Drag Reduction in Synthetic Seawater by Flexible and Rigid Polymer Addition Into a Rotating Cylindrical Double Gap Device

2015 ◽  
Vol 138 (2) ◽  
Author(s):  
Rafhael M. Andrade ◽  
Anselmo S. Pereira ◽  
Edson J. Soares
Keyword(s):  
Drag Reduction ◽  
Turbulent Flows ◽  
Salt Concentration ◽  
Polymer Concentration ◽  
Transient Behavior ◽  
Turbulent Structures ◽  
Polymer Addition ◽  
Rigid Polymer ◽  
Potential Applications ◽  
Poly Ethylene

Flexible and rigid long chain polymers in very dilute solutions can significantly reduce the drag in turbulent flows. The polymers successively stretch and coil by interacting with the turbulent structures, which changes the turbulent flow and further imposes a transient behavior on the drag reduction (DR) as well as a subsequent mechanical polymer degradation. This time-dependent phenomenon is strongly affected by a number of parameters, which are analyzed here, such as the Reynolds number, polymer concentration, polymer molecular weight, and salt concentration. This last parameter can dramatically modify the polymeric structure. The investigation of the salt concentration's impact on the DR is mostly motivated by some potential applications of this technique to ocean transport and saline fluid flows. In the present paper, a cylindrical double gap rheometer device is used to study the effects of salt concentration on DR over time. The reduction of drag is induced by three polymers: poly (ethylene oxide) (PEO), polyacrylamide (PAM), and xanthan gum (XG). These polymers are dissolved in deionized water both in the presence of salt and in its absence. The DR is displayed from the very start of the test to the time when the DR achieves its final level of efficiency, following the mechanical degradations. The presence of salt in PEO and XG solutions reduces the maximum DR, DRmax, as well as the time to achieve it. In contrast, the DR does not significantly change over the time for PAM solutions upon the addition of salt.

Bubble Effects on Wall Shear in Vortical Flows

2003 ◽  
Author(s):  
Arturo Ferna´ndez ◽  
Jiacai Lu ◽  
Gre´tar Tryggvason
Keyword(s):  
Surface Tension ◽  
Drag Reduction ◽  
Numerical Simulations ◽  
Turbulent Flows ◽  
Front Tracking ◽  
Direct Numerical Simulations ◽  
Fluid Inertia ◽  
Fundamental Interaction ◽  
Turbulent Structures ◽  
Simplified Models

Direct numerical simulations of the motion of bubbles in turbulent flows are being carried out, using a finite volume/front tracking technique that accounts fully for the effect of fluid inertia, viscosity, bubble deformability, and surface tension. The objective of the simulations is both to address the fundamental interaction mechanisms between the bubbles and the flow and how the bubbles modify the wall turbulent structures, as well as to provide data for validation of simplified models. Results for bubbles placed in the so-called “minimum turbulent channel” show significant drag reduction as the bubbles disrupt the near-wall turbulent flow.

Drag reduction by spanwise wall oscillation in wall-bounded turbulent flows

AIAA Journal ◽  
2002 ◽  
Vol 40 ◽  
pp. 842-850 ◽  
Author(s):  
J.-I. Choi ◽  
C.-X. Xu ◽  
H. J. Sung
Keyword(s):  
Drag Reduction ◽  
Turbulent Flows ◽  
Wall Oscillation

Effect of High Salt Concentration on Ion Clustering and Transport in Polymer Solid Electrolytes: a Molecular Dynamics Study of PEO-LiTFSI

2018 ◽  
Author(s):  
Nicola Molinari ◽  
Jonathan P. Mailoa ◽  
Boris Kozinsky
Keyword(s):  
Polymer Electrolyte ◽  
Salt Concentration ◽  
Rational Design ◽  
Material System ◽  
Ion Dynamics ◽  
High Concentration ◽  
Anion Clusters ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

<div> <div> <div> <p>The model and analysis methods developed in this work are generally applicable to any polymer electrolyte/cation-anion combination, but we focus on the currently most prominent polymer electrolyte material system: poly(ethylene) oxide/Li- bis(trifluoromethane) sulfonamide (PEO + LiTFSI). The obtained results are surprising and challenge the conventional understanding of ionic transport in polymer electrolytes: the investigation of a technologically relevant salt concentration range (1 - 4 M) revealed the central role of the anion in coordinating and hindering Li ion movement. Our results provide insights into correlated ion dynamics, at the same time enabling rational design of better PEO-based electrolytes. In particular, we report the following novel observations. 1. Strong binding of the Li cation with the polymer competes with significant correlation of the cation with the salt anion. 2. The appearance of cation-anion clusters, especially at high concentration. 3. The asymmetry in the composition (and therefore charge) of such clusters; specifically, we find the tendency for clusters to have a higher number of anions than cations.</p> </div> </div> </div>

Effect of High Salt Concentration on Ion Clustering and Transport in Polymer Solid Electrolytes: a Molecular Dynamics Study of PEO-LiTFSI

2018 ◽  
Author(s):  
Nicola Molinari ◽  
Jonathan P. Mailoa ◽  
Boris Kozinsky
Keyword(s):  
Polymer Electrolyte ◽  
Salt Concentration ◽  
Rational Design ◽  
Material System ◽  
Ion Dynamics ◽  
High Concentration ◽  
Anion Clusters ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

<div> <div> <div> <p>The model and analysis methods developed in this work are generally applicable to any polymer electrolyte/cation-anion combination, but we focus on the currently most prominent polymer electrolyte material system: poly(ethylene) oxide/Li- bis(trifluoromethane) sulfonamide (PEO + LiTFSI). The obtained results are surprising and challenge the conventional understanding of ionic transport in polymer electrolytes: the investigation of a technologically relevant salt concentration range (1 - 4 M) revealed the central role of the anion in coordinating and hindering Li ion movement. Our results provide insights into correlated ion dynamics, at the same time enabling rational design of better PEO-based electrolytes. In particular, we report the following novel observations. 1. Strong binding of the Li cation with the polymer competes with significant correlation of the cation with the salt anion. 2. The appearance of cation-anion clusters, especially at high concentration. 3. The asymmetry in the composition (and therefore charge) of such clusters; specifically, we find the tendency for clusters to have a higher number of anions than cations.</p> </div> </div> </div>

scholarly journals Bottlebrush polymers in the melt and polyelectrolytes in solution share common structural features

2020 ◽  
Vol 117 (10) ◽  
pp. 5168-5175 ◽  
Author(s):  
Joel M. Sarapas ◽  
Tyler B. Martin ◽  
Alexandros Chremos ◽  
Jack F. Douglas ◽  
Kathryn L. Beers
Keyword(s):  
Neutron Scattering ◽  
Correlation Length ◽  
Salt Concentration ◽  
Polymer Concentration ◽  
Structural Features ◽  
Peak Position ◽  
Correlation Peak ◽  
Grafting Density ◽  
Scattering Measurements ◽  
Polyelectrolyte Solutions

Uncharged bottlebrush polymer melts and highly charged polyelectrolytes in solution exhibit correlation peaks in scattering measurements and simulations. Given the striking superficial similarities of these scattering features, there may be a deeper structural interrelationship in these chemically different classes of materials. Correspondingly, we constructed a library of isotopically labeled bottlebrush molecules and measured the bottlebrush correlation peak position q*=2π/ξ by neutron scattering and in simulations. We find that the correlation length scales with the backbone concentration, ξ∼cBB−0.47, in striking accord with the scaling of ξ with polymer concentration cP in semidilute polyelectrolyte solutions (ξ∼cP−1/2). The bottlebrush correlation peak broadens with decreasing grafting density, similar to increasing salt concentration in polyelectrolyte solutions. ξ also scales with sidechain length to a power in the range of 0.35–0.44, suggesting that the sidechains are relatively collapsed in comparison to the bristlelike configurations often imagined for bottlebrush polymers.

Drag reduction capability of uniform blowing in supersonic wall-bounded turbulent flows

2017 ◽  
Vol 2 (12) ◽  
Author(s):  
Yukinori Kametani ◽  
Ayane Kotake ◽  
Koji Fukagata ◽  
Naoko Tokugawa
Keyword(s):  
Drag Reduction ◽  
Turbulent Flows

scholarly journals Fibre-induced drag reduction

2008 ◽  
Vol 602 ◽  
pp. 209-218 ◽  
Author(s):  
J. J. J. GILLISSEN ◽  
B. J. BOERSMA ◽  
P. H. MORTENSEN ◽  
H. I. ANDERSSON
Keyword(s):  
Experimental Data ◽  
Numerical Simulation ◽  
Reynolds Number ◽  
Drag Reduction ◽  
Elastic Layer ◽  
Turbulent Drag Reduction ◽  
Rigid Polymer ◽  
Fibre Concentration ◽  
Induced Drag ◽  
Turbulent Drag

We use direct numerical simulation to study turbulent drag reduction by rigid polymer additives, referred to as fibres. The simulations agree with experimental data from the literature in terms of friction factor dependence on Reynolds number and fibre concentration. An expression for drag reduction is derived by adopting the concept of the elastic layer.

Drag Reducing Polymer in Helicoidal Flow

1981 ◽  
Vol 103 (4) ◽  
pp. 491-496 ◽  
Author(s):  
J. T. Kuo ◽  
L. S. G. Kovasznay
Keyword(s):  
Drag Reduction ◽  
Polymer Solution ◽  
Ph Value ◽  
Flow Behavior ◽  
Superposition Principle ◽  
Polymer Concentration ◽  
Second Phase ◽  
Additional Parameter ◽  
Solution Flow ◽  
Screw Pump

A novel flow configuration was explored for the study of the behavior of drag reducing polymers. A screw pump consisting of a smooth cylinder and a concentrically placed screw was used to create a strongly three-dimensional but essentially laminar flow. In the first phase of the study, the static pressure head developed by the screw pump was measured as a function of polymer concentration (polyox 10 to 100 ppm in water). A large increase of the developed head was observed that behaved in an analogous manner to drag reduction as far as concentration and straining of the polymer solution was concerned. In the second phase of the study, a new apparatus was constructed and the additional parameter of a superimposed through flow was included and the degree of failure of the superposition principle was established. Sensitivity of the phenomenon to chemicals like HCl, HNO3, and NaOH in the polymer solution was also studied. When the effect of these chemicals on the polymer solution flow behavior was presented in terms of the pH value of the polymer solution, it showed a similar trend to those observed in drag reduction.

Sign in / Sign up

Export Citation Format

Share Document