Influence of Gas Turbine Combustor Design and Operating Parameters on Effectiveness of NOx Suppression by Injected Steam or Water

1985 ◽  
Vol 107 (3) ◽  
pp. 706-713 ◽  
Author(s):  
G. L. Touchton

Steam or water injection has become the state-of-the-art abatement technique for NOx, with steam strongly preferred for combined-cycle application. In combined-cycle plants, the degradation of the plant efficiency due to steam injection into the gas turbine combustor provides a powerful incentive for minimizing this flow over the entire plant operating map. This paper presents the results of extensive tests carried out on a variety of gas turbine combustor designs. Both test stand and field test data are presented. The usual fuel in the tests is methane; however, some data are presented for combustion of No. 2 distillate oil and intermediate Btu gas fuel. Similarly, the usual inert injected is steam, but some water injection data are included for comparison. The results support the conclusions: 1. Steam and water injection suppress NOx exclusively through thermal mechanisms, i.e., by lowering the peak flame temperature. 2. Design changes have little effect on NOx suppression effectiveness of steam or water in jet-stirred or swirl-mixed combustors. 3. Primary zone injection of steam in methane-fueled, jet-stirred combustors is equally effective whether the steam enters with an air stream or with the fuel stream. 4. Water-to-fuel ratio corrected to equivalent energy content correlates NOx suppression effectiveness for turbulent diffusion flame combustors.

Author(s):  
G. L. Touchton

Steam or water injection has become the state-of-the-art abatement technique for NOx, with steam strongly preferred for combined-cycle application. In combined-cycle plants, the degradation of the plant efficiency due to steam injection into the gas turbine combustor provides a powerful incentive for minimizing this flow over the entire plant operating map. This paper presents the results of extensive tests carried out on a variety of gas turbine combustor designs. Both test stand and field test data are presented. The usual fuel in the tests is methane; however, some data are presented for combustion of No. 2 distillate oil and intermediate Btu gas fuel. Similarly, the usual inert injected is steam, but some water injection data are included for comparison. The results support the conclusions: 1. Steam and water injection suppress NOx exclusively through thermal mechanisms, i.e., by lowering the peak flame temperature. 2. Design changes have little effect on NOx suppression effectiveness of steam or water in jet-stirred or swirl-mixed combustors. 3. Primary zone injection of steam in methane-fueled, jet-stirred combustors is equally effective whether the steam enters with an air stream or with the fuel stream. 4. Water-to-fuel ratio corrected to equivalent energy content correlates NOx suppression effectiveness for turbulent diffusion flame combustors.


1995 ◽  
Vol 117 (4) ◽  
pp. 673-677 ◽  
Author(s):  
C. S. Cook ◽  
J. C. Corman ◽  
D. M. Todd

The integration of gas turbines and combined cycle systems with advances in coal gasification and gas stream cleanup systems will result in economically viable IGCC systems. Optimization of IGCC systems for both emission levels and cost of electricity is critical to achieving this goal. A technical issue is the ability to use a wide range of coal and petroleum-based fuel gases in conventional gas turbine combustor hardware. In order to characterize the acceptability of these syngases for gas turbines, combustion studies were conducted with simulated coal gases using full-scale advanced gas turbine (7F) combustor components. It was found that NOx emissions could be correlated as a simple function of stoichiometric flame temperature for a wide range of heating values while CO emissions were shown to depend primarily on the H2 content of the fuel below heating values of 130 Btu/scf (5125 kJ/NM3) and for H2/CO ratios less than unity. The test program further demonstrated the capability of advanced can-annular combustion systems to burn fuels from air-blown gasifiers with fuel lower heating values as low as 90 Btu/scf (3548 kJ/NM3) at 2300°F (1260°C) firing temperature. In support of ongoing economic studies, numerous IGCC system evaluations have been conducted incorporating a majority of the commercial or near-commercial coal gasification systems coupled with “F” series gas turbine combined cycles. Both oxygen and air-blown configurations have been studied, in some cases with high and low-temperature gas cleaning systems. It has been shown that system studies must start with the characteristics and limitations of the gas turbine if output and operating economics are to be optimized throughout the range of ambient operating temperature and load variation.


1975 ◽  
Vol 97 (4) ◽  
pp. 610-618
Author(s):  
D. A. Sullivan

The pressure, temperature, and fuel-to-air ratio of a gas turbine combustor vary with ambient conditions, machine speed, and load. Only a few of these parameters are independent. An analysis has been developed which predicts the combustor operating parameters. The analysis includes low heating value fuel combustion, water injection, and three modes of steam injection. The analysis is used to predict the combustor operation for a simple-cycle gas turbine, but it is not restricted to this case. In addition, a simplified analysis is deduced and shown to be surprisingly accurate. Special solutions are presented which permit direct calculation of the firing temperatures, fuel heating value, or air extraction required to achieve a specified compressor pressure ratio. Finally, the analysis is compared with experimental results.


Author(s):  
Olav Bolland ◽  
Jan Fredrik Stadaas

Combined cycles have gained widespread acceptance as the most efficient utilization of the gas turbine for power generation, particularly for large plants. A variety of alternatives to the combined cycle that recover exhaust gas heat for re-use within the gas turbine engine have been proposed and some have been commercially successful in small to medium plants. Most notable has been the steam injected, high-pressure aero-derivatives in sizes up to about 50 MW. Many permutations and combinations of water injection, steam injection, and recuperation, with or without intercooling, have been shown to offer the potential for efficiency improvements in certain ranges of gas turbine cycle design parameters. A detailed, general model that represents the gas turbine with turbine cooling has been developed. The model is intended for use in cycle analysis applications. Suitable choice of a few technology description parameters enables the model to accurately represent the performance of actual gas turbine engines of different technology classes. The model is applied to compute the performance of combined cycles as well as that of three alternatives. These include the simple cycle, the steam injected cycle and the dual-recuperated intercooled aftercooled steam injected cycle (DRIASI cycle). The comparisons are based on state-of-the-art gas turbine technology and cycle parameters in four classes: large industrial (123–158 MW), medium industrial (38–60 MW), aeroderivatives (21–41 MW) and small industrial (4–6 MW). The combined cycle’s main design parameters for each size range are in the present work selected for computational purposes to conform with practical constraints. For the small systems, the proposed development of the gas turbine cycle, the DRIASI cycle, are found to provide efficiencies comparable or superior to combined cycles, and superior to steam injected cycles. For the medium systems, combined cycles provide the highest efficiencies but can be challenged by the DRIASI cycle. For the largest systems, the combined cycle was found to be superior to all of the alternative gas turbine based cycles considered in this study.


Author(s):  
C. S. Cook ◽  
J. C. Corman ◽  
D. M. Todd

The integration of gas turbines and combined cycle systems with advances in coal gasification and gas stream cleanup systems will result in economically viable IGCC systems. Optimization of IGCC systems for both emission levels and cost of electricity is critical to achieving this goal. A technical issue is the ability to use a wide range of coal and petroleum-based fuel gases in conventional gas turbine combustor hardware. In order to characterize the acceptability of these syngases for gas turbines, combustion studies were conducted with simulated coal gases using full scale advanced gas turbine (7F) combustor components. It was found that NOx emissions could be correlated as a simple function of stoichiometric flame temperature for a wide range of heating values while CO emissions were shown to depend primarily on the H2 content of the fuel below heating values of 130 Btu/scf (5125 kJ/NM3) and for H2/CO ratios less than unity. The test program further demonstrated the capability of advanced can-annular combustion systems to burn fuels from air-blown gasifiers with fuel lower heating values as low as 90 Btu/scf (3548 kJ/NM3) at 2300 F (1260 C) firing temperature. In support of ongoing economic studies, numerous IGCC system evaluations have been conducted incorporating a majority of the commercial or near commercial coal gasification systems coupled with “F” series gas turbine combined cycles. Both oxygen and air-blown configurations have been studied, in some cases with high and low temperature gas cleaning systems. It has been shown that system studies must start with the characteristics and limitations of the gas turbine if output and operating economics are to be optimized throughout the range of ambient operating temperature and load variation.


Author(s):  
A. Schwärzle ◽  
T. O. Monz ◽  
M. Aigner

Using gas turbines for waste gas treatment is a promising technology compared to other thermal oxidizing systems in terms of total efficiency, due to the combined heat and power production. In this work, experiments have been carried out where an air stream containing volatile organic compounds (VOCs) is fed to a micro gas turbine combustor which is co-fired using natural gas. All experiments were conducted at atmospheric pressure. For lower preheat temperatures, the equivalence ratio of the pilot stage was step-wise increased at constant global air to fuel ratios to further extend the operation limit. The VOC destruction efficiency of the burner is analyzed for various oxygenated VOCs and concentrations with a maximum lower heating value of the VOC containing air stream of 0.25 MJ/Nm3. The stability range of the burner is presented for various equivalence ratios with a global volumetric heat release up to 33 MW/m3 and air preheat temperatures up to 650 °C. The flame is analyzed in terms of shape, length and lift-off height, using the OH* chemiluminescence signal detected by an ICCD-camera. At same air numbers, changes on the flame are insignificant to the different VOCs in most cases. Regarding the emissions of NOx, the VOC containing air is beneficial at all air numbers, while a decrease in CO is only observed for lower air numbers. A minimum of CO emissions for both preheat temperatures is obtained at an adiabatic flame temperature of 1671 K.


1995 ◽  
Vol 117 (1) ◽  
pp. 138-145 ◽  
Author(s):  
O. Bolland ◽  
J. F. Stadaas

Combined cycles have gained widespread acceptance as the most efficient utilization of the gas turbine for power generation, particularly for large plants. A variety of alternatives to the combined cycle that recover exhaust gas heat for re-use within the gas turbine engine have been proposed and some have been commercially successful in small to medium plants. Most notable have been the steam-injected, high-pressure aeroderivatives in sizes up to about 50 MW. Many permutations and combinations of water injection, steam injection, and recuperation, with or without intercooling, have been shown to offer the potential for efficiency improvements in certain ranges of gas turbine cycle design parameters. A detailed, general model that represents the gas turbine with turbine cooling has been developed. The model is intended for use in cycle analysis applications. Suitable choice of a few technology description parameters enables the model to represent accurately the performance of actual gas turbine engines of different technology classes. The model is applied to compute the performance of combined cycles as well as that of three alternatives. These include the simple cycle, the steam-injected cycle, and the dual-recuperated intercooled aftercooled steam-injected cycle (DRIASI cycle). The comparisons are based on state-of-the-art gas turbine technology and cycle parameters in four classes: large industrial (123–158 MW), medium industrial (38–60 MW), aeroderivatives (21–41 MW), and small industrial (4–6 MW). The combined cycle’s main design parameters for each size range are in the present work selected for computational purposes to conform with practical constraints. For the small systems, the proposed development of the gas turbine cycle, the DRIASI cycle, are found to provide efficiencies comparable or superior to combined cycles, and superior to steam-injected cycles. For the medium systems, combined cycles provide the highest efficiencies but can be challenged by the DRIASI cycle. For the largest systems, the combined cycle was found to be superior to all of the alternative gas turbine based cycles considered in this study.


Author(s):  
Thormod Andersen ◽  
Hanne M. Kvamsdal ◽  
Olav Bolland

A concept for capturing and sequestering CO2 from a natural gas fired combined cycle power plant is presented. The present approach is to decarbonise the fuel prior to combustion by reforming natural gas, producing a hydrogen-rich fuel. The reforming process consists of an air-blown pressurised auto-thermal reformer that produces a gas containing H2, CO and a small fraction of CH4 as combustible components. The gas is then led through a water gas shift reactor, where the equilibrium of CO and H2O is shifted towards CO2 and H2. The CO2 is then captured from the resulting gas by chemical absorption. The gas turbine of this system is then fed with a fuel gas containing approximately 50% H2. In order to achieve acceptable level of fuel-to-electricity conversion efficiency, this kind of process is attractive because of the possibility of process integration between the combined cycle and the reforming process. A comparison is made between a “standard” combined cycle and the current process with CO2-removal. This study also comprise an investigation of using a lower pressure level in the reforming section than in the gas turbine combustor and the impact of reduced steam/carbon ratio in the main reformer. The impact on gas turbine operation because of massive air bleed and the use of a hydrogen rich fuel is discussed.


Author(s):  
Anoop Kumar Shukla ◽  
Onkar Singh

Gas/steam combined cycle power plants are extensively used for power generation across the world. Today’s power plant operators are persistently requesting enhancement in performance. As a result, the rigour of thermodynamic design and optimization has grown tremendously. To enhance the gas turbine thermal efficiency and specific power output, the research and development work has centered on improving firing temperature, cycle pressure ratio, adopting improved component design, cooling and combustion technologies, and advanced materials and employing integrated system (e.g. combined cycles, intercooling, recuperation, reheat, chemical recuperation). In this paper a study is conducted for combining three systems namely inlet fogging, steam injection in combustor, and film cooling of gas turbine blade for performance enhancement of gas/steam combined cycle power plant. The evaluation of the integrated effect of inlet fogging, steam injection and film cooling on the gas turbine cycle performance is undertaken here. Study involves thermodynamic modeling of gas/steam combined cycle system based on the first law of thermodynamics. The results obtained based on modeling have been presented and analyzed through graphical depiction of variations in efficiency, specific work output, cycle pressure ratio, inlet air temperature & density variation, turbine inlet temperature, specific fuel consumption etc.


Author(s):  
Sebastian Harder ◽  
Franz Joos

The combustion process in a typical can combustor of an industrial gas turbine is determined by the nature of turbulent flow, the chemical reaction and the interaction with each other. Turbulent non-premixed combustion can be divided into different flame regimes in terms of time- and length scales. A typical non-premixed turbulent diffusion flame in a gas turbine combustor covers all regimes. PDF methods are suitable to describe the entire combustion regime without any limitation to a certain regime. In this paper a hybrid pdf/RANS method is presented. The pdf model is based on the transported composition pdf equation, coupled with a commercial three dimensional CFD solver. A stochastic particle system in a Lagrangian framework is used to solve the pdf equation. The chemistry is described by an ILDM approach. The numerical results have been validated with measurements. The test rig consists of an non-premixed gas turbine can combustor with a typical primary and secondary zone. A main air swirler stabilizes the natural gas/air mixture in the primary zone, followed by a burnout and a mixing zone. The setup is investigated using conventional measurement techniques. Field measurements of compositions and mixture fraction as well as temperature are compared with the pdf/RANS calculations. The benefit of this approach is a realistic prediction of all relevant species. The complete one point statistics of the numerical calculations are used to identify the different combustion regimes from the combustor to the exit. The numerical comparison of pdf-, edm- and flamelet-model shows that the pdf approach can be used to describe a realistic gas turbine combustor. In the past, pdf-methods were applied only on simple generic model flames. The purpose of the presented paper is to demonstrate the application of a transported-pdf approach to a realistic gas turbine combustor.


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