Refractive Indices at Visible Wavelengths of Soot Emitted From Buoyant Turbulent Diffusion Flames

1997 ◽  
Vol 119 (2) ◽  
pp. 230-237 ◽  
Author(s):  
J.-S. Wu ◽  
S. S. Krishnan ◽  
G. M. Faeth

Measurements of the optical properties of soot, emphasizing refractive indices, are reported for visible wavelengths (350–800 nm). The experiments considered soot in the fuel-lean (overfire) region of buoyant turbulent diffusion flames in the long residence time regime where soot properties are relatively independent of position in the overfire region and residence time. Flames fueled with acetylene, propylene, ethylene, and propane that were burning in still air provided a range of soot physical and structure properties. Measurements included soot composition, density, structure, gravimetric volume fraction, and scattering and absorption properties. These data were analyzed to find soot fractal dimensions, refractive indices, refractive index functions, and dimensionless extinction coefficients assuming Rayleigh-Debye-Gans scattering for polydisperse mass fractal aggregates (RDG-PFA theory). RDG-PFA theory was successfully evaluated using measured scattering properties. Soot fractal dimensions were independent of both fuel type and wavelength, yielding a mean value of 1.77 with a standard deviation of 0.04. Refractive indices were independent of fuel type within experimental uncertainties and were in reasonably good agreement with earlier measurements for soot in the fuel-lean region of diffusion flames due to Dalzell and Sarofim (1969). Dimensionless extinction coefficients were independent of both fuel type and wavelength, yielding a mean value of 5.1 with a standard deviation of 0.5, which is lower than earlier measurements for reasons that still must be explained.

2000 ◽  
Vol 122 (3) ◽  
pp. 517-524 ◽  
Author(s):  
S. S. Krishnan ◽  
K.-C. Lin ◽  
G. M. Faeth

Nonintrusive measurements of the optical properties of soot at visible wavelengths (351.2–800.0 nm) were completed for soot in the overfire region of large (2–7 kW) buoyant turbulent diffusion flames burning in still air at standard temperature and pressure, where soot properties are independent of position and characteristic flame residence time for a particular fuel. Soot from flames fueled with gaseous (acetylene, ethylene, propylene, and butadiene) and liquid (benzene, cyclohexane, toluene, and n-heptane) hydrocarbon fuels were studied. Scattering and extinction measurements were interpreted to find soot optical properties using the Rayleigh-Debye-Gans/polydisperse-fractal-aggregate theory after establishing that this theory provided good predictions of scattering patterns over the present test range. Effects of fuel type on soot optical properties were comparable to experimental uncertainties. Dimensionless extinction coefficients were relatively independent of wavelength for wavelengths of 400–800 nm and yielded a mean value of 8.4 in good agreement with earlier measurements. Present measurements of the refractive index function for absorption, Em, were in good agreement with earlier independent measurements of Dalzell and Sarofim and Stagg and Charalampopoulos. Present values of the refractive index function for scattering, Fm, however, only agreed with these earlier measurements for wavelengths of 400–550 nm but otherwise increased with increasing wavelength more rapidly than the rest. The comparison between present and earlier measurements of the real and imaginary parts of the complex refractive index was similar to Em and Fm.[S0022-1481(00)02203-9]


1996 ◽  
Vol 118 (2) ◽  
pp. 415-421 ◽  
Author(s):  
U¨. O¨. Ko¨ylu¨ ◽  
G. M. Faeth

The spectral extinction coefficients of soot aggregates were studied in the fuel-lean (overfire) region of buoyant turbulent diffusion flames. Extinction measurements were carried out in the wavelength region of 0.2–5.2 μm for flames fueled with acetylene, propylene, ethylene, and propane, burning in air. The present measurements were combined with earlier measurements of soot morphology and light scattering at 0.514 μm in order to evaluate the spectral soot refractive indices reported by Dalzell and Sarofim (1969), Lee and Tien (1981), and Chang and Charalampopoulos (1990). The specific extinction coefficients and emissivities were predicted based on Rayleigh–Debye–Gans theory for polydisperse fractal aggregates, which has been recently found to be the best approximation to treat optical cross sections of soot aggregates. The results indicated that available refractive indices of soot do not predict the spectral trends of present measurements in the ultraviolet and infrared regions. Soot complex refractive index was inferred to be m = 1.54 + 0.48i at 0.514 μm, which is surprisingly in best agreement with the values reported by Dalzell and Sarofim (1969). Additionally, specific extinction coefficients of soot aggregates varied with wavelength as λ−0.83 from the visible to the infrared. Finally, soot refractive indices were found to be relatively independent of fuel type for the visible and infrared spectral regions over the H/C ratio range of 0.08–0.22.


1994 ◽  
Vol 116 (1) ◽  
pp. 152-159 ◽  
Author(s):  
U¨. O¨. Ko¨ylu¨ ◽  
G. M. Faeth

The optical properties of soot were studied for the fuel-lean (overfire) region of buoyant turbulent diffusion flames in still air. Results were limited to the long residence time regime where soot structure is independent of position in the overfire region and residence time for a particular fuel. Measurements included scattering, absorption, and extinction cross sections at 514.5 nm and extinction cross sections at 632.8 and 1152 nm for flames fueled with acetylene, propylene, ethylene, and propane. The measurements were used to evaluate scattering predictions based on the Rayleigh-Debye-Gans (RDG) approximation for randomly oriented poly disperse fractal aggregates of spherical primary soot particles having constant diameters. The present soot aggregates exhibited significant departures from Rayleigh-scattering behavior at 514.5 nm, with forward scattering roughly 100 times larger than wide-angle scattering and ratios of scattering to absorption cross sections in the range 0.22–0.41, increasing with increasing propensity of the fuel to soot. The approximate RDG theory generally provided an acceptable basis to treat the optical properties of the present overfire soot aggregates, although additional measurements in the Guinier (small angle) regime are needed for a definitive evaluation of model performance.


2000 ◽  
Vol 123 (2) ◽  
pp. 331-339 ◽  
Author(s):  
S. S. Krishnan ◽  
K.-C. Lin ◽  
G. M. Faeth

Extinction and scattering properties at wavelengths of 250–5200 nm were studied for soot emitted from buoyant turbulent diffusion flames in the long residence time regime where soot properties are independent of position in the overfire region and characteristic flame residence times. Flames burning in still air and fueled with gas (acetylene, ethylene, propane, and propylene) and liquid (benzene, toluene, cyclohexane, and n-heptane) hydrocarbon fuels were considered. Measured scattering patterns and ratios of total scattering/absorption cross sections were in good agreement with predictions based on the Rayleigh-Debye-Gans (RDG) scattering approximation in the visible. Measured depolarization ratios were roughly correlated by primary particle size parameter, suggesting potential for completing RDG methodology needed to make soot scattering predictions as well as providing a nonintrusive way to measure primary soot particle diameters. Measurements of dimensionless extinction coefficients were in good agreement with earlier measurements for similar soot populations and were independent of fuel type and wavelength except for reduced values as the near ultraviolet was approached. The ratios of the scattering/absorption refractive index functions were independent of fuel type within experimental uncertainties and were in good agreement with earlier measurements. The refractive index function for absorption was similarly independent of fuel type but was larger than earlier reflectometry measurements in the infrared. Ratios of total scattering/absorption cross sections were relatively large in the visible and near infrared, with maximum values as large as 0.9 and with values as large as 0.2 at 2000 nm, suggesting greater potential for scattering from soot particles to affect flame radiation properties than previously thought.


Cancers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 2421
Author(s):  
Roberta Fusco ◽  
Vincenza Granata ◽  
Mauro Mattace Raso ◽  
Paolo Vallone ◽  
Alessandro Pasquale De Rosa ◽  
...  

Purpose. To combine blood oxygenation level dependent magnetic resonance imaging (BOLD-MRI), dynamic contrast enhanced MRI (DCE-MRI), and diffusion weighted MRI (DW-MRI) in differentiation of benign and malignant breast lesions. Methods. Thirty-seven breast lesions (11 benign and 21 malignant lesions) pathologically proven were included in this retrospective preliminary study. Pharmaco-kinetic parameters including Ktrans, kep, ve, and vp were extracted by DCE-MRI; BOLD parameters were estimated by basal signal S0 and the relaxation rate R2*; and diffusion and perfusion parameters were derived by DW-MRI (pseudo-diffusion coefficient (Dp), perfusion fraction (fp), and tissue diffusivity (Dt)). The correlation coefficient, Wilcoxon-Mann-Whitney U-test, and receiver operating characteristic (ROC) analysis were calculated and area under the ROC curve (AUC) was obtained. Moreover, pattern recognition approaches (linear discrimination analysis and decision tree) with balancing technique and leave one out cross validation approach were considered. Results. R2* and D had a significant negative correlation (−0.57). The mean value, standard deviation, Skewness and Kurtosis values of R2* did not show a statistical significance between benign and malignant lesions (p > 0.05) confirmed by the ‘poor’ diagnostic value of ROC analysis. For DW-MRI derived parameters, the univariate analysis, standard deviation of D, Skewness and Kurtosis values of D* had a significant result to discriminate benign and malignant lesions and the best result at the univariate analysis in the discrimination of benign and malignant lesions was obtained by the Skewness of D* with an AUC of 82.9% (p-value = 0.02). Significant results for the mean value of Ktrans, mean value, standard deviation value and Skewness of kep, mean value, Skewness and Kurtosis of ve were obtained and the best AUC among DCE-MRI extracted parameters was reached by the mean value of kep and was equal to 80.0%. The best diagnostic performance in the discrimination of benign and malignant lesions was obtained at the multivariate analysis considering the DCE-MRI parameters alone with an AUC = 0.91 when the balancing technique was considered. Conclusions. Our results suggest that the combined use of DCE-MRI, DW-MRI and/or BOLD-MRI does not provide a dramatic improvement compared to the use of DCE-MRI features alone, in the classification of breast lesions. However, an interesting result was the negative correlation between R2* and D.


Author(s):  
Athanasios N. Papadimopoulos ◽  
Stamatios A. Amanatiadis ◽  
Nikolaos V. Kantartzis ◽  
Theodoros T. Zygiridis ◽  
Theodoros D. Tsiboukis

Purpose Important statistical variations are likely to appear in the propagation of surface plasmon polariton waves atop the surface of graphene sheets, degrading the expected performance of real-life THz applications. This paper aims to introduce an efficient numerical algorithm that is able to accurately and rapidly predict the influence of material-based uncertainties for diverse graphene configurations. Design/methodology/approach Initially, the surface conductivity of graphene is described at the far infrared spectrum and the uncertainties of its main parameters, namely, the chemical potential and the relaxation time, on the propagation properties of the surface waves are investigated, unveiling a considerable impact. Furthermore, the demanding two-dimensional material is numerically modeled as a surface boundary through a frequency-dependent finite-difference time-domain scheme, while a robust stochastic realization is accordingly developed. Findings The mean value and standard deviation of the propagating surface waves are extracted through a single-pass simulation in contrast to the laborious Monte Carlo technique, proving the accomplished high efficiency. Moreover, numerical results, including graphene’s surface current density and electric field distribution, indicate the notable precision, stability and convergence of the new graphene-based stochastic time-domain method in terms of the mean value and the order of magnitude of the standard deviation. Originality/value The combined uncertainties of the main parameters in graphene layers are modeled through a high-performance stochastic numerical algorithm, based on the finite-difference time-domain method. The significant accuracy of the numerical results, compared to the cumbersome Monte Carlo analysis, renders the featured technique a flexible computational tool that is able to enhance the design of graphene THz devices due to the uncertainty prediction.


2018 ◽  
Vol 189 ◽  
pp. 04009
Author(s):  
Kun Liu ◽  
Shiping Wang ◽  
Linyuan He ◽  
Duyan Bi ◽  
Shan Gao

Aiming at the color distortion of the restored image in the sky region, we propose an image dehazing algorithm based on double priors constraint. Firstly, we divided the haze image into sky and non-sky regions. Then the Color-lines prior and dark channel prior are used for estimating the transmission of sky and non-sky regions respectively. After introducing color-lines prior to correct sky regions restored by the dark channel prior, we get an accurate transmission. Finally, the local media mean value and standard deviation are used to refine the transmission to obtain the dehazing image. Experimental results show that the algorithm has obvious advantages in the recovery of the sky area.


AIAA Journal ◽  
1991 ◽  
Vol 29 (6) ◽  
pp. 932-935 ◽  
Author(s):  
T. Neill ◽  
I. M. Kennedy

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