Effect of Cetane Improver on Combustion and Emission Characteristics of Coal-Derived Sasol Isomerized Paraffinic Kerosene in a Single Cylinder Diesel Engine

Author(s):  
Ziliang Zheng ◽  
Umashankar Joshi ◽  
Naeim Henein ◽  
Eric Sattler

Sasol isomerized paraffinic kerosene (IPK) is a coal-derived synthetic fuel under consideration as a blending stock with JP-8 for use in military ground vehicles. Since Sasol IPK is a low ignition quality fuel with derived cetane number (DCN) of 31, there is a need to improve its ignition quality. This paper investigates the effect of adding different amounts of Lubrizol 8090 cetane improver to Sasol IPK on increasing its DCN. The experimental investigation was conducted in a single cylinder research type diesel engine. The engine is equipped with a common rail injection system and an open engine control unit. Experiments covered different injection pressures and intake air temperatures. Analysis of test results was made to determine the effect of cetane improver percentage in the coal-derived Sasol IPK blend on auto-ignition, combustion and emissions of carbon monoxide (CO), total unburned hydrocarbon (HC), oxides of nitrogen (NOx), and particulate matter (PM). In addition, the effect of cetane improver on the apparent activation energy of the global auto-ignition reactions was determined.

Author(s):  
Ziliang Zheng ◽  
Umashankar Joshi ◽  
Naeim Henein ◽  
Eric Sattler

Sasol IPK is a coal-derived synthetic fuel under consideration as a blending stock with JP-8 for use in military ground vehicles. Since Sasol IPK is a low ignition quality fuel with Derived Cetane Number (DCN) of 31, there is a need to improve its ignition quality. This paper investigates the effect of adding different amounts of Lubrizol 8090 cetane improver to Sasol IPK on increasing its DCN. The experimental investigation was conducted in a single-cylinder research type diesel engine. The engine is equipped with a common rail injection system and an open Engine Control Unit (ECU). Experiments covered different injection pressures and intake air temperatures. Analysis of test results was made to determine the effect of cetane improver percentage in the coal-derived Sasol IPK blend on autoignition, combustion and emissions of carbon monoxide (CO), total unburned hydrocarbon (HC), oxides of nitrogen (NOx), and particulate matter (PM). In addition, the effect of cetane improver on the apparent activation energy of the global autoignition reactions was determined.


Author(s):  
Samy Alkhayat ◽  
Manan Trivedi ◽  
Naeim Henein ◽  
Sampad Mukhopadhyay ◽  
Peter Schihl

Surrogates development is important to extensively investigate the combustion behavior of fuels. Development of comprehensive surrogates has been focusing on matching chemical and physical properties of their target fuel to mimic its atomization, evaporation, mixing, and auto-ignition behavior. More focus has been given to matching the derived cetane number (DCN) as a measure of the auto-ignition quality. In this investigation, we carried out experimental validation of a three-component surrogate for Sasol-Isoparaffinic Kerosene (IPK) in ignition quality tester (IQT) and in an actual diesel engine. The surrogate fuel is composed of three components (46% iso-cetane, 44% decalin, and 10% n-nonane on a volume basis). The IQT experiments were conducted as per ASTM D6890-10a. The engine experiments were conducted at 1500 rpm, two engine loads, and two injection timings. Analysis of ignition delay (ID), peak pressure, peak rate of heat release (RHR), and other combustion phasing parameters showed a closer match in the IQT than in the diesel engine. Comparison between the surrogate combustion behavior in the diesel engine and IQT revealed that matching the DCN of the surrogate to its respective target fuel did not result in the same negative temperature coefficient (NTC) profile—which led to unmatched combustion characteristics in the high temperature combustion (HTC) regimes, despite the same auto-ignition and low temperature combustion (LTC) profiles. Moreover, a comparison between the combustion behaviors of the two fuels in the IQT is not consistent with the comparison in the diesel engine, which suggests that the surrogate validation in a single-cylinder diesel engine should be part of the surrogate development methodology, particularly for low ignition quality fuels.


Author(s):  
Ziliang Zheng ◽  
Tamer Badawy ◽  
Naeim Henein ◽  
Eric Sattler

This paper investigates the physical and chemical ignition delay (ID) periods in the constant volume combustion chamber of the Ignition Quality Tester (IQT). IQT was used to determine the derived cetane number (DCN) according to ASTM D6890-10a standards. The fuels tested were ultra low sulfur diesel (ULSD), jet propellant-8 (JP-8), and two synthetic fuels of Sasol IPK and F-T SPK (S-8). A comparison was made between the DCN and cetane number (CN) determined according to ASTM-D613 standards. Tests were conducted under steady state conditions at a constant pressure of 21 bars and various air temperatures ranging from 778 K to 848 K. The rate of heat release (RHR) was calculated from the measured pressure trace, and a detailed analysis of the RHR trace was made particularly for the auto-ignition process. Tests were conducted to determine the physical and chemical delay periods by comparing results obtained from two tests. In the first test, the fuel was injected into air according to ASTM standards. In the second test, the fuel was injected into nitrogen. The point at which the two resultant pressure traces separated was considered to be the end of the physical delay period. The effects of the charge temperature on the total ID as defined in ASTM D6890-10a standards, as well as on the physical and chemical delays, were determined. It was noticed that the physical delay represented a significant part of the total ID over all the air temperatures covered in this investigation. Arrhenius plots were developed to determine the apparent activation energy for each fuel using different IDs. The first was based on the total ID measured according to ASTM standards. The second was the chemical delay determined in this investigation. The activation energy calculated from the total ID showed higher values for lower CN fuels except Sasol IPK. The activation energy calculated from the chemical delay period showed consistency in the increase of the activation energy with the drop in CN including Sasol IPK. The difference between the two findings could be explained by examining the sensitivity of the physical delay period of different fuels to the change in air temperature.


2018 ◽  
Vol 4 (2) ◽  
Author(s):  
Soni S. Wirawan dkk

Biodiesel is a viable substitute for petroleum-based diesel fuel. Its advantages are improved lubricity, higher cetane number and cleaner emission. Biodiesel and its blends with petroleum-based diesel fuel can be used in diesel engines without any signifi cant modifi cations to the engines. Data from the numerous research reports and test programs showed that as the percent of biodiesel in blends increases, emission of hydrocarbons (HC), carbon monoxide (CO), and particulate matter (PM) all decrease, but the amount of oxides of nitrogen (NOx) and fuel consumption is tend to increase. The most signifi cant hurdle for broader commercialization of biodiesel is its cost. In current fuel price policy in Indonesia (especially fuel for transportation), the higher percent of biodiesel in blend will increase the price of blends fuel. The objective of this study is to assess the optimum blends of biodiesel with petroleum-based diesel fuel from the technically and economically consideration. The study result recommends that 20% biodiesel blend with 80% petroleum-based diesel fuel (B20) is the optimum blend for unmodifi ed diesel engine uses.Keywords: biodiesel, emission, optimum, blend


Author(s):  
Naeim A. Henein ◽  
Tamer Badawy ◽  
Nilesh Rai ◽  
Walter Bryzik

Advanced electronically controlled diesel engines require a feedback signal to the ECU to adjust different operating parameters and meet demands for power, better fuel economy and low emissions. Different types of in-cylinder combustion sensors are being considered to produce this signal. This paper presents results of an experimental investigation on the characteristics of the ion current in an automotive diesel engine equipped with a common rail injection system. The engine is a 1.9 L, 4-cylinder, direct injection diesel engine. Experiments covered different engine loads and injection pressures. The relationships between the ion current, combustion parameters and engine out NO emissions and opacity are presented. The analysis of the experimental data identified possible sources of the ion current produced in diesel engines.


Author(s):  
Eric Bermudez ◽  
Andrew McDaniel ◽  
Terrence Dickerson ◽  
Dianne Luning Prak ◽  
Len Hamilton ◽  
...  

A new hydroprocessed depolymerized cellulosic diesel (HDCD) fuel has been developed using a process which takes biomass feedstock (principally cellulosic wood) to produce a synthetic fuel that has nominally ½ cycloparaffins and ½ aromatic hydrocarbons in content. This HDCD fuel with a low cetane value (derived cetane number from the ignition quality tester, DCN = 27) was blended with naval distillate fuel (NATO symbol F-76) in various quantities and tested in order to determine how much HDCD could be blended before diesel engine operation becomes problematic. Blends of 20% HDCD (DCN = 45), 30%, 40% (DCN = 41), and 60% HDCD (DCN = 37) by volume were tested with conventional naval distillate fuel (DCN = 49). Engine start performance was evaluated with a conventional mechanically direct injected (DI) Yanmar engine and a Waukesha mechanical indirect injected (IDI) Cooperative Fuels Research (CFR) diesel engine and showed that engine start times increased steadily with increasing HDCD content. Longer start times with increasing HDCD content were the result of some engine cycles with poor combustion leading to a slower rate of engine acceleration toward rated speed. A repeating sequence of alternating cycles which combust followed by a noncombustion cycle was common during engine run-up. Additionally, steady-state engine testing was also performed using both engines. HDCD has a significantly higher bulk modulus than F76 due to its very high aromatic content, and the engines showed earlier start of injection (SOI) timing with increasing HDCD content for equivalent operating conditions. Additionally, due to the lower DCN, the higher HDCD blends showed moderately longer ignition delay (IGD) with moderately shorter overall burn durations. Thus, the midcombustion metric (CA50: 50% burn duration crank angle position) was only modestly affected with increasing HDCD content. Increasing HDCD content beyond 40% leads to significantly longer start times.


Author(s):  
Biplab K. Debnath ◽  
Ujjwal K. Saha ◽  
Niranjan Sahoo

Palm Oil Methyl Ester (POME) is a very promising alternative renewable biofuel. This is because it has a better cetane number and a comparable lower calorific value with respect to its competitors. However, due to difference in molecular composition and hence dissimilar properties, it does not perform proficiently in diesel engine with standard design and operating parameters. Therefore, a study is arranged to realize the effect of compression ratio variation on POME run in diesel engine. The load is varied from ‘no load’ to ‘full load’ with six equal intervals. During this study, standard diesel injection timing is maintained unaffected. The study conveys that at higher compression ratio, POME causes reduction in brake fuel consumption and thereby increases the engine efficiency. The increase in compression ratio also causes smoother combustion, lower ignition delay with early heat release than diesel operation. The detrimental emission quantities in the form of carbon monoxide, oxides of nitrogen and hydrocarbon emissions are also cut down with presence of POME in the diesel engine at high compression ratio. Thus, POME can be regarded as a good alternative fuel for diesel engine for locomotive applications.


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