The Experimental Behavior of Premixed Flames in Tubes: The Effects of Diluent Gases

1980 ◽  
Vol 102 (2) ◽  
pp. 422-426 ◽  
Author(s):  
J. Odgers ◽  
I. White ◽  
D. Kretschmer
Keyword(s):  
Carbon Dioxide ◽  
Transport Properties ◽  
Gas Turbine ◽  
Reaction Rate ◽  
Laminar Flame ◽  
Laminar Flame Speed ◽  
Gaseous Fuels ◽  
Gas Transport Properties ◽  
The Stability ◽  
Stability Limits

One of the problems facing gas turbine users is the proliferation of gaseous fuels which may be available. These are so many that a comprehensive rig/engine study would be far too costly to undertake. The present studies represent an attempt to quantify the behavior of such fuels, in a simple environment. Measurements of the rates of flame travel and the stability limits have been made for propane/oxygen mixtures diluted with nitrogen, carbon dioxide, helium or argon. The results have been used to forecast the laminar flame speed of mixtures, and rates of flame travel for the various mixtures have been correlated with groups representative of reaction rate and gas transport properties.

A Generalized Presentation of Gas-Turbine Combustor Performance

1957 ◽  
Author(s):  
A. E. Noreen ◽  
W. T. Martin
Keyword(s):  
Experimental Data ◽  
Gas Turbine ◽  
Dimensional Analysis ◽  
Combustion Rate ◽  
Laminar Flame ◽  
Empirical Evaluation ◽  
Combustion Efficiency ◽  
Laminar Flame Speed ◽  
Gas Turbine Combustor ◽  
Stability Limits

Experimental data on stability limits and combustion efficiency of a 3-in-diam combustor using gaseous fuel are presented. These data have been correlated by an empirical evaluation of the results of a dimensional analysis. Theories are proposed, based upon the experimental data, regarding combustor-stabilization processes. Laminar flame speed was shown to be a satisfactory index of the influence of base combustion rate on combustor performance.

A Numerical Study on the Reactivity of Biogas/Reformed-Gas/Air and Methane/Reformed-Gas/Air Mixtures at Gas Turbine Relevant Conditions

2016 ◽  
Author(s):  
Pablo Diaz Gomez Maqueo ◽  
Philippe Versailles ◽  
Gilles Bourque ◽  
Jeffrey M. Bergthorson
Keyword(s):  
Gas Turbine ◽  
Laminar Flame ◽  
Numerical Study ◽  
Flame Temperature ◽  
Flame Speed ◽  
Flame Stability ◽  
Laminar Flame Speed ◽  
Fuel Reforming ◽  
Numerical Work ◽  
Chemical Effects

This study investigates the increase in methane and biogas flame reactivity enabled by the addition of syngas produced through fuel reforming. To isolate thermodynamic and chemical effects on the reactivity of the mixture, the burner simulations are performed with a constant adiabatic flame temperature of 1800 K. Compositions and temperatures are calculated with the chemical equilibrium solver of CANTERA® and the reactivity of the mixture is quantified using the adiabatic, freely-propagating premixed flame, and perfectly-stirred reactors of the CHEMKIN-Pro® software package. The results show that the produced syngas has a content of up to 30 % H2 with a temperature up to 950 K. When added to the fuel, it increases the laminar flame speed while maintaining a burning temperature of 1800 K. Even when cooled to 300 K, the laminar flame speed increases up to 30 % from the baseline of pure biogas. Hence, a system can be developed that controls and improves biogas flame stability under low reactivity conditions by varying the fraction of added syngas to the mixture. This motivates future experimental work on reforming technologies coupled with gas turbine exhausts to validate this numerical work.

Evaluation of Kinetic Mechanisms for Direct Fired Supercritical Oxy-Combustion of Natural Gas

2016 ◽  
Author(s):  
Shane Coogan ◽  
Xiang Gao ◽  
Aaron McClung ◽  
Wenting Sun
Keyword(s):  
Carbon Dioxide ◽  
Natural Gas ◽  
San Diego ◽  
Laminar Flame ◽  
Flame Speed ◽  
Laminar Flame Speed ◽  
Validation Data ◽  
Data Set ◽  
Reduced Mechanism ◽  
Kinetic Mechanisms

Existing kinetic mechanisms for natural gas combustion are not validated under supercritical oxy-fuel conditions because of the lack of experimental validation data. Our studies show that different mechanisms have different predictions under supercritical oxy-fuel conditions. Therefore, preliminary designers may experience difficulties when selecting a mechanism for a numerical model. This paper evaluates the performance of existing chemical kinetic mechanisms and produces a reduced mechanism for preliminary designers based on the results of the evaluation. Specifically, the mechanisms considered were GRI-Mech 3.0, USC-II, San Diego 204-10-04, NUIG-I, and NUIG-III. The set of mechanisms was modeled in Cantera and compared against the literature data closest to the application range. The high pressure data set included autoignition delay time in nitrogen and argon diluents up to 85 atm and laminar flame speed in helium diluent up to 60 atm. The high carbon dioxide data set included laminar flame speed with 70% carbon dioxide diluent and the carbon monoxide species profile in an isothermal reactor with up to 95% carbon dioxide diluent. All mechanisms performed adequately against at least one dataset. Among the evaluated mechanisms, USC-II has the best overall performance and is preferred over the other mechanisms for use in the preliminary design of supercritical oxy-combustors. This is a significant distinction; USC-II predicts slower kinetics than GRI-Mech 3.0 and San Diego 2014 at the combustor conditions expected in a recompression cycle. Finally, the global pathway selection method was used to reduce the USC-II model from 111 species, 784 reactions to a 27 species, 150 reactions mechanism. Performance of the reduced mechanism was verified against USC-II over the range relevant for high inlet temperature supercritical oxy-combustion.

scholarly journals Catalytic Influence of Water Vapor on Lean Blowoff and NOx Reduction for Pressurised Swirling Syngas Flames

2017 ◽  
Author(s):  
Daniel Pugh ◽  
Philip Bowen ◽  
Andrew Crayford ◽  
Richard Marsh ◽  
Jon Runyon ◽  
...  
Keyword(s):  
Elevated Temperature ◽  
Reaction Rate ◽  
Catalytic Effect ◽  
Laminar Flame ◽  
Nox Reduction ◽  
Flame Temperature ◽  
Stability Limit ◽  
Flame Speed ◽  
Laminar Flame Speed ◽  
Water Loading

It has become increasingly cost-effective for the steel industry to invest in the capture of heavily carbonaceous BOF (Basic Oxygen Furnace) or converter gas, and use it to support the intensive energy demands of the integrated facility, or for surplus energy conversion in power plants. As industry strives for greater efficiency via ever more complex technologies, increased attention is being paid to investigate the complex behavior of by-product syngases. Recent studies have described and evidenced the enhancement of fundamental combustion parameters such as laminar flame speed due to the catalytic influence of H2O on heavily carbonaceous syngas mixtures. Direct formation of CO2 from CO is slow due to its high activation energy, and the presence of disassociated radical hydrogen facilitates chain branching species (such as OH), changing the dominant path for oxidation. The observed catalytic effect is non-monotonic, with the reduction in flame temperature eventually prevailing, and overall reaction rate quenched. The potential benefits of changes in water loading are explored in terms of delayed lean blowoff, and primary emission reduction in a premixed turbulent swirling flame, scaled for practical relevance at conditions of elevated temperature (423 K) and pressure (0.1–0.3 MPa). Chemical kinetic models are used initially to characterize the influence that H2O has on the burning characteristics of the fuel blend employed, modelling laminar flame speed and extinction strain rate across an experimental range with H2O vapor fraction increased to eventually diminish the catalytic effect. These modelled predictions are used as a foundation to investigate the experimental flame. OH* chemiluminescence and OH planar laser induced fluorescence (PLIF) are employed as optical diagnostic techniques to analyze changes in heat release structure resulting from the experimental variation in water loading. A comparison is made with a CH4/air flame and changes in lean blow off stability limits are quantified, measuring the incremental increase in air flow and again compared against chemical models. The compound benefit of CO and NOx reduction is quantified also, with production first decreasing due to the thermal effect of H2O addition from a reduction in flame temperature, coupled with the potential for further reduction from the change in lean stability limit. Power law correlations have been derived for change in pressure, and equivalent water loading. Hence, the catalytic effect of H2O on reaction pathways and reaction rate predicted and observed for laminar flames, are compared against the challenging environment of turbulent, swirl-stabilized flames at elevated temperature and pressure, characteristic of piratical systems.

Effects of carbon dioxide-induced plasticization on the gas transport properties of glassy polyimide membranes

2007 ◽  
Vol 298 (1-2) ◽  
pp. 147-155 ◽  
Author(s):  
Shinji Kanehashi ◽  
Tsutomu Nakagawa ◽  
Kazukiyo Nagai ◽  
Xavier Duthie ◽  
Sandra Kentish ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Transport Properties ◽  
Gas Transport ◽  
Gas Transport Properties ◽  
Polyimide Membranes

scholarly journals Selected combustion parameters of biogas at elevated pressure–temperature conditions

2012 ◽  
Vol 148 (1) ◽  
pp. 40-47
Author(s):  
Stanisław SZWAJA ◽  
Wojciech TUTAK ◽  
Karol GRAB-ROGALIŃSKI ◽  
Arkadiusz JAMROZIK ◽  
Arkadiusz KOCISZEWSKI
Keyword(s):  
Carbon Dioxide ◽  
Ignition Delay ◽  
Combustion Temperature ◽  
Laminar Flame ◽  
Engine Performance ◽  
Elevated Pressure ◽  
Flame Speed ◽  
Methane Content ◽  
Laminar Flame Speed ◽  
Adiabatic Combustion Temperature

Results from tests conducted in several RTD centers lead to conclusion that biogas as a potential fuel for the internal combustion (IC) spark ignited (SI) engine features with its satisfactory combustion predisposition causing smooth engine run without accidental misfiring or knock events. This good predisposition is obtained due to carbon dioxide (CO2) content in the biogas. On the other hand, carbon dioxide as incombustible gas contribute to decrease in the brake power of the biogas fueled engine. To analyze mutual CO2 and CH4 content on biogas burning the combustion parameters as follows: adiabatic combustion temperature, laminar flame speed and ignition delay of biogas with various methane content were determined and presented in the paper. Additionally, these parameters for pure methane were also included in order to make comparison between each other. As computed, ignition delay, which has is strongly correlated with knock resistance, can change several times with temperature increase, but does not change remarkably with increase in methane content. Adiabatic combustion temperature does not also ought to influence on engine performance or increase in engine cooling and exhaust losses due to its insignificant changes. The largest change was observed in laminar flame speed, that can influence on development of the first premixed combustion phase.

Gas Turbines in Alternative Fuel Applications: How to Predict the Stability of Olefin-Containing Process Gases

2003 ◽  
Author(s):  
P. A. Glaude ◽  
O. Mahier ◽  
V. Warth ◽  
R. Fournet ◽  
M. Moliere ◽  
...  
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Alternative Fuel ◽  
Liquefied Petroleum Gas ◽  
Gaseous Fuels ◽  
Process Gas ◽  
History Of ◽  
Process Gases ◽  
Heavy Duty Gas Turbine ◽  
The Stability

Throughout the history of combustion engines, the Heavy Duty Gas Turbine stands out as the most fuel-flexible prime mover in the field. This gas turbine (GT) is suited for a rich portfolio of gaseous fuels that include: natural gas, liquefied petroleum gas, coal and biomass-derived syngases, and a great variety of process gases with diverse compositions (hydrogen, carbon monoxide, olefins, etc.). Process gas fuels provide a promising array of alternative fuel opportunities in the major sectors of the industry such as the Coal, Oil & Gas, Steel, Chemical and Petrochemical branches. In an increasingly uncertain fuel environment, this significant match between gas turbine capabilities and the energy schemes of industrial plants can lead to further business opportunities.

Assessment of the Role of Fuel Autoignition Delay at the Limits of Gas Turbine Combustion and Ignition

2009 ◽  
Author(s):  
Victor Burger ◽  
Andy Yates ◽  
Nicholas Savage ◽  
Owen Metcalf
Keyword(s):  
Gas Turbine ◽  
Laminar Flame ◽  
Chemical Kinetic ◽  
Jet Fuel ◽  
Laminar Flame Speed ◽  
Lean Blowout ◽  
Boiling Points ◽  
Fuel Evaporation ◽  
Autoignition Delay

The influence of fuel autoignition chemistry is known to be relevant when approaching the limits of lean blowout and lean ignition in a continuous combustion environment. This was investigated by employing four reference fuels having very different autoignition delay profiles but similar boiling points to interrogate various test environments and thereby to assess the relevance of the differences in autoignition chemistry. A combustion bomb apparatus was used to characterize the reference fuels together with a sample of commercial Jet A-1 for comparison. The measurements were cross-checked using a chemical kinetic simulation model. A continuous combustion rig was used to study the threshold ignition and blowout performance of the pre-vaporized reference fuels and a laminar flame speed bomb was used to study the influence of autoignition chemistry on normal, stoichiometric combustion and normal ignition conditions. In all the experiments, the results reflected the distinctive differences of the test fuels in terms of their autoignition delay timescales. The findings were interpreted against the background of the commercial jet fuel autoignition chemistry and the relevance of traditional autoignition delay metrics such as Octane or Cetane rating. Notwithstanding the influence of fuel evaporation and mixing timescales which can exert an overriding influence in a practical, gas turbine application, it was concluded that the fuel’s autoignition delay timescale also plays a very significant role in threshold operational situations.

Ignition Delay Time and Laminar Flame Speed Calculations for Natural Gas/Hydrogen Blends at Elevated Pressures

2012 ◽  
Author(s):  
Marissa Brower ◽  
Eric Petersen ◽  
Wayne Metcalfe ◽  
Henry J. Curran ◽  
Marc Füri ◽  
...  
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Chemical Kinetics ◽  
Ignition Delay ◽  
Ignition Delay Time ◽  
Laminar Flame ◽  
Turbulent Flame ◽  
Flame Speed ◽  
Laminar Flame Speed ◽  
Hydrogen Addition

Applications of natural gas and hydrogen co-firing have received increased attention in the gas turbine market, which aims at higher flexibility due to concerns over the availability of fuels. While much work has been done in the development of a fuels database and corresponding chemical kinetics mechanism for natural gas mixtures, there are nonetheless few if any data for mixtures with high levels of hydrogen at conditions of interest to gas turbines. The focus of the present paper is on gas turbine engines with primary and secondary reaction zones as represented in the Alstom and Rolls Royce product portfolio. The present effort includes a parametric study, a gas turbine model study, and turbulent flame speed predictions. Using a highly optimized chemical kinetics mechanism, ignition delay times and laminar burning velocities were calculated for fuels from pure methane to pure hydrogen and with natural gas/hydrogen mixtures. A wide range of engine-relevant conditions were studied: pressures from 1 to 30 atm, flame temperatures from 1600 to 2200 K, primary combustor inlet temperature from 300 to 900 K, and secondary combustor inlet temperatures from 900 to 1400 K. Hydrogen addition was found to increase the reactivity of hydrocarbon fuels at all conditions by increasing the laminar flame speed and decreasing the ignition delay time. Predictions of turbulent flame speeds from the laminar flame speeds show that hydrogen addition affects the reactivity more when turbulence is considered. This combined effort of industrial and university partners brings together the know-how of applied, as well as experimental and theoretical disciplines.

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