Effect of Flue-Gas Impurities on the Process of Injection and Storage of CO2 in Depleted Gas Reservoirs

2008 ◽  
Vol 130 (1) ◽  
Author(s):  
Marjorie Nogueira ◽  
Daulat D. Mamora

Our previous coreflood experiments—injecting pure CO2 into carbonate cores—showed that the process is a win-win technology, sequestrating CO2 while recovering a significant amount of hitherto unrecoverable natural gas that could help defray the cost of CO2 sequestration. In this paper, we report our findings on the effect of “impurities” in flue gas—N2, O2, H2O, SO2, NO2, and CO—on the displacement of natural gas during CO2 sequestration. Results show that injection of CO2 with approximately less than 1mole% impurities would result in practically the same volume of CO2 being sequestered as injecting pure CO2. This gas would have the advantage of being a cheaper separation process compared to pure CO2 as not all the impurities are removed. Although separation of CO2 out of flue gas is a costly process, it appears that this is necessary to maximize CO2 sequestration volume, reduce compression costs of N2 (approximately 80% of the stream), and improve sweep efficiency and gas recovery in the reservoir.

Author(s):  
R. M. Kondrat ◽  
L. I. Khaidarova

Most natural gas reservoirs of Ukraine are depleted to some extent; still they contain significant tail gas reserves. A promising direction for increasing gas recovery from depleted gas reservoirs is the displacement of tail gas from the porous medium with nitrogen which is easily accessible and does not cause corrosion of the down-hole equipment. This article characterizes the technologies for increasing gas recovery from depleted gas reser-voirs by injecting nitrogen into them. The technology of replacing tail gas with nitrogen is tested on the example of the depleted reservoir of ND-9 horizon of Lyubeshivskyy gas field, the productive deposits of which are composed mainly of sandstones with interlayers of limestone and clay. The authors consider fifteen options of injecting ni-trogen into the reservoir, including options of treating the bottom-hole of low-production wells at the beginning of the process of further reservoir development and at the beginning of the injection of nitrogen into the reservoir. In all cases, the reservoir is first redeveloped in the depletion mode until the reservoir pressure decreases to 0,1 from the initial value. After that, nitrogen is injected into one of the producing wells which is transferred to the injection well. The injection of nitrogen into the reservoir continues until the nitrogen content in the last produc-ing well is less than 5 % vol. All options are characterized by high values of the gas recovery coefficient and close values of the dura-tion of the reservoir further development. The positions of the front of the displacement of natural gas by nitrogen at various time points are given. According to the research results, the gas recovery coefficient for tail gas for var-ious options varies from 14,12 to 34,58 %. With the introduction of the technology of injecting nitrogen into the reservoir, the overall gas recovery coefficient increases from 72,25 % (at present development system) to 80,28 % when the residual gas is displaced by nitrogen.


2019 ◽  
Vol 34 ◽  
pp. 646-655 ◽  
Author(s):  
Erfan Mohagheghian ◽  
Hassan Hassanzadeh ◽  
Zhangxin Chen

Author(s):  
Maria Elena Diego ◽  
Jean-Michel Bellas ◽  
Mohamed Pourkashanian

Post-combustion CO2 capture from natural gas combined cycle (NGCC) power plants is challenging due to the large flow of flue gas with low CO2 content (∼3–4%vol.) that needs to be processed in the capture stage. A number of alternatives have been proposed to solve this issue and reduce the costs of the associated CO2 capture plant. This work focuses on the selective exhaust gas recirculation (S-EGR) configuration, which uses a membrane to selectively recirculate CO2 back to the inlet of the compressor of the turbine, thereby greatly increasing the CO2 content of the flue gas sent to the capture system. For this purpose, a parallel S-EGR NGCC system (53% S-EGR ratio) coupled to an amine capture plant using MEA 30%wt. was simulated using gCCS (gPROMS). It was benchmarked against an unabated NGCC system, a conventional NGCC coupled with an amine capture plant (NGCC+CCS), and an EGR NGCC power plant (39% EGR ratio) using amine scrubbing as the downstream capture technology. The results obtained indicate that the net power efficiency of the parallel S-EGR system can be up to 49.3% depending on the specific consumption of the auxiliary S-EGR systems, compared to the 49.0% and 49.8% values obtained for the NGCC+CCS and EGR systems, respectively. A preliminary economic study was also carried out to quantify the potential of the parallel S-EGR configuration. This high-level analysis shows that the cost of electricity for the parallel S-EGR system varies from 82.1–90.0 $/MWhe for the scenarios considered, with the cost of CO2 avoided being in the range of 79.7–105.1 $/tonne CO2. The results obtained indicate that there are potential advantages of the parallel S-EGR system in comparison to the NGCC+CCS configuration in some scenarios. However, further benefits with respect to the EGR configuration will depend on future advancements and cost reductions achieved on membrane-based systems.


2017 ◽  
Vol 111 ◽  
pp. 599-607 ◽  
Author(s):  
Xiling Zhao ◽  
Lin Fu ◽  
Xiaoyin Wang ◽  
Tao Sun ◽  
Jingyi Wang ◽  
...  

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