Perspective on the Mechanical Interaction Between Lithium Dendrites and Polymer Separators at Low Temperature

2016 ◽  
Vol 13 (3) ◽  
Author(s):  
Corey T. Love
Keyword(s):  
Mechanical Properties ◽  
Lithium Battery ◽  
Critical Role ◽  
Physical Interaction ◽  
Temperature Dependent ◽  
Passive Components ◽  
Battery Systems ◽  
Lithium Dendrites ◽  
Polymer Separator ◽  
Lithium Dendrite

This perspective paper underscores the importance of coupled electro-mechanical studies in lithium battery systems with a specific example given of the interaction between temperature-dependent dendrite morphologies and polymer separators. Polymer separators are passive components in lithium battery systems yet play a critical role in cell safety. Separators must maintain dimensional stability to provide electronic isolation of the active electrodes and resist puncture and penetration from lithium dendrites. The polyolefin class of polymers has been used extensively for this application with mixed success. Recent research efforts to characterize lithium dendrite formation and growth have shown distinct temperature-dependent dendrite morphologies: rounded blunt mushroom-shaped, sharp jagged needle-like, and granular particulates. Each of these dendrite morphologies will induce a difference physical interaction with the polymer separator. Anticipating this interaction is difficult since the mechanical properties of the polymer separator itself are largely temperature dependent. This paper describes the anticipated physical interaction of the three different dendrite morphologies listed above as a function of temperature and the local physical properties of the commercial polymer separator. A discussion is also provided on the utility of estimating local mechanical properties in the electrochemical battery environment from traditional mechanical and thermomechanical measurements made in the laboratory.

scholarly journals Transcriptional coregualtor NUPR1 maintains tamoxifen resistance in breast cancer cells

2021 ◽  
Vol 12 (2) ◽  
Author(s):  
Lingling Wang ◽  
Jiashen Sun ◽  
Yueyuan Yin ◽  
Yanan Sun ◽  
Jinyi Ma ◽  
...  
Keyword(s):  
Breast Cancer ◽  
Cancer Cells ◽  
Breast Cancer Cells ◽  
Critical Role ◽  
Endocrine Resistance ◽  
Autophagic Flux ◽  
Physical Interaction ◽  
Premature Senescence ◽  
Breast Cancers ◽  
Transcriptional Coregulator

AbstractTo support cellular homeostasis and mitigate chemotherapeutic stress, cancer cells must gain a series of adaptive intracellular processes. Here we identify that NUPR1, a tamoxifen (Tam)-induced transcriptional coregulator, is necessary for the maintenance of Tam resistance through physical interaction with ESR1 in breast cancers. Mechanistically, NUPR1 binds to the promoter regions of several genes involved in autophagy process and drug resistance such as BECN1, GREB1, RAB31, PGR, CYP1B1, and regulates their transcription. In Tam-resistant ESR1 breast cancer cells, NUPR1 depletion results in premature senescence in vitro and tumor suppression in vivo. Moreover, enforced-autophagic flux augments cytoplasmic vacuolization in NUPR1-depleted Tam resistant cells, which facilitates the transition from autophagic survival to premature senescence. Collectively, these findings suggest a critical role for NUPR1 as a transcriptional coregulator in enabling endocrine persistence of breast cancers, thus providing a vulnerable diagnostic and/or therapeutic target for endocrine resistance.

scholarly journals Temperature-Dependent Creep Behavior and Quasi-Static Mechanical Properties of Heat-Treated Wood

Forests ◽  
2021 ◽  
Vol 12 (8) ◽  
pp. 968
Author(s):  
Dong Xing ◽  
Xinzhou Wang ◽  
Siqun Wang
Keyword(s):  
Mechanical Properties ◽  
Creep Behavior ◽  
Cell Walls ◽  
Treated Wood ◽  
Crosslinking Reaction ◽  
Depth Sensing ◽  
Temperature Dependent ◽  
Heat Treated ◽  
Static Mechanical ◽  
Static Mechanical Properties

In this paper, Berkovich depth-sensing indentation has been used to study the effects of the temperature-dependent quasi-static mechanical properties and creep deformation of heat-treated wood at temperatures from 20 °C to 180 °C. The characteristics of the load–depth curve, creep strain rate, creep compliance, and creep stress exponent of heat-treated wood are evaluated. The results showed that high temperature heat treatment improved the hardness of wood cell walls and reduced the creep rate of wood cell walls. This is mainly due to the improvement of the crystallinity of the cellulose, and the recondensation and crosslinking reaction of the lignocellulose structure. The Burgers model is well fitted to study the creep behavior of heat-treated wood cell walls under different temperatures.

Elastic-Viscoplastic Mechanics of Lithium in a Standard Dry Room

2020 ◽  
Author(s):  
Lara L. Dienemann ◽  
Anil Saigal ◽  
Michael A. Zimmerman
Keyword(s):  
High Volume ◽  
Lattice Diffusion ◽  
Mechanical Parameters ◽  
Mechanical Modeling ◽  
Lithium Metal ◽  
Temperature Dependent ◽  
Linear Elastic ◽  
Battery Safety ◽  
Lithium Dendrites ◽  
Solid State Batteries

Abstract In electrochemical-mechanical modeling of solid-state batteries, there is a lack of understanding of the mechanical parameters and mode of deformation of lithium metal. Understanding these characteristics is crucial for predicting the propagation of lithium dendrites through the electrolyte — a key element of battery safety. Past theories have assumed linear elastic as well as elastic-plastic deformation of lithium. However, recent experiments show that the primary mode of deformation is creep. This study replicates the temperature dependent mechanical experiments but inside an industrial dry room, where battery cells are manufactured at high volume. Furthermore, this work conducts time dependent studies — also inside the dry room — to gain insight of the large deformation theories of lithium metal. The results confirm the activation energy, which dictates the creep mechanism, is correlated to core diffusion rather than lattice diffusion.

scholarly journals Numerical study of flow patterns and heat transfer in mini twisted oval tubes

2015 ◽  
Vol 26 (12) ◽  
pp. 1550140 ◽  
Author(s):  
Amin Ebrahimi ◽  
Ehsan Roohi
Keyword(s):  
Heat Transfer ◽  
Heat Transfer Performance ◽  
Numerical Study ◽  
Critical Role ◽  
Reynolds Numbers ◽  
Flow Patterns ◽  
Working Fluid ◽  
Transfer Performance ◽  
Temperature Dependent ◽  
Overall Performance

Flow patterns and heat transfer inside mini twisted oval tubes (TOTs) heated by constant-temperature walls are numerically investigated. Different configurations of tubes are simulated using water as the working fluid with temperature-dependent thermo-physical properties at Reynolds numbers ranging between 500 and 1100. After validating the numerical method with the published correlations and available experimental results, the performance of TOTs is compared to a smooth circular tube. The overall performance of TOTs is evaluated by investigating the thermal-hydraulic performance and the results are analyzed in terms of the field synergy principle and entropy generation. Enhanced heat transfer performance for TOTs is observed at the expense of a higher pressure drop. Additionally, the secondary flow generated by the tube-wall twist is concluded to play a critical role in the augmentation of convective heat transfer, and consequently, better heat transfer performance. It is also observed that the improvement of synergy between velocity and temperature gradient and lower irreversibility cause heat transfer enhancement for TOTs.

Thermal Effects on the Vibration of Functionally Graded Deep Beams with Porosity

2017 ◽  
Vol 09 (05) ◽  
pp. 1750076 ◽  
Author(s):  
Şeref Doğuşcan Akbaş
Keyword(s):  
Mechanical Properties ◽  
Finite Element Method ◽  
Finite Element ◽  
Thermal Effects ◽  
Functionally Graded ◽  
Deep Beam ◽  
Material Distribution ◽  
Governing Equations ◽  
Temperature Dependent ◽  
Deep Beams

The purpose of this study is to investigate the thermal effects on the free vibration of functionally graded (FG) porous deep beams. Mechanical properties of the FG deep beam are temperature-dependent and vary across the height direction with different porosity models. The governing equations problem is obtained by using the Hamilton’s principle. In the solution of the problem, plane piecewise solid continua model and finite element method are used. The effects of porosity parameters, material distribution, porosity models and temperature rising on the vibration characteristics are presented and discussed with porosity effects for FG deep beams.

scholarly journals Temperature-Dependent Superplasticity and Strengthening in CoNiCrFeMn High Entropy Alloy Nanowires Using Atomistic Simulations

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 2111
Author(s):  
Pawan Kumar Tripathi ◽  
Yu-Chen Chiu ◽  
Somnath Bhowmick ◽  
Yu-Chieh Lo
Keyword(s):  
Mechanical Properties ◽  
Cross Section ◽  
Partial Dislocation ◽  
Semiconductor Industry ◽  
Apparent Temperature ◽  
High Entropy Alloy ◽  
Single Element ◽  
Temperature Dependent ◽  
High Entropy ◽  
Ag Nanowires

High strength and ductility, often mutually exclusive properties of a structural material, are also responsible for damage tolerance. At low temperatures, due to high surface energy, single element metallic nanowires such as Ag usually transform into a more preferred phase via nucleation and propagation of partial dislocation through the nanowire, enabling superplasticity. In high entropy alloy (HEA) CoNiCrFeMn nanowires, the motion of the partial dislocation is hindered by the friction due to difference in the lattice parameter of the constituent atoms which is responsible for the hardening and lowering the ductility. In this study, we have examined the temperature-dependent superplasticity of single component Ag and multicomponent CoNiCrFeMn HEA nanowires using molecular dynamics simulations. The results demonstrate that Ag nanowires exhibit apparent temperature-dependent superplasticity at cryogenic temperature due to (110) to (100) cross-section reorientation behavior. Interestingly, HEA nanowires can perform exceptional strength-ductility trade-offs at cryogenic temperatures. Even at high temperatures, HEA nanowires can still maintain good flow stress and ductility prior to failure. Mechanical properties of HEA nanowires are better than Ag nanowires due to synergistic interactions of deformation twinning, FCC-HCP phase transformation, and the special reorientation of the cross-section. Further examination reveals that simultaneous activation of twining induced plasticity and transformation induced plasticity are responsible for the plasticity at different stages and temperatures. These findings could be very useful for designing nanowires at different temperatures with high stability and superior mechanical properties in the semiconductor industry.

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