior ◽  
Fracture Energy ◽  
Cross Link ◽  
Poly Methyl Methacrylate ◽  
Link Density ◽  
Cross Link Density ◽  
The Cross ◽  
The Ideal

We demonstrate that the fracture energy of ionogels correlates inversely with the cross-link density. The behavior of ionogels is well captured by the ideal elastomeric gel model.

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