Rheology of Lubricants in Real Bearing Contacts

1975 ◽  
Vol 97 (2) ◽  
pp. 228-235 ◽  
Author(s):  
J. W. Kannel ◽  
S. S. Bupara

Experimental traction-slip and lubricant film-thickness data have been determined for selected lubricants to provide information for use in conjunction with the design of lubricated machine elements. The traction-slip experiments were performed using a rolling-disk rheometer which closely simulates those conditions existent in real lubricated contacts; the film-thickness data were obtained using an X-ray technique. The range of experimental conditions included two rolling speeds (5000 and 10,000 rpm), several contact pressures [(690 – 2400 MN/m2) (100 to 350 ksi)], and three temperatures [(338, 366 and 423 K) (150, 200, and 300 F)]. The slip conditions imposed on the lubricants ranged as high as 6 m/s (1200 fpm) which is equivalent to a shear rate of approximately 0.5 × 108 sec−1. Interpretative analyses have been developed to infer basic lubricant properties from the experimental data. These analyses include time delay parameters and “dynamic” pressure-viscosity parameters. The analytical treatment of the data provides: (1) a generalization of the experimental data to apply over a wider range of conditions than those actually covered, and (2) a basis for comparing lubricants and obtaining a more fundamental understanding of lubricant behavior.

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2518
Author(s):  
Dorota Kołodyńska ◽  
Yongming Ju ◽  
Małgorzata Franus ◽  
Wojciech Franus

The possibility of application of chitosan-modified zeolite as sorbent for Cu(II), Zn(II), Mn(II), and Fe(III) ions and their mixtures in the presence of N-(1,2-dicarboxyethyl)-D,L-aspartic acid, IDHA) under different experimental conditions were investigated. Chitosan-modified zeolite belongs to the group of biodegradable complexing agents used in fertilizer production. NaP1CS as a carrier forms a barrier to the spontaneous release of the fertilizer into soil. The obtained materials were characterized by Fourier transform infrared spectroscopy (FTIR); surface area determination (ASAP); scanning electron microscopy (SEM-EDS); X-ray fluorescence (XRF); X-ray diffraction (XRD); and carbon, hydrogen, and nitrogen (CHN), as well as thermogravimetric (TGA) methods. The concentrations of Cu(II), Zn(II), Mn(II), and Fe(III) complexes with IDHA varied from 5–20 mg/dm3 for Cu(II), 10–40 mg/dm3 for Fe(III), 20–80 mg/dm3 for Mn(II), and 10–40 mg/dm3 for Zn(II), respectively; pH value (3–6), time (1–120 min), and temperature (293–333 K) on the sorption efficiency were tested. The Langmuir, Freundlich, Dubinin–Radushkevich, and Temkin adsorption models were applied to describe experimental data. The pH 5 proved to be appropriate for adsorption. The pseudo-second order and Langmuir models were consistent with the experimental data. The thermodynamic parameters indicate that adsorption is spontaneous and endothermic. The highest desorption percentage was achieved using the HCl solution, therefore, proving that method can be used to design slow-release fertilizers.


2005 ◽  
Vol 127 (4) ◽  
pp. 890-892 ◽  
Author(s):  
I. Křupka ◽  
M. Hartl ◽  
M. Liška

Recent numerical results have indicated that the relationship between the film thickness and the speed may not always follow the simple power law, especially under severe conditions. This paper is aimed at obtaining experimental results at high contact stresses and low speeds to study the thin film behavior. Ultrathin lubricant films were observed at maximum Hertz pressures of 0.52, 1.01, and 1.54 GPa by using an optical test rig. Central and minimum film thickness values were obtained with thin film colorimetric interferometry from chromatic interferograms. The nonlinear behavior of both central and minimum film thicknesses in log-log coordinates was observed as rolling speed and thereby film thickness decreased. This tendency became more obvious at higher contact pressures.


2003 ◽  
Vol 36 (1) ◽  
pp. 154-157 ◽  
Author(s):  
F. Bocquet ◽  
P. Gergaud ◽  
O. Thomas

The diffraction of X-rays by a thin layer (of the order of a few nanometres) with a gradient in interplanar spacings is considered. It is shown that optical coherence over the film thickness leads to diffraction peak positions that no longer obey Bragg's law. Although a fitting of the diffracted intensity is indeed still possible, this has direct consequences on the applicability of more straightforward analysis methods, such as the sin2ψ method, which rely on diffraction peak positions. The intensity and peak position calculations are supported by a comparison with experimental data from a (001) Fe/GaAs thin (3 nm) epitaxic film.


Author(s):  
N. J. Zaluzec

The ultimate sensitivity of microchemical analysis using x-ray emission rests in selecting those experimental conditions which will maximize the measured peak-to-background (P/B) ratio. This paper presents the results of calculations aimed at determining the influence of incident beam energy, detector/specimen geometry and specimen composition on the P/B ratio for ideally thin samples (i.e., the effects of scattering and absorption are considered negligible). As such it is assumed that the complications resulting from system peaks, bremsstrahlung fluorescence, electron tails and specimen contamination have been eliminated and that one needs only to consider the physics of the generation/emission process.The number of characteristic x-ray photons (Ip) emitted from a thin foil of thickness dt into the solid angle dΩ is given by the well-known equation


Author(s):  
K.B. Reuter ◽  
D.B. Williams ◽  
J.I. Goldstein

In the Fe-Ni system, although ordered FeNi and ordered Ni3Fe are experimentally well established, direct evidence for ordered Fe3Ni is unconvincing. Little experimental data for Fe3Ni exists because diffusion is sluggish at temperatures below 400°C and because alloys containing less than 29 wt% Ni undergo a martensitic transformation at room temperature. Fe-Ni phases in iron meteorites were examined in this study because iron meteorites have cooled at slow rates of about 10°C/106 years, allowing phase transformations below 400°C to occur. One low temperature transformation product, called clear taenite 2 (CT2), was of particular interest because it contains less than 30 wtZ Ni and is not martensitic. Because CT2 is only a few microns in size, the structure and Ni content were determined through electron diffraction and x-ray microanalysis. A Philips EM400T operated at 120 kV, equipped with a Tracor Northern 2000 multichannel analyzer, was used.


Author(s):  
D.E. Jesson ◽  
S. J. Pennycook

It is well known that conventional atomic resolution electron microscopy is a coherent imaging process best interpreted in reciprocal space using contrast transfer function theory. This is because the equivalent real space interpretation involving a convolution between the exit face wave function and the instrumental response is difficult to visualize. Furthermore, the crystal wave function is not simply related to the projected crystal potential, except under a very restrictive set of experimental conditions, making image simulation an essential part of image interpretation. In this paper we present a different conceptual approach to the atomic imaging of crystals based on incoherent imaging theory. Using a real-space analysis of electron scattering to a high-angle annular detector, it is shown how the STEM imaging process can be partitioned into components parallel and perpendicular to the relevant low index zone-axis.It has become customary to describe STEM imaging using the analytical treatment developed by Cowley. However, the convenient assumption of a phase object (which neglects the curvature of the Ewald sphere) fails rapidly for large scattering angles, even in very thin crystals. Thus, to avoid unpredictive numerical solutions, it would seem more appropriate to apply pseudo-kinematic theory to the treatment of the weak high angle signal. Diffraction to medium order zero-layer reflections is most important compared with thermal diffuse scattering in very thin crystals (<5nm). The electron wave function ψ(R,z) at a depth z and transverse coordinate R due to a phase aberrated surface probe function P(R-RO) located at RO is then well described by the channeling approximation;


2019 ◽  
Vol 13 (3) ◽  
pp. 5513-5527
Author(s):  
J. W. Tee ◽  
S. H. Hamdan ◽  
W. W. F. Chong

Fundamental understanding of piston ring-pack lubrication is essential in reducing engine friction. This is because a substantial portion of engine frictional losses come from piston-ring assembly. Hence, this study investigates the tribological impact of different piston ring profiles towards engine in-cylinder friction. Mathematical models are derived from Reynolds equation by using Reynolds’ boundary conditions to generate the contact pressure distribution along the complete piston ring-pack/liner conjunction. The predicted minimum film thickness is then used to predict the friction generated between the piston ring-pack and the engine cylinder liner. The engine in-cylinder friction is predicted using Greenwood and Williamson’s rough surface contact model. The model considers both the boundary friction and the viscous friction components. These mathematical models are integrated to simulate the total engine in-cylinder friction originating from the studied piston ring-pack for a complete engine cycle. The predicted minimum film thickness and frictional properties from the current models are shown to correlate reasonably with the published data. Hence, the proposed mathematical approach prepares a simplistic platform in predicting frictional losses of piston ring-pack/liner conjunction, allowing for an improved fundamental understanding of the parasitic losses in an internal combustion engine.


Author(s):  
Ivan Saenko ◽  
O. Fabrichnaya

AbstractThermodynamic parameters were assessed for the MgO–FeOx system and combined with already available descriptions of ZrO2-FeOx and ZrO2-MgO systems to calculate preliminary phase diagrams for planning experimental investigations. Samples of selected compositions were heat treated at 1523, 1673 and 1873 K and characterized using x-ray and scanning electron microscopy combined with energy dispersive x-ray spectroscopy (SEM/EDX). Experiments indicated extension of cubic ZrO2 solid solution into the ternary system at 1873 K (75 mol.% ZrO2, 10 mol.% FeOx and 15 mol.% MgO) and limited solubility of 4 mol.% ZrO2 in spinel phase. Based on the obtained results thermodynamic parameters of C-ZrO2 and spinel phase were optimized.


Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 510
Author(s):  
Yongqiang Pan ◽  
Huan Liu ◽  
Zhuoman Wang ◽  
Jinmei Jia ◽  
Jijie Zhao

SiO2 thin films are deposited by radio frequency (RF) plasma-enhanced chemical vapor deposition (PECVD) technique using SiH4 and N2O as precursor gases. The stoichiometry of SiO2 thin films is determined by the X-ray photoelectron spectroscopy (XPS), and the optical constant n and k are obtained by using variable angle spectroscopic ellipsometer (VASE) in the spectral range 380–1600 nm. The refractive index and extinction coefficient of the deposited SiO2 thin films at 500 nm are 1.464 and 0.0069, respectively. The deposition rate of SiO2 thin films is controlled by changing the reaction pressure. The effects of deposition rate, film thickness, and microstructure size on the conformality of SiO2 thin films are studied. The conformality of SiO2 thin films increases from 0.68 to 0.91, with the increase of deposition rate of the SiO2 thin film from 20.84 to 41.92 nm/min. The conformality of SiO2 thin films decreases with the increase of film thickness, and the higher the step height, the smaller the conformality of SiO2 thin films.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Kahina Bouhadjra ◽  
Wahiba Lemlikchi ◽  
Azedine Ferhati ◽  
Samuel Mignard

AbstractIn the present study, the potato peel waste (PP) was used for the removal of the anionic dye Cibacron Blue P3R from an aqueous solution, activated with phosphoric acid (PPa) and calcined at 800 °C (PPc). The materials were characterized by Scanning Electron Microscope, Energy dispersive X-ray analysis and Fourier Transform Infrared Spectroscopy. The effects of various experimental parameters (pH, dye concentration, contact time) were also studied. The experimental results have shown that PPc has a greater capacity compared to pp and ppa. The capacity of PP bio-char (PPc) is 270.3 mg g−1 compared to PP (100 mg g−1) and PPa (125 mg g−1). Equilibrium experiments at 180 min for all materials were carried out at optimum pH (2.2): 76.41, 88.6 and 94% for PP, PPa and PPc respectively; and the Langmuir models agreed very well with experimental data. The ability of sorbent for the sorption of CB dye follows this order: calcined > activated > native materials. Potato peel biochar (PPc) can be considered a promising adsorbent for removing persistent dyes from water.


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