Discussion: “Experimental and Theoretical Studies of Two-Dimensional Fixed-Type Cavities” (Furness, R. A., and Hutton, S. P., 1975, ASME J. Fluids Eng., 97, pp. 515–521)

1975 ◽  
Vol 97 (4) ◽  
pp. 521-521
Author(s):  
T. Y. Wu
Keyword(s):  
Theoretical Studies ◽  
Two Dimensional ◽  
Fixed Type ◽  
Experimental And Theoretical Studies

Experimental and Theoretical Studies of Two-Dimensional Fixed-Type Cavities

1975 ◽  
Vol 97 (4) ◽  
pp. 515-521 ◽  
Author(s):  
R. A. Furness ◽  
S. P. Hutton
Keyword(s):  
Potential Flow ◽  
Reasonable Agreement ◽  
Experimental Studies ◽  
Liquid Jet ◽  
Theoretical Studies ◽  
Two Dimensional ◽  
Nozzle Throat ◽  
Jet Behavior ◽  
Fixed Type ◽  
Experimental And Theoretical Studies

Theoretical and experimental studies have been made of the growth and collapse of fixed cavities in a two-dimensional convergent-divergent nozzle. In this particular configuration an important feature was a re-entrant liquid jet which invaded the growing cavity from the downstream end, travelling upstream along the wall and interrupting the cavity when it reached the nozzle throat. A simple two-dimensional unsteady potential flow theory, developed to model the cycle, gave reasonable agreement with cinephotography and predicted the jet behavior. Because vaporization was neglected the theory overestimated the speed of the cycle.

scholarly journals Piezoelectric property comparison of two-dimensional ZnO nanostructures for energy harvesting devices

RSC Advances ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 3363-3370
Author(s):  
Ang Yang ◽  
Yu Qiu ◽  
Dechao Yang ◽  
Kehong Lin ◽  
Shiying Guo
Keyword(s):  
Energy Harvesting ◽  
Piezoelectric Property ◽  
Piezoelectric Effect ◽  
Theoretical Studies ◽  
Two Dimensional ◽  
Zno Nanostructures ◽  
Energy Harvesting Devices ◽  
Experimental And Theoretical Studies

In this paper, experimental and theoretical studies of the piezoelectric effect of two-dimensional ZnO nanostructures, including straight nanosheets (SNSs) and curved nanosheets (CNSs) are conducted.

The Stabilizing Effect of Pre-Equilibria: A Trifluoromethyl Complex as CF2 Reservoir in Catalytic Olefin Difluorocarbenation

2020 ◽  
Author(s):  
Thomas Louis-Goff ◽  
Huu Vinh Trinh ◽  
Eileen Chen ◽  
Arnold L. Rheingold ◽  
Christian Ehm ◽  
...  
Keyword(s):  
High Selectivity ◽  
Side Reactions ◽  
Theoretical Studies ◽  
Attractive Feature ◽  
Catalyst Recovery ◽  
Wide Range ◽  
Stabilizing Effect ◽  
Experimental And Theoretical Studies

A new, efficient, catalytic difluorocarbenation of olefins to give 1,1-difluorocyclopropanes is presented. The catalyst, an organobismuth complex, uses TMSCF<sub>3</sub> as a stoichiometric difluorocarbene source. We demonstrate both the viability and robustness of this reaction over a wide range of alkenes and alkynes, including electron-poor alkenes, to generate the corresponding 1,1-difluorocyclopropanes and 1,1-difluorocyclopropenes. Ease of catalyst recovery from the reaction mixture is another attractive feature of this method. In depth experimental and theoretical studies showed that the key difluorocarbene-generating step proceeds through a bismuth non-redox synchronous mechanism generating a highly reactive free CF<sub>2</sub> in an endergonic pre-equilibrium. It is the reversibility when generating the difluorocarbene that accounts for the high selectivity, while minimizing CF<sub>2</sub>-recombination side-reactions.

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