Transient Performance of Micro-Tubular Solid Oxide Fuel Cells

Author(s):  
Katie S. Howe ◽  
Kevin Kendall

The transient performance of microtubular solid oxide fuel cells was investigated, with promising results. It was found that a single cell can take less than half a second to adjust to load changes, even when the change steps across the majority of the cell’s range. In addition, no undershooting of the voltage step was seen in these tests. When steps of equal size were ranged across the current-voltage spectrum, more distortion was seen at the higher voltages. Cells with cathodes applied by dip-coating (instead of brush-painting) were then dynamically tested in a similar way. Their transient performance was significantly weaker, with visible undershooting and longer re-adjustment times of 10–15 s. This is thought to be due to the difference in the microstructure of the cathode layers made by the different coating methods.

2008 ◽  
Vol 13 (12) ◽  
pp. 1905-1911 ◽  
Author(s):  
R. Z. Liu ◽  
S. R. Wang ◽  
Bo Huang ◽  
C. H. Zhao ◽  
J. L. Li ◽  
...  

2016 ◽  
Vol 685 ◽  
pp. 776-780
Author(s):  
Andrey A. Solovyev ◽  
Anastasya N. Kovalchuk ◽  
Igor V. Ionov ◽  
S.V. Rabotkin ◽  
Anna V. Shipilova ◽  
...  

Reducing the operating temperature of solid oxide fuel cells (SOFCs) from 800-1000°C is one of the main SOFC research goals. It can be achieved by lowering the thickness of an electrolyte (ZrO2:Y2O3 (YSZ) is widely used as electrolyte material). On the other hand the problem can be solved by using of another electrolyte material with high ionic conductivity at intermediate temperatures. Therefore the present study deals with magnetron sputtering of ceria gadolinium oxide (CGO), which has a higher conductivity compared to YSZ. The microstructure of CGO layers deposited on porous NiO/YSZ substrates by reactive magnetron sputtering of Ce:Gd cathode is investigated. Current voltage characteristics (CVC) of a fuel cell with NiO/YSZ anode, CGO electrolyte and LSCF/CGO cathode were obtained. It was shown that the power density of a fuel cell with CGO electrolyte weakly depends on the operating temperature in the range of 650-750°C in contradistinction to YSZ electrolyte, and is about 600-650 mW/cm2.


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