Manufacturing of High-Temperature Polymer Electrolyte Membranes—Part I: System Design and Modeling

Author(s):  
Tequila A. L. Harris ◽  
Daniel F. Walczyk ◽  
Mathias M. Weber

The most important component of the fuel cell is the membrane electrolyte, having the fundamental responsibility of separating protons and electrons. Minor defects (e.g., pin holes) in the film will cause premature and/or catastrophic failure. As such, special attention should be given to the manufacturing of this fuel cell component. Increased interest in identifying and overcoming the technical and manufacturing challenges associated with fuel cells has surfaced over the past few years. To this end, a design methodology, the science, and the technology to manufacture unique high-temperature polymer electrolyte membranes in a uniform and continuous manner are presented, specifically focusing on system conceptualization, design, and modeling. It has been shown that an overall manufacturing system can be designed for a power-law fluid with time-temperature varying properties.

Energies ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 5440 ◽  
Author(s):  
Khadijeh Hooshyari ◽  
Bahman Amini Horri ◽  
Hamid Abdoli ◽  
Mohsen Fallah Vostakola ◽  
Parvaneh Kakavand ◽  
...  

This review summarizes the current status, operating principles, and recent advances in high-temperature polymer electrolyte membranes (HT-PEMs), with a particular focus on the recent developments, technical challenges, and commercial prospects of the HT-PEM fuel cells. A detailed review of the most recent research activities has been covered by this work, with a major focus on the state-of-the-art concepts describing the proton conductivity and degradation mechanisms of HT-PEMs. In addition, the fuel cell performance and the lifetime of HT-PEM fuel cells as a function of operating conditions have been discussed. In addition, the review highlights the important outcomes found in the recent literature about the HT-PEM fuel cell. The main objectives of this review paper are as follows: (1) the latest development of the HT-PEMs, primarily based on polybenzimidazole membranes and (2) the latest development of the fuel cell performance and the lifetime of the HT-PEMs.


Author(s):  
Tequila A. L. Harris ◽  
Daniel F. Walczyk ◽  
Mathias M. Weber

In this paper, a complex system of theoretical models, which predicts flow rate as a function of pressure drop, formulated previously by Harris et al. (2007, “Manufacturing of High-Temperature Polymer Electrolyte Membranes—Part I: System Design and Modeling,” ASME J. Fuel Cell Sci. Technol., 7, p. 011007), are validated through a case study. Specifically, the flow behavior of a power law polymer electrolyte membrane solution, as it flows through a novel manufacturing system, is investigated. It is found that a strategic design methodology can be used to develop a complete manufacturing system to fabricate a defect free film. Moreover, the casting method offers significant improvements for the thickness uniformity of the membrane film, compared with film that is fabricated using scaled laboratory processes. The pressure losses predicted throughout the system are validated accordingly, not only from experimental results but also from computational fluid dynamics modeling.


2019 ◽  
Vol 33 (1) ◽  
pp. 811-822 ◽  
Author(s):  
Joannis K. Kallitsis ◽  
Maria Geormezi ◽  
Nora Gourdoupi ◽  
Fotis Paloukis ◽  
Aikaterini K. Andreopoulou ◽  
...  

2007 ◽  
Vol 129 (13) ◽  
pp. 3879-3887 ◽  
Author(s):  
Kenji Miyatake ◽  
Yohei Chikashige ◽  
Eiji Higuchi ◽  
Masahiro Watanabe

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