Nonlinear Modeling and Experimental Analysis of Vertically Aligned Carbon Nanotube Pads Under Uniaxial Compressive Loading

Author(s):  
Nicholas Candelino ◽  
Nader Jalili

There have been a variety of attempts to model the quasi-static and high energy impact dynamics of vertically aligned carbon nanotube (VACNT) pads. However, very little work has focused on identifying the behavior at the midlevel frequencies that may occur in materials handling or vibration suppression applications. Moreover, the existing models are predominantly very complex, and yet provide only a very rough approximation of the bulk behavior. While several of the existing models make attempts at ascribing physical relevance, an adequate first principles approach has yet to be demonstrated. In this work, a close-fitting continuous model of these midfrequency dynamics is developed utilizing a combination of phenomenological- and identification-based methodologies. First, a set of specially fabricated carbon nanotube pads are preconditioned and subjected to various position-controlled compression experiments. The measured position and force responses are used to develop load–displacement curves, from which several characteristic features are identified. Based on these observations, a preliminary version of the proposed model is introduced. This simplified model is then systematically refined in order to demonstrate completely both the modeling approach and parameter identification scheme. The accuracy of the model is demonstrated through a comparison between the modeled and experimental responses including a normalized vector correlation of >0.998 across all sets of sinusoidal experimental data. A brief analysis utilizing a Lyapunov linearization approach follows, as well as a discussion of the advantages and limitations of the final model.

Author(s):  
Nicholas Candelino ◽  
Nader Jalili

Vertically-aligned carbon nanotube (VACNT) pads have recently received widespread attention for use as contact surfaces in material handling processes that involve the transfer of bare silicon wafers. Such processes will benefit from the strong friction force interactions and minimal adhesion force offered by these pads, allowing the wafer to be picked up, carried, and quickly placed, without encountering problems which may arise due to excessive adhesive forces. Despite these benefits, practical implementation has been hindered because VACNTs have nonlinear mechanical characteristics which are still not well understood. Consequently, significant attention has been devoted to fully understand and determine the behaviors associated with their nonlinear dynamic mechanical properties. Along this line, several experimental techniques are applied in this paper to further develop a comprehensive understanding of the mechanical behavior of these pads under compressive loading. It is important to note that the samples used in this testing are not standard VACNTs, but have been grown separately from the final substrate on which they are mounted during testing. After growth, the samples are turned upside-down and fixed so that the bottom ends of all VACNTs are planar and present an ultra-flat top surface for contact during manipulation. The tests performed in this research include a low energy impact test and position controlled load-displacement testing with both constant and sinusoidal velocity loading and unloading. Through these testing procedures, the dependencies of the VACNT material properties to compression depth and displacement rate are observed and an attempt is made to incorporate them into a continuous model. For this, the results from the low energy impact testing provide grounds to state the nature of the nonlinear behavior in our VACNTs. By interrogating the available data from each testing technique, a combination of information provided by the theoretical energy balance and the identified coefficients from the Levenberg-Marquardt curve-fitting algorithm is then applied to generate a parametrized phenomenological model of the VACNT pad behavior. The proposed identified model is continuous and reasonably accounts for the overall material behavior as seen in the experimental data. The validity of this model is shown by means of normalized vector correlation of over 99% between the results of the numerical simulations and the existing experimental data. The material behaviors observed in this research qualitatively support those of several earlier investigators who have previously recognized the complex dissipative behavior of VACNTs. The proposed work itself paves the road for developing a useful engineering model of VACNT pad dynamics which will enable their introduction to mechanical applications in industry.


2015 ◽  
Vol 231 ◽  
pp. 65-73 ◽  
Author(s):  
Roseanne Warren ◽  
Firas Sammoura ◽  
Kwok Siong Teh ◽  
Alina Kozinda ◽  
Xining Zang ◽  
...  

2016 ◽  
Vol 4 (48) ◽  
pp. 19026-19036 ◽  
Author(s):  
Wenkang Zhang ◽  
Bin Zhao ◽  
Yaolong Yin ◽  
Tong Yin ◽  
Junye Cheng ◽  
...  

An asymmetric supercapacitor with extremely high energy and power densities has been developed by using the novel Fe2O3/VACNTs anode.


Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 444 ◽  
Author(s):  
Eleftheria Roumeli ◽  
Marianna Diamantopoulou ◽  
Marc Serra-Garcia ◽  
Paul Johanns ◽  
Giulio Parcianello ◽  
...  

Vertically aligned carbon nanotube (CNT) forests are a particularly interesting class of nanomaterials, because they combine multifunctional properties, such as high energy absorption, compressive strength, recoverability, and super-hydrophobicity with light weight. These characteristics make them suitable for application as coating, protective layers, and antifouling substrates for metallic pipelines and blades. Direct growth of CNT forests on metals offers the possibility of transferring the tunable CNT functionalities directly onto the desired substrates. Here, we focus on characterizing the structure and mechanical properties, as well as wettability and adhesion, of CNT forests grown on different types of stainless steel. We investigate the correlations between composition and morphology of the steel substrates with the micro-structure of the CNTs and reveal how the latter ultimately controls the mechanical and wetting properties of the CNT forest. Additionally, we study the influence of substrate morphology on the adhesion of CNTs to their substrate. We highlight that the same structure-property relationships govern the mechanical performance of CNT forests grown on steels and on Si.


2003 ◽  
Vol 772 ◽  
Author(s):  
Masakazu Muroyama ◽  
Kazuto Kimura ◽  
Takao Yagi ◽  
Ichiro Saito

AbstractA carbon nanotube triode using Helicon Plasma-enhanced CVD with electroplated NiCo catalyst has been successfully fabricated. Isolated NiCo based metal catalyst was deposited at the bottom of the cathode wells by electroplating methods to control the density of carbon nanotubes and also reduce the activation energy of its growth. Helicon Plasma-enhanced CVD (HPECVD) has been used to deposit nanotubes at 400°C. Vertically aligned carbon nanotubes were then grown selectively on the electroplated Ni catalyst. Field emission measurements were performed with a triode structure. At a cathode to anode gap of 1.1mm, the turn on voltage for the gate was 170V.


1985 ◽  
Vol 40 (7) ◽  
pp. 752-773
Author(s):  
H. Stumpf

Unified nonlinear spinorfield models are self-regularizing quantum field theories in which all observable (elementary and non-elementary) particles are assumed to be bound states of fermionic preon fields. Due to their large masses the preons themselves are confined and below the threshold of preon production the effective dynamics of the model is only concerned with bound state reactions. In preceding papers a functional energy representation, the statistical interpretation and the dynamical equations were derived and the effective dynamics for preon-antipreon boson states and three preon-fermion states (with corresponding anti-fermions) was studied in the low energy limit. The transformation of the functional energy representation of the spinorfield into composite particle functional operators produced a hierarchy of effective interactions at the composite particle level, the leading terms of which are identical with the functional energy representation of a phenomenological boson-fermion coupling theory. In this paper these calculations are extended into the high energy range. This leads to formfactors for the composite particle interaction terms which are calculated in a rough approximation and which in principle are observable. In addition, the mathematical and physical interpretation of nonlocal quantum field theories and the meaning of the mapping procedure, its relativistic invariance etc. are discussed.


2016 ◽  
Vol 9 (6) ◽  
pp. 2152-2158 ◽  
Author(s):  
Joo Hyeong Lee ◽  
Chong S. Yoon ◽  
Jang-Yeon Hwang ◽  
Sung-Jin Kim ◽  
Filippo Maglia ◽  
...  

A Li-rechargeable battery system based on state-of-the-art cathode and anode technologies demonstrated high energy density, meeting demands for vehicle application.


2015 ◽  
Vol 117 (21) ◽  
pp. 214306 ◽  
Author(s):  
Richard J. Castellano ◽  
Cevat Akin ◽  
Gabriel Giraldo ◽  
Sangil Kim ◽  
Francesco Fornasiero ◽  
...  

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