Study of Heat and Mass Transfer in MgCl2/NH3 Thermochemical Batteries

2017 ◽  
Vol 139 (3) ◽  
Author(s):  
Seyyed Ali Hedayat Mofidi ◽  
Kent S. Udell
Keyword(s):  
Heat Transfer ◽  
Mass Transfer ◽  
Phase Change ◽  
Heat And Mass Transfer ◽  
Waste Heat ◽  
Experimental Studies ◽  
Reaction Rates ◽  
Solid Matrix ◽  
Dominant Factor ◽  
Gaseous Ammonia

Intermittency of sustainable energy or waste heat availability calls for energy storage systems such as thermal batteries. Thermochemical batteries based on a reversible solid–gas (MgCl2–NH3) reactions and NH3 liquid–gas phase change are of specific interest since the kinetics of absorption are fast and the heat transfer rates for liquid–vapor phase change are high. Thus, a thermochemical battery based on reversible reaction between magnesium chloride and ammonia was studied. Two-dimensional experimental studies were conducted on a reactor in which temperature profiles within the solid matrix and pressure and flow rates of gas were obtained during discharging processes. A numerical model based on heat and mass transfer within the salt and salt–gas reactions was developed to simulate the NH3 absorption processes within the solid matrix, and the results were compared with experimental data to determine dominant heat and mass transfer processes within the salt. It is shown that for high permeability salt beds, the reactor uniformly adsorbs gaseous ammonia until the bed reaches the equilibrium temperature, then adsorbs gas near the cooled boundaries as the reaction front moves inward. In that mode, the heat transfer is the dominant factor in determining reaction rates.

Study of Heat and Mass Transfer in MgCl2/NH3 Thermo-Chemical Batteries

2016 ◽  
Author(s):  
Seyyed Ali Hedayat Mofidi ◽  
Kent S. Udell
Keyword(s):  
Heat Transfer ◽  
Mass Transfer ◽  
Energy Storage ◽  
Phase Change ◽  
Heat And Mass Transfer ◽  
Waste Heat ◽  
Reaction Rates ◽  
High Energy ◽  
Solid Matrix ◽  
Dominant Factor

Intermittency of sustainable energy or waste heat availability calls for energy storage systems such as thermal batteries. Thermo-chemical batteries are particularly appealing for energy storage applications due to their high energy densities and ability to store thermal energy as chemical energy for long periods of time without any energy loss. Thermo-chemical batteries based on a reversible solid-gas (MgCl2 - NH3) reactions and NH3 liquid-gas phase change are of specific interest since the kinetics of absorption are fast and the heat transfer rates for liquid — vapor phase change are high. Thus, a thermo-chemical battery based on reversible reaction between magnesium chloride and ammonia was studied. Experimental studies were conducted on a reactor in which temperature profiles within the solid matrix and pressure and flow rates of gas were obtained during charging processes. A numerical model based on heat and mass transfer within the salt and salt-gas reactions was developed to simulate the absorption processes within the solid matrix and the results were compared with experimental data. The studies were used to determine dominant heat and mass transfer processes within the salt. It is shown that for high permeability materials, heat transfer is the dominant factor in determining reaction rates. However increasing thermal conductivity might decrease permeability and reduce reaction rates. The effect of constraining mass flow rate on the temperature and reaction propagation is also studied. These results show that optimized heat and mass transfer within the solid-gas reactor will lead to improved performance for heating and air conditioning applications.

scholarly journals A novel internal heat recycling concept for reducing energy consumption and increasing flux through three-stage air-gap–water-gap membrane distillation system

2020 ◽  
Vol 20 (7) ◽  
pp. 2858-2874
Author(s):  
Mostafa Abd El-Rady Abu-Zeid ◽  
Xiaolong Lu ◽  
Shaozhe Zhang
Keyword(s):  
Heat Transfer ◽  
Mass Transfer ◽  
Energy Consumption ◽  
Heat And Mass Transfer ◽  
Waste Heat ◽  
Internal Heat ◽  
High Energy ◽  
Membrane Distillation ◽  
Air Gap ◽  
Air Gap Membrane Distillation

Abstract The low flux and high energy consumption problems of the conventional three-stage air-gap membrane distillation (AG-AG-AG)MD system caused by the low temperature difference between hot and cold feed at both sides of the membrane and high boundary layer thickness were solved successfully by replacing one of the three stages of air gaps by a water gap. The novel three-stage air-gap–water-gap membrane distillation (AG-AG-WG)MD system reduced energy consumption and increased flux due to efficient internal heat recycling by virtue of a water-gap module. Heat and mass transfer in novel and conventional three-stage systems were analyzed theoretically. Under a feed temperature of 45 °C, flow rate of 20 l/h, cooling temperature of 20 °C, and concentration of 340 ppm, the (AG-AG-WG)MD promoted flux by 17.59% and 211.69%, and gained output ratio (GOR) by 60.57% and 204.33% compared with two-stage (AG-WG)MD and one-stage AGMD, respectively. This work demonstrated the important role of a water gap in changing the heat and mass transfer where convection heat transfer across the water gap is faster by 24.17 times than conduction heat transfer through the air gap. The increase in flux and GOR economized the heating energy and decreased waste heat input into the system. Additionally, the number of MD stages could increase the achieving of a high flux with operation stability.

Heat Transfer and Air Diffusion Phenomena in a Bed of Polymer Powder Using Apparent Heat Capacity Method: Application to the Rotational Molding Process

2007 ◽  
Author(s):  
M. Boutaous ◽  
E. Pe´rot ◽  
A. Maazouz ◽  
P. Bourgin ◽  
P. Chantrenne
Keyword(s):  
Heat Transfer ◽  
Mass Transfer ◽  
Heat Flux ◽  
Phase Change ◽  
Heat And Mass Transfer ◽  
Granular Media ◽  
Transfer Model ◽  
Melting Front ◽  
Polymer Powder ◽  
Air Diffusion

The process of rotational moulding consists in manufacturing plastic parts by heating a polymer powder in a biaxial rotating mould. In order to optimise the production cycle of this process, a complete simulation model has to be used. This model should describe the phenomena of heat and mass transfer in a moving granular media with phase change, coalescence, sintering, air evacuation and crystallization during the cooling stage. This paper focus on the study of heat and mass transfer in a quiescent polymer powder during the heating stage. An experimental device has been built. It consists in an open plane static mold on which an initial thickness, e, of a polymer powder is deposited. This powder is then heated until it melts. An inverse heat conduction method is used to determine the heat flux and temperature at the interface between the mold and the powder. This interfacial heat flux is taken as a boundary condition in a numerical heat transfer model witch takes into account the heat transfer in granular media with phase change, coalescence, sintering, air bubbles evacuation and rheological behaviour of the polymer. For the numerical simulation of the heat transfer, the apparent specific heat method is used. This approach allows to solve the same energy equation for all the material phases, so one do not have to calculate the melting front evolution. This fine modelling, close to the real physical phenomena makes it possible to estimate the temperature profile and the evolution of the polymer powder characteristics (phase change, air diffusion, viscosity, evolution of the thermophysical properties of the equivalent homogeneous medium, thickness reduction, air volume fraction...). Several results are then presented, and the influence of different parameters, like the thermal contact resistance, the process initial conditions and the polymer’s rheological characteristics are studied and commented. Indeed the predictions of the temperature rises in the polymer bed, agree well with the experimental measurements.

Analysis of Integral Transform Solutions for Thermally Developing Flow in Microchannels With Isothermal Wall

2011 ◽  
Author(s):  
D. J. N. M. Chalhub ◽  
L. A. Sphaier
Keyword(s):  
Heat Transfer ◽  
Mass Transfer ◽  
Heat And Mass Transfer ◽  
Flow Problem ◽  
Integral Transform ◽  
Scale Effects ◽  
Experimental Studies ◽  
Macro Scale ◽  
Optimum Solution ◽  
Solution Methodology

There is a growing interest for applications of heat and mass transfer in microchannels. Consequently, several numerical and experimental studies related to transport phenomena in microchannels have been carried-out. The flow problem in microchannels is different from the macro-scale problems due to rarefaction effects, surface roughness, viscous dissipation heating as well as other effects. As a result, a number of studies have been proposed for investigating the micro-flow problem and how each of these phenomena affect heat and mass transfer characteristics. Naturally, there is particular focus on how the observed micro-scale phenomena differ from the traditionally known macro-scale effects. In the realm of simulation studies for heat transfer in micro-sized channels, this paper proposes a comparison between hybrid solution strategies for solving steady heat transfer problems within microchannels. The Generalized Integral Transform Technique (GITT) is employed as the main solution methodology; however, different solution approaches are investigated in order to determine advantages and drawbacks of each alternative. The presented results can serve as guidance for choosing an optimum solution methodology for thermally developing heat transfer in microchannels using GITT implementations.

Heat and Mass Transfer With Phase Change and Chemical Reactions in Microscale

2010 ◽  
Author(s):  
Vladimir V. Kuznetsov
Keyword(s):  
Heat Transfer ◽  
Experimental Data ◽  
Mass Transfer ◽  
Phase Change ◽  
Heat And Mass Transfer ◽  
Chemical Reactions ◽  
Boiling Heat Transfer ◽  
Flow Boiling ◽  
Microscale Flow ◽  
Explosive Evaporation

In recent years considerable attention has been paid to the study of microscale flow and heat transfer with phase change and chemical reactions. This article reviews the patterns of the microscale two-phase gas-liquid flow, the statistical parameters of slug flow and capillary phenomena in annular flow for a rectangular microchannel. The evaporative and condensing heat transfer model for the curved liquid microfilm in microchannel and near contact line is developed and discussed. The influence of forced convection, nucleate boiling and thin film evaporation on microscale flow boiling heat transfer is reviewed and analyzed. The model of forced boiling heat transfer in microchannel is developed and compared with the existing experimental data. The mechanism and patterns of microscale explosive evaporation in the MEMS system is determined at high external heat flux density and the acousto-thermal model of the explosive evaporation is considered. The results of calculations are compared with the experimental data. The peculiarities of heat and mass transfer in a micro channel with surface catalytic reactions producing the hydrogen are presented. The kinetics of sequence of chemical reactions at nanoscale catalyst under conditions of significant nonuniformity of temperature and species concentration fields is considered.

scholarly journals Impact of Binary Chemical Reaction and Activation Energy on Heat and Mass Transfer of Marangoni Driven Boundary Layer Flow of a Non-Newtonian Nanofluid

Processes ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 702
Author(s):  
Ramanahalli Jayadevamurthy Punith Gowda ◽  
Rangaswamy Naveen Kumar ◽  
Anigere Marikempaiah Jyothi ◽  
Ballajja Chandrappa Prasannakumara ◽  
Ioannis E. Sarris
Keyword(s):  
Heat Transfer ◽  
Activation Energy ◽  
Boundary Layer ◽  
Mass Transfer ◽  
Heat And Mass Transfer ◽  
Velocity Gradient ◽  
Boundary Layer Flow ◽  
Biological Fluids ◽  
Porosity Parameter ◽  
Layer Flow

The flow and heat transfer of non-Newtonian nanofluids has an extensive range of applications in oceanography, the cooling of metallic plates, melt-spinning, the movement of biological fluids, heat exchangers technology, coating and suspensions. In view of these applications, we studied the steady Marangoni driven boundary layer flow, heat and mass transfer characteristics of a nanofluid. A non-Newtonian second-grade liquid model is used to deliberate the effect of activation energy on the chemically reactive non-Newtonian nanofluid. By applying suitable similarity transformations, the system of governing equations is transformed into a set of ordinary differential equations. These reduced equations are tackled numerically using the Runge–Kutta–Fehlberg fourth-fifth order (RKF-45) method. The velocity, concentration, thermal fields and rate of heat transfer are explored for the embedded non-dimensional parameters graphically. Our results revealed that the escalating values of the Marangoni number improve the velocity gradient and reduce the heat transfer. As the values of the porosity parameter increase, the velocity gradient is reduced and the heat transfer is improved. Finally, the Nusselt number is found to decline as the porosity parameter increases.

CFD-based structure optimization of plate bundle in plate-fin heat exchanger considering flow and heat transfer performance

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Yao Li ◽  
Haiqing Si ◽  
Jingxuan Qiu ◽  
Yingying Shen ◽  
Peihong Zhang ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Mass Transfer ◽  
Heat Exchanger ◽  
Heat And Mass Transfer ◽  
Field Performance ◽  
High Specific Surface Area ◽  
Calculation Model ◽  
Air Separation ◽  
Transfer Efficiency ◽  
Heat Transfer Efficiency

Abstract The plate-fin heat exchanger has been widely applied in the field of air separation and aerospace due to its high specific surface area of heat transfer. However, the low heat transfer efficiency of its plate bundles has also attracted more attention. It is of great significance to optimize the structure of plate-fin heat exchanger to improve its heat transfer efficiency. The plate bundle was studied by combining numerical simulation with experiment. Firstly, according to the heat and mass transfer theory, the plate bundle calculation model of plate-fin heat exchanger was established, and the accuracy of the UDF (User-Defined Functions) for describing the mass and heat transfer was verified. Then, the influences of fin structure parameters on the heat and mass transfer characteristics of channel were discussed, including the height, spacing, thickness and length of fins. Finally the influence of various factors on the flow field performance under different flow states was integrated to complete the optimal design of the plate bundle.

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