Effect of Impurities on Compressor and Cooler in Supercritical CO2 Cycles

2018 ◽  
Vol 141 (1) ◽  
Author(s):  
Ladislav Vesely ◽  
K. R. V. Manikantachari ◽  
Subith Vasu ◽  
Jayanta Kapat ◽  
Vaclav Dostal ◽  
...  

With the increasing demand for electric power, the development of new power generation technologies is gaining increased attention. The supercritical carbon dioxide (S-CO2) cycle is one such technology, which has relatively high efficiency, compactness, and potentially could provide complete carbon capture. The S-CO2 cycle technology is adaptable for almost all of the existing heat sources such as solar, geothermal, fossil, nuclear power plants, and waste heat recovery systems. However, it is known that optimal combinations of operating conditions, equipment, working fluid, and cycle layout determine the maximum achievable efficiency of a cycle. Within an S-CO2 cycle, the compression device is of critical importance as it is operating near the critical point of CO2. However, near the critical point, the thermo-physical properties of CO2 are highly sensitive to changes of pressure and temperature. Therefore, the conditions of CO2 at the compressor inlet are critical in the design of such cycles. Also, the impurity species diluted within the S-CO2 will cause deviation from an ideal S-CO2 cycle as these impurities will change the thermodynamic properties of the working fluid. Accordingly, the current work examines the effects of different impurity compositions, considering binary mixtures of CO2 and He, CO, O2, N2, H2, CH4, or H2S on various S-CO2 cycle components. The second part of the study focuses on the calculation of the basic cycles and component efficiencies. The results of this study will provide guidance and define the optimal composition of mixtures for compressors and coolers.

Author(s):  
Ladislav Vesely ◽  
K. R. V. Manikantachari ◽  
Subith Vasu ◽  
Jayanta Kapat ◽  
Vaclav Dostal ◽  
...  

With the increasing demand for electric power, the development of new power generation technologies is gaining increased attention. The supercritical carbon dioxide (S-CO2) cycle is one such technology, which has relatively high efficiency, compactness, and potentially could provide complete carbon capture. The S-CO2 cycle technology is adaptable for almost all of the existing heat sources such as solar, geothermal, fossil, nuclear power plants, and waste heat recovery systems. However, it is known that, optimal combinations of: operating conditions, equipment, working fluid, and cycle layout determine the maximum achievable efficiency of a cycle. Within an S-CO2 cycle the compression device is of critical importance as it is operating near the critical point of CO2. However, near the critical point, the thermo-physical properties of CO2 are highly sensitive to changes of pressure and temperature. Therefore, the conditions of CO2 at the compressor inlet are critical in the design of such cycles. Also, the impurity species diluted within the S-CO2 will cause deviation from an ideal S-CO2 cycle as these impurities will change the thermodynamic properties of the working fluid. Accordingly the current work examines the effects of different impurity compositions, considering binary mixtures of CO2 and: He, CO, O2, N2, H2, CH4, or H2S; on various S-CO2 cycle components. The second part of the study focuses on the calculation of the basic cycles and component efficiencies. The results of this study will provide guidance and defines the optimal composition of mixtures for compressors and coolers.


Author(s):  
Rene Pecnik ◽  
Enrico Rinaldi ◽  
Piero Colonna

The merit of using supercritical CO2 (scCO2) as the working fluid of a closed Brayton cycle gas turbine is now widely recognized, and the development of this technology is now actively pursued. scCO2 gas turbine power plants are an attractive option for solar, geothermal and nuclear energy conversion. Among the challenges which must be overcome in order to successfully bring the technology to the market, the efficiency of the compressor and turbine operating with the supercritical fluid should be increased as much as possible. High efficiency can be reached by means of sophisticated aerodynamic design, which, compared to other overall efficiency improvements, like cycle maximum pressure and temperature increase, or increase of recuperator effectiveness, does not require an increase in equipment cost, but only an additional effort in research and development. This paper reports a three-dimensional CFD study of a high-speed centrifugal compressor operating with CO2 in the thermodynamic region slightly above the vapor-liquid critical point. The investigated geometry is the compressor impeller tested in the Sandia scCO2 compression loop facility [1]. The fluid dynamic simulations are performed with a fully implicit parallel Reynolds-averaged Navier-Stokes code based on a finite volume formulation on arbitrary polyhedral mesh elements. The CFD code has been validated on test cases which are relevant for this study, see Ref. [2,3]. In order to account for the strongly nonlinear variation of the thermophysical properties of supercritical CO2, the CFD code is coupled with an extensive library for the computation of properties of fluids and mixtures [4]. Among the available models, the one based on reference equations of state for CO2 [5,6] has been selected, as implemented in one of the sub-libraries [7]. A specialized look-up table approach and a meshing technique suited for turbomachinery geometries are also among the novelties introduced in the developed methodology. A detailed evaluation of the CFD results highlights the challenges of numerical studies aimed at the simulation of technically relevant compressible flows occurring close to the liquid-vapor critical point. The data of the obtained flow field are used for a comparison with experiments performed at the Sandia scCO2 compression-loop facility.


Author(s):  
Alireza Ameli ◽  
Ali Afzalifar ◽  
Teemu Turunen-Saaresti ◽  
Jari Backman

Rankine and Brayton cycles are common energy conversion cycles and constitute the basis of a significant proportion of global electricity production. Even a seemingly marginal improvement in the efficiency of these cycles can considerably decrease the annual use of primary energy sources and bring a significant gain in power plant output. Recently, supercritical Brayton cycles using CO2 as the working fluid have attracted much attention, chiefly due to their high efficiency. As with conventional cycles, improving the compressor performance in supercritical cycles is major route to increasing the efficiency of the whole process. This paper numerically investigates the flow field and performance of a supercritical CO2 centrifugal compressor. A thermodynamic look-up table is coupled with the flow solver, and the look-up table is systematically refined to take into account the large variation of thermodynamic properties in the vicinity of the critical point. Effects of different boundary and operating conditions are also discussed. It is shown that the compressor performance is highly sensitive to the look-up table resolution as well as the operating and boundary conditions near the critical point. Additionally, a method to overcome the difficulties of simulation close to the critical point is explained.


Author(s):  
Alireza Ameli ◽  
Ali Afzalifar ◽  
Teemu Turunen-Saaresti ◽  
Jari Backman

Rankine and Brayton cycles are common energy conversion cycles and constitute the basis of a significant proportion of global electricity production. Even a seemingly marginal improvement in the efficiency of these cycles can considerably decrease the annual use of primary energy sources and bring a significant gain in power plant output. Recently, supercritical Brayton cycles using CO2 as the working fluid have attracted much attention, chiefly due to their high efficiency. As with conventional cycles, improving the compressor performance in supercritical cycles is major route to increasing the efficiency of the whole process. This paper numerically investigates the flow field and performance of a supercritical CO2 centrifugal compressor. A thermodynamic look-up table is coupled with the flow solver and the look-up table is systematically refined to take into account the large variation of thermodynamic properties in the vicinity of the critical point. Effects of different boundary and operating conditions are also discussed. It is shown that the compressor performance is highly sensitive to the look-up table resolution as well as the operating and boundary conditions near the critical point. Additionally, a method to overcome the difficulties of simulation close to the critical point is explained.


Author(s):  
Rene Pecnik ◽  
Enrico Rinaldi ◽  
Piero Colonna

The merit of using supercritical CO2(scCO2) as the working fluid of a closed Brayton cycle gas turbine is now widely recognized, and the development of this technology is now actively pursued. scCO2 gas turbine power plants are an attractive option for solar, geothermal, and nuclear energy conversion. Among the challenges that must be overcome in order to successfully bring the technology to the market is that the efficiency of the compressor and turbine operating with the supercritical fluid should be increased as much as possible. High efficiency can be reached by means of sophisticated aerodynamic design, which, compared to other overall efficiency improvements, like cycle maximum pressure and temperature increase, or increase of recuperator effectiveness, does not require an increase in equipment cost, but only an additional effort in research and development. This paper reports a three-dimensional computational fluid dynamics (CFD) study of a high-speed centrifugal compressor operating with CO2 in the thermodynamic region slightly above the vapor–liquid critical point. The investigated geometry is the compressor impeller tested in the Sandia scCO2 compression loop facility. The fluid dynamic simulations are performed with a fully implicit parallel Reynolds-averaged Navier–Stokes code based on a finite volume formulation on arbitrary polyhedral mesh elements. In order to account for the strongly nonlinear variation of the thermophysical properties of supercritical CO2, the CFD code is coupled with an extensive library for the computation of properties of fluids and mixtures. A specialized look-up table approach and a meshing technique suited for turbomachinery geometries are also among the novelties introduced in the developed methodology. A detailed evaluation of the CFD results highlights the challenges of numerical studies aimed at the simulation of technically relevant compressible flows occurring close to the liquid–vapor critical point. The data of the obtained flow field are used for a comparison with experiments performed at the Sandia scCO2 compression-loop facility.


2019 ◽  
Vol 13 ◽  
Author(s):  
Haisheng Li ◽  
Wenping Wang ◽  
Yinghua Chen ◽  
Xinxi Zhang ◽  
Chaoyong Li

Background: The fly ash produced by coal-fired power plants is an industrial waste. The environmental pollution problems caused by fly ash have been widely of public environmental concern. As a waste of recoverable resources, it can be used in the field of building materials, agricultural fertilizers, environmental materials, new materials, etc. Unburned carbon content in fly ash has an influence on the performance of resource reuse products. Therefore, it is the key to remove unburned carbon from fly ash. As a physical method, triboelectrostatic separation technology has been widely used because of obvious advantages, such as high-efficiency, simple process, high reliability, without water resources consumption and secondary pollution. Objective: The related patents of fly ash triboelectrostatic separation had been reviewed. The structural characteristics and working principle of these patents are analyzed in detail. The results can provide some meaningful references for the improvement of separation efficiency and optimal design. Methods: Based on the comparative analysis for the latest patents related to fly ash triboelectrostatic separation, the future development is presented. Results: The patents focused on the charging efficiency and separation efficiency. Studies show that remarkable improvements have been achieved for the fly ash triboelectrostatic separation. Some patents have been used in industrial production. Conclusion: According to the current technology status, the researches related to process optimization and anti-interference ability will be beneficial to overcome the influence of operating conditions and complex environment, and meet system security requirements. The intelligent control can not only ensure the process continuity and stability, but also realize the efficient operation and management automatically. Meanwhile, the researchers should pay more attention to the resource utilization of fly ash processed by triboelectrostatic separation.


2021 ◽  
Vol 11 (5) ◽  
pp. 1984
Author(s):  
Ramin Moradi ◽  
Emanuele Habib ◽  
Enrico Bocci ◽  
Luca Cioccolanti

Organic Rankine cycle (ORC) systems are some of the most suitable technologies to produce electricity from low-temperature waste heat. In this study, a non-regenerative, micro-scale ORC system was tested in off-design conditions using R134a as the working fluid. The experimental data were then used to tune the semi-empirical models of the main components of the system. Eventually, the models were used in a component-oriented system solver to map the system electric performance at varying operating conditions. The analysis highlighted the non-negligible impact of the plunger pump on the system performance Indeed, the experimental results showed that the low pump efficiency in the investigated operating range can lead to negative net electric power in some working conditions. For most data points, the expander and the pump isentropic efficiencies are found in the approximate ranges of 35% to 55% and 17% to 34%, respectively. Furthermore, the maximum net electric power was about 200 W with a net electric efficiency of about 1.2%, thus also stressing the importance of a proper selection of the pump for waste heat recovery applications.


Author(s):  
Graeme G. King ◽  
Satish Kumar

Masdar is developing several carbon capture projects from power plants, smelters, steel works, industrial facilities and oil and gas processing plants in Abu Dhabi in a phased series of projects. Captured CO2 will be transported in a new national CO2 pipeline network with a nominal capacity of 20×106 T/y to oil reservoirs where it will be injected for reservoir management and sequestration. Design of the pipeline network considered three primary factors in the selection of wall thickness and toughness, (a) steady and transient operating conditions, (b) prevention of longitudinal ductile fractures and (c) optimization of total project owning and operating costs. The paper explains how the three factors affect wall thickness and toughness. It sets out code requirements that must be satisfied when choosing wall thickness and gives details of how to calculate toughness to prevent propagation of long ductile fracture in CO2 pipelines. It then uses cost optimization to resolve contention between the different requirements and arrive at a safe and economical pipeline design. The design work selected a design pressure of 24.5 MPa, well above the critical point for CO2 and much higher than is normally seen in conventional oil and gas pipelines. Despite its high operating pressure, the proposed network will be one of the safest pipeline systems in the world today.


Author(s):  
Noman Yousuf ◽  
Timothy Anderson ◽  
Roy Nates

Abstract Despite being identified nearly a century ago, the diffusion absorption refrigeration (DAR) cycle has received relatively little attention. One of the strongest attractions of the DAR cycle lies in the fact that it is thermally driven and does not require high value work. This makes it a prime candidate for harnessing low grade heat from solar collectors, or the waste heat from stationary generators, to produce cooling. However, to realize the benefits of the DAR cycle, there is a need to develop an improved understanding of how design parameters influence its performance. In this vein, this work developed a new parametric model that can be used to examine the performance of the DAR cycle for a range of operating conditions. The results showed that the cycle's performance was particularly sensitive to several factors: the rate of heat added and the temperature of the generator, the effectiveness of the gas and solution heat exchangers, the mass flowrate of the refrigerant and the type of the working fluid. It was shown that can deliver good performance at low generator temperatures if the refrigerant mass fraction in the strong solution is made as high as possible. Moreover, it was shown that a H2O-LiBr working pair could be useful for achieving cooling at low generator temperatures.


2003 ◽  
Vol 125 (2) ◽  
pp. 223-229 ◽  
Author(s):  
Gunnar Tamm ◽  
D. Yogi Goswami

A combined thermal power and cooling cycle proposed by Goswami is under intensive investigation, both theoretically and experimentally. The proposed cycle combines the Rankine and absorption refrigeration cycles, producing refrigeration while power is the primary goal. A binary ammonia-water mixture is used as the working fluid. This cycle can be used as a bottoming cycle using waste heat from a conventional power cycle or as an independent cycle using low temperature sources such as geothermal and solar energy. An experimental system was constructed to demonstrate the feasibility of the cycle and to compare the experimental results with the theoretical simulation. Results showed that the vapor generation and absorption condensation processes work experimentally, exhibiting expected trends, but with deviations from ideal and equilibrium modeling. The potential for combined turbine work and refrigeration output was evidenced in operating the system. Analysis of losses showed where improvements could be made, in preparation for further testing over a broader range of operating conditions.


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