Effect of CO2 on Heavy Oil Recovery and Physical Properties in Huff-n-Puff Processes Under Reservoir Conditions

2018 ◽  
Vol 140 (7) ◽  
Author(s):  
Songyan Li ◽  
Binfei Li ◽  
Qiliang Zhang ◽  
Zhaomin Li ◽  
Daoyong Yang

In this paper, experimental and numerical techniques have been utilized to quantify heavy oil properties in CO2 huff-n-puff processes under reservoir conditions. Experimentally, fluid properties together with viscosity reduction of heavy oil and interfacial properties between CO2 and heavy oil have been quantified, while five cycles of CO2 huff-n-puff processes have been conducted to determine oil recovery together with component variation of produced and residual oils. Theoretically, numerical simulation has been conducted to analyze the underlying recovery mechanisms associated with the CO2 huff-n-puff processes. CO2 huff-n-puff processes are only effective in the first two cycles under the existing experimental conditions, while the effective sweep range is limited near the wellbore region, resulting in poor oil recovery in the subsequent cycles. As for produced oil, its viscosity, density, resin and asphaltene contents, and molecular weight of asphaltene are reduced, whereas, for the residual oil, they are increased. The asphaltene component in the residual oil shows weak stability compared to that of the produced oil, while the ultimate oil recovery after the fifth CO2 cycle of huff-n-huff processes is measured to be 31.56%.

2021 ◽  
Author(s):  
Randy Agra Pratama ◽  
Tayfun Babadagli

Abstract Our previous research, honoring interfacial properties, revealed that the wettability state is predominantly caused by phase change—transforming liquid phase to steam phase—with the potential to affect the recovery performance of heavy-oil. Mainly, the system was able to maintain its water-wetness in the liquid (hot-water) phase but attained a completely and irrevocably oil-wet state after the steam injection process. Although a more favorable water-wetness was presented at the hot-water condition, the heavy-oil recovery process was challenging due to the mobility contrast between heavy-oil and water. Correspondingly, we substantiated that the use of thermally stable chemicals, including alkalis, ionic liquids, solvents, and nanofluids, could propitiously restore the irreversible wettability. Phase distribution/residual oil behavior in porous media through micromodel study is essential to validate the effect of wettability on heavy-oil recovery. Two types of heavy-oils (450 cP and 111,600 cP at 25oC) were used in glass bead micromodels at steam temperatures up to 200oC. Initially, the glass bead micromodels were saturated with synthesized formation water and then displaced by heavy-oils. This process was done to exemplify the original fluid saturation in the reservoirs. In investigating the phase change effect on residual oil saturation in porous media, hot-water was injected continuously into the micromodel (3 pore volumes injected or PVI). The process was then followed by steam injection generated by escalating the temperature to steam temperature and maintaining a pressure lower than saturation pressure. Subsequently, the previously selected chemical additives were injected into the micromodel as a tertiary recovery application to further evaluate their performance in improving the wettability, residual oil, and heavy-oil recovery at both hot-water and steam conditions. We observed that phase change—in addition to the capillary forces—was substantial in affecting both the phase distribution/residual oil in the porous media and wettability state. A more oil-wet state was evidenced in the steam case rather than in the liquid (hot-water) case. Despite the conditions, auspicious wettability alteration was achievable with thermally stable surfactants, nanofluids, water-soluble solvent (DME), and switchable-hydrophilicity tertiary amines (SHTA)—improving the capillary number. The residual oil in the porous media yielded after injections could be favorably improved post-chemicals injection; for example, in the case of DME. This favorable improvement was also confirmed by the contact angle and surface tension measurements in the heavy-oil/quartz/steam system. Additionally, more than 80% of the remaining oil was recovered after adding this chemical to steam. Analyses of wettability alteration and phase distribution/residual oil in the porous media through micromodel visualization on thermal applications present valuable perspectives in the phase entrapment mechanism and the performance of heavy-oil recovery. This research also provides evidence and validations for tertiary recovery beneficial to mature fields under steam applications.


SPE Journal ◽  
2021 ◽  
pp. 1-20
Author(s):  
Yaoze Cheng ◽  
Yin Zhang ◽  
Abhijit Dandekar ◽  
Jiawei Li

Summary Shallow reservoirs on the Alaska North Slope (ANS), such as Ugnu and West Sak-Schrader Bluff, hold approximately 12 to 17 × 109 barrels of viscous oil. Because of the proximity of these reservoirs to the permafrost, feasible nonthermal enhanced oil recovery (EOR) methods are highly needed to exploit these oil resources. This study proposes three hybrid nonthermal EOR techniques, including high-salinity water (HSW) injection sequentially followed by low-salinity water (LSW) and low-salinity polymer (LSP) flooding (HSW-LSW-LSP), solvent-alternating-LSW flooding, and solvent-alternating-LSP flooding, to recover ANS viscous oils. The oil recovery performance of these hybrid EOR techniques has been evaluated by conducting coreflooding experiments. Additionally, constant composition expansion (CCE) tests, ζ potential determinations, and interfacial tension (IFT) measurements have been conducted to reveal the EOR mechanisms of the three proposed hybrid EOR techniques. Coreflooding experiments and IFT measurements have been conducted at reservoir conditions of 1,500 psi and 85°F, while CCE tests have been carried out at a reservoir temperature of 85°F. ζ potential determinations have been conducted at 14.7 psi and 77°F. The coreflooding experiment results have demonstrated that all of the three proposed hybrid EOR techniques could result in much better performance in reducing residual oil saturation than waterflooding and continuous solvent flooding in viscous oil reservoirs on ANS, implying better oil recovery potential. In particular, severe formation damage or blockage at the production end occurred when natural sand was used to prepare the sandpack column, indicating that the natural sand may have introduced some unknown constituents that may react with the injected solvent and polymer, resulting in a severe blocking issue. Our investigation on this is ongoing, and more detailed studies are being conducted in our laboratory. The CCE test results demonstrate that more solvent could be dissolved into the tested viscous oil with increasing pressure, simultaneously resulting in more oil swelling and viscosity reduction. At the desired reservoir conditions of 1,500 psi and 85°F, as much as 60 mol% of solvent could be dissolved into the ANS viscous oil, resulting in more than 31% oil swelling and 97% oil viscosity reduction. Thus, the obvious oil swelling and significant viscosity reduction resulting from solvent injection could lead to much better microscopic displacement efficiency during the solvent flooding. The ζ potential determination results illustrate that LSW resulted in more negative ζ potential than HSW on the interface between sand and water, indicating that lowering the salinity of injected brine could result in the sand surface being more water-wet, but adding polymer to the LSW could not further enhance the water wetness. The IFT measurement results show that the IFT between the tested ANS viscous oil and LSW is higher than that between the tested viscous oil and HSW, which conflicts with the commonly recognized IFT reduction effect by LSW flooding. Thus, the EOR theory of the LSW flooding in our proposed hybrid techniques may be attributed to low-salinity effects (LSEs) such as multi-ion exchange, expansion of electrical double layer, and salting-in effect, while water wetness enhancement may benefit the LSW flooding process to some extent. The LSP’s viscosity is much higher than the viscosities of LSW and solvent, so LSP injection could result in better mobility control in the tested viscous oil reservoirs, leading to improvement of macroscopic sweep efficiency. Combining these EOR theories, the proposed hybrid EOR techniques have the potential to significantly increase oil recovery in viscous oil reservoirs on ANS by maximizing the overall displacement efficiency.


SPE Journal ◽  
2021 ◽  
pp. 1-20
Author(s):  
Seunghwan Baek ◽  
I. Yucel Akkutlu

Summary Organic matters in source rocks store oil in significantly larger volume than that based on its pore volume (PV) due to so-called nanoconfinement effects. With pressure depletion and production, however, oil recovery is characteristically low because of the low compressibility of the fluid and amplified interaction with pore surface in the nanoporous material. For the additional recovery, CO2 injection has been widely adopted in shale gas and tight oil recovery over the last decades. But its supply and corrosion are often pointed out as drawbacks. In this study, we propose ethane injection as an alternative enhanced oil recovery (EOR) strategy for more productive oil production from tight unconventional reservoirs. Monte Carlo (MC) molecular simulation is used to reconstruct molecular configuration in pores under reservoir conditions. Further, molecular dynamics (MD) simulation provides the basis for understanding the recovery mechanism of in-situ fluids. These enable us to estimate thermodynamic recovery and the free energy associated with dissolution of injected gas. Primary oil recovery is typically below 15%, indicating that pressure depletion and fluid expansion are no longer effective recovery mechanisms. Ethane injection shows 5 to 20% higher recovery enhancement than CO2 injection. The superior performance is more pronounced, especially in nanopores, because oil in the smaller pores is richer in heavy components compared to the bulk fluids, and ethane molecules are more effective in displacing the heavy hydrocarbons. Analysis of the dissolution free energy confirms that introducing ethane into reservoirs is more favored and requires less energy for the enhanced recovery.


SPE Journal ◽  
2019 ◽  
Vol 24 (06) ◽  
pp. 2889-2910 ◽  
Author(s):  
Pål Østebø Andersen ◽  
Dhruvit Satishchandra Berawala

Summary Numerical and analytical 1D solutions are presented to interpret the link between geochemical alterations and creep compaction (compaction under constant effective stress) in chalk cores. Chemically reactive flow enhancing chalk compaction is of significant importance for enhanced oil recovery (EOR), compaction, and subsidence in North Sea chalk reservoirs. The focus of this study is on Ca-, Mg-, and NaCl brines that interact with the chalk by the dissolution of calcite and the precipitation of magnesite. An explicit analytical solution is derived for the steady–state ion and dissolution–rate distributions at a given injected composition and injection rate. A mathematical description of creep compaction is proposed on the basis of applied affective stresses and rock ability to carry these stresses as a function of porosity. The reaction and compaction models are then coupled as follows: The compaction rate is assumed, which is enhanced by the dissolution rate, which can vary spatially. Furthermore, the solid volume changes by mineral dissolution and precipitation. Brine–dependent and nonuniform compaction is hence built into the model by means of the dissolution–rate distribution. The model is validated and parameterized against data from a total of 22 core samples from two chalk types (Åalborg and Liege) where reactive and inert brines were injected from ambient to Ekofisk–reservoir conditions (130°C). Experimentally measured effluent concentrations, distributions in mineralogy after flooding, and creep–compaction behavior were matched. Our model is the first to link a vast set of data on this subject and predict performance under new experimental conditions. This also represents a first step in upscaling such results from the laboratory toward the field. Our interpretations indicate that the two chalk types would respond differently chemically and by compaction to changes in the concentration and injection rate. Brines injected through Liege chalk appeared to approach stable oversaturation, while in Åalborg, the equilibrium condition was in agreement with geochemical calculations.


SPE Journal ◽  
2019 ◽  
Vol 24 (02) ◽  
pp. 413-430
Author(s):  
Zhanxi Pang ◽  
Lei Wang ◽  
Zhengbin Wu ◽  
Xue Wang

Summary Steam-assisted gravity drainage (SAGD) and steam and gas push (SAGP) are used commercially to recover bitumen from oil sands, but for thin heavy-oil reservoirs, the recovery is lower because of larger heat losses through caprock and poorer oil mobility under reservoir conditions. A new enhanced-oil-recovery (EOR) method, expanding-solvent SAGP (ES-SAGP), is introduced to develop thin heavy-oil reservoirs. In ES-SAGP, noncondensate gas and vaporizable solvent are injected with steam into the steam chamber during SAGD. We used a 3D physical simulation scale to research the effectiveness of ES-SAGP and to analyze the propagation mechanisms of the steam chamber during ES-SAGP. Under the same experimental conditions, we conducted a contrast analysis between SAGP and ES-SAGP to study the expanding characteristics of the steam chamber, the sweep efficiency of the steam chamber, and the ultimate oil recovery. The experimental results show that the steam chamber gradually becomes an ellipse shape during SAGP. However, during ES-SAGP, noncondensate gas and a vaporizable solvent gather at the reservoir top to decrease heat losses, and oil viscosity near the condensate layer of the steam chamber is largely decreased by hot steam and by solvent, making the boundary of the steam chamber vertical and gradually a similar, rectangular shape. As in SAGD, during ES-SAGP, the expansion mechanism of the steam chamber can be divided into three stages: the ascent stage, the horizontal-expansion stage, and the descent stage. In the ascent stage, the time needed is shorter during ES-SAGP than during SAGP. However, the other two stages take more time during nitrogen, solvent, and steam injection to enlarge the cross-sectional area of the bottom of the steam chamber. For the conditions in our experiments, when the instantaneous oil/steam ratio is lower than 0.1, the corresponding oil recovery is 51.11%, which is 7.04% higher than in SAGP. Therefore, during ES-SAGP, not only is the volume of the steam chamber sharply enlarged, but the sweep efficiency and the ultimate oil recovery are also remarkably improved.


Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 983 ◽  
Author(s):  
Pablo Druetta ◽  
Francesco Picchioni

Chemical Enhanced Oil Recovery (cEOR) processes comprise a number of techniques whichmodify the rock/fluid properties in order to mobilize the remaining oil. Among these, surfactantflooding is one of the most used and well-known processes; it is mainly used to decrease the interfacialenergy between the phases and thus lowering the residual oil saturation. A novel two-dimensionalflooding simulator is presented for a four-component (water, petroleum, surfactant, salt), two-phase(aqueous, oleous) model in porous media. The system is then solved using a second-order finitedifference method with the IMPEC (IMplicit Pressure and Explicit Concentration) scheme. The oilrecovery efficiency evidenced a strong dependency on the chemical component properties and itsphase behaviour. In order to accurately model the latter, the simulator uses and improves a simplifiedternary diagram, introducing the dependence of the partition coefficient on the salt concentration.Results showed that the surfactant partitioning between the phases is the most important parameterduring the EOR process. Moreover, the presence of salt affects this partitioning coefficient, modifyingconsiderably the sweeping efficiency. Therefore, the control of the salinity in the injection water isdeemed fundamental for the success of EOR operations with surfactants.


2012 ◽  
Vol 268-270 ◽  
pp. 547-550
Author(s):  
Qing Wang Liu ◽  
Xin Wang ◽  
Zhen Zhong Fan ◽  
Jiao Wang ◽  
Rui Gao ◽  
...  

Liaohe oil field block 58 for Huancai, the efficiency of production of thickened oil is low, and the efficiency of displacement is worse, likely to cause other issues. Researching and developing an type of Heavy Oil Viscosity Reducer for exploiting. The high viscosity of W/O emulsion changed into low viscosity O/W emulsion to facilitate recovery, enhanced oil recovery. Through the experiment determine the viscosity properties of Heavy Oil Viscosity Reducer. The oil/water interfacial tension is lower than 0.0031mN•m-1, salt-resisting is good. The efficiency of viscosity reduction is higher than 90%, and also good at 180°C.


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