scholarly journals A Numerical Study on the Effect of Water Addition on NO Formation in Counterflow CH4/Air Premixed Flames

2008 ◽  
Vol 130 (5) ◽  
Author(s):  
Hongsheng Guo ◽  
W. Stuart Neill ◽  
Gregory J. Smallwood
Keyword(s):  
Numerical Study ◽  
Temperature Drop ◽  
Flame Temperature ◽  
Premixed Flames ◽  
Chemical Effect ◽  
Water Addition ◽  
Detailed Chemistry ◽  
Effect Of Water ◽  
No Formation ◽  
The Rich

The effect of water addition on NO formation in counterflow CH4/air premixed flames was investigated by numerical simulation. Detailed chemistry and complex thermal and transport properties were employed. The results show that the addition of water to a flame suppresses the formation of NO primarily due to flame temperature drop. Among a lean, a stoichiometric, and a rich premixed flame, the effectiveness of water addition is most significant for the stoichiometric flame and least for the rich flame. The addition of water also reduces the formation of NO in a flame because of the chemical effect. Compared to the stoichiometric flame, the chemical effect is intensified in the lean and rich flames.

A Numerical Study on the Effect of Water Addition on NO Formation in Counterflow CH4/Air Premixed Flames

2005 ◽  
Author(s):  
Hongsheng Guo ◽  
Stuart W. Neill ◽  
Gregory J. Smallwood
Keyword(s):  
Numerical Study ◽  
Temperature Drop ◽  
Flame Temperature ◽  
Premixed Flames ◽  
Chemical Effect ◽  
Water Addition ◽  
Detailed Chemistry ◽  
Effect Of Water ◽  
No Formation ◽  
The Rich

The effect of water addition on NO formation in counterflow CH4/air premixed flames was investigated by numerical simulation. Detailed chemistry and complex thermal and transport properties were employed. The results show that the addition of water to a flame suppresses the formation of NO primarily due to the flame temperature drop. Among a lean, a stoichiometric and a rich premixed flame, the effectiveness of water addition is most significant for the stoichiometric flame and least for the rich flame, since the dominant NO formation mechanism varies. The addition of water also reduces the formation of NO in a flame because of chemical effect that increases the concentration of OH, while reduces the concentrations of O and H. Compared to the stoichiometric flame, the chemical effect is intensified in the lean and rich flames.

scholarly journals Effects of strain rate and CO2 on no formation in CH4/N2/O2 counter-flow diffusion flames

2018 ◽  
Vol 22 (Suppl. 2) ◽  
pp. 769-776
Author(s):  
Fei Ren ◽  
Longkai Xiang ◽  
Huaqiang Chu ◽  
Weiwei Han
Keyword(s):  
Strain Rate ◽  
Diffusion Flames ◽  
Numerical Study ◽  
Flame Temperature ◽  
Co2 Concentration ◽  
No Production ◽  
Counter Flow ◽  
Detailed Chemistry ◽  
No Formation ◽  
Key Factor

The reduction of nitrogen oxides in the high temperature flame is the key factor affecting the oxygen-enriched combustion performance. A numerical study using an OPPDIF code with detailed chemistry mechanism GRI 3.0 was carried out to focus on the effect of strain rate (25-130 s?1) and CO2 addition (0-0.59) on the oxidizer side on NO emission in CH4 / N2 / O2 counter-flow diffusion flame. The mole fraction profiles of flame structures, NO, NO2 and some selected radicals (H, O, OH) and the sensitivity of the dominant reactions contributing to NO formation in the counter-flow diffusion flames of CH4\/ N2 /O2 and CH4 / N2 / O2 / CO2 were obtained. The results indicated that the flame temperature and the amount of NO were reduced while the sensitivity of reactions to the prompt NO formation was gradually increased with the increasing strain rate. Furthermore, it is shown that with the increasing CO2 concentration in oxidizer, CO2 was directly involved in the reaction of NO consumption. The flame temperature and NO production were decreased dramatically and the mechanism of NO production was transformed from the thermal to prompt route.

scholarly journals Numerical study of the superadiabatic flame temperature phenomenon in hydrocarbon premixed flames

2002 ◽  
Vol 29 (2) ◽  
pp. 1543-1550 ◽  
Author(s):  
Fengshan Liu ◽  
Hongsheng Guo ◽  
Gregory J. Smallwood ◽  
Ömer L. Gülder
Keyword(s):  
Numerical Study ◽  
Flame Temperature ◽  
Premixed Flames

scholarly journals A Numerical Study on the Effect of CO Addition on Flame Temperature and NO Formation in Counterflow CH4/Air Diffusion Flames

2008 ◽  
Vol 130 (5) ◽  
Author(s):  
Hongsheng Guo ◽  
W. Stuart Neill
Keyword(s):  
Carbon Monoxide ◽  
Strain Rate ◽  
Diffusion Flames ◽  
Numerical Study ◽  
Formation Rate ◽  
Flame Temperature ◽  
No Emission ◽  
No Formation ◽  
Air Diffusion ◽  
Emission Index

A numerical study was carried out to understand the effect of CO enrichment on flame temperature and NO formation in counterflow CH4/air diffusion flames. The results indicate that when CO is added to the fuel, both flame temperature and NO formation rate are changed due to the variations in adiabatic flame temperature, fuel Lewis number, and chemical reaction. At a low strain rate, the addition of carbon monoxide causes a monotonic decrease in flame temperature and peak NO concentration. However, NO emission index first slightly increases, and then decreases. At a moderate strain rate, the addition of CO has negligible effect on flame temperature and leads to a slight increase in both peak NO concentration and NO emission index, until the fraction of carbon monoxide reaches about 0.7. Then, with a further increase in the fraction of added carbon monoxide, all three quantities quickly decrease. At a high strain rate, the addition of carbon monoxide causes increase in flame temperature and NO formation rate, until a critical carbon monoxide fraction is reached. After the critical fraction, the further addition of carbon monoxide leads to decrease in both flame temperature and NO formation rate.

scholarly journals Numerical Study of Hydrogen Addition Fuel on Soot Formation in Axisymmetric Laminar Methane/Air Diffusion Flames

2020 ◽  
Vol 194 ◽  
pp. 04054
Author(s):  
Bencheng Zhu ◽  
Yuhan Zhu ◽  
Jiajia Wu ◽  
Kun Lu ◽  
Yang Wang ◽  
...  
Keyword(s):  
Diffusion Flames ◽  
Soot Formation ◽  
Numerical Study ◽  
Flame Temperature ◽  
Surface Growth ◽  
Chemical Effect ◽  
Oh Radicals ◽  
Phase Reaction ◽  
Hydrogen Addition ◽  
Air Diffusion

This article employs the CoFlame Code to investigate the effects of hydrogen addition to fuel on soot formation characteristics in laminar coflow methane/air diffusion flames at atmospheric pressure. Numerical calculations were carried out using a detailed C1-C2 gas phase reaction mechanism and a soot model consisting of two pyrene molecules colliding into a dimer as soot nucleation, hydrogen abstraction acetylene addition (HACA) and pyrene condensation as surface growth, and soot oxidation by O2, O and OH radicals. Calculations were conducted for five levels of hydrogen addition on volume basis. To quantify the chemical effect of hydrogen, additional calculations are performed for addition of inert pseudo-hydrogen (FH2). The addition of H2 or FH2 does not have a strong influence on flame temperature. The results confirm that hydrogen addition can inhibit soot formation in the methane/air diffusion flame by reducing both the nucleation and surface growth steps of soot formation process. The effect of FH2 addition on soot formation suppression is more remarkable than H2, indicating that the chemical effect of hydrogen added to methane prompts soot formation. The dilution effect of hydrogen addition on soot formation suppression is stronger than its chemical effect on soot formation enhancement the present findings are consistent with those of previous numerical studies.

Fundamental Combustion Characteristics of Lean and Stoichiometric Hydrogen Laminar Premixed Flames Diluted With Nitrogen or Carbon Dioxide

2016 ◽  
Vol 138 (11) ◽  
Author(s):  
Hong-Meng Li ◽  
Guo-Xiu Li ◽  
Zuo-Yu Sun ◽  
Zi-Hang Zhou ◽  
Yuan Li ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Equivalence Ratio ◽  
Burning Velocity ◽  
Flame Temperature ◽  
Premixed Flames ◽  
Combustion Characteristics ◽  
Inert Gas ◽  
Chemical Effect ◽  
Laminar Burning Velocity ◽  
Suppression Effect

In this work, the laminar combustion characteristics of H2/N2/air (H2/CO2/air) were systematically investigated under different hydrogen ratios (40–100%) and equivalence ratios (0.4–1.0) in a closed combustion vessel using the spherical expanding flame method associated with Schlieren technology. The unstretched laminar burning velocities were compared with data from previous study, and the result indicates that excellent agreements are obtained. Numerical simulations were also conducted using GRI3.0 and USC II mechanisms to compare with the present experimental results. The Markstein length for H2/inert gas can be decreased by decreasing the equivalence ratio and hydrogen ratio. The results indicate that the H2/inert gas premixed flames tend to be more unstable with the decrease of equivalence ratio and hydrogen ratio. For H2/N2 mixture, the suppression effect on laminar burning velocity is caused by modified specific heat of mixtures and decreased heat release, which result in a decreased flame temperature. For H2/CO2 mixture, the carbon dioxide has stronger dilution effect than nitrogen in reducing laminar burning velocity owing to both thermal effect and chemical effect.

scholarly journals A Numerical Study on the Effect of CO Addition on Flame Temperature and NO Formation in Counterflow CH4/Air Diffusion Flames

2007 ◽  
Author(s):  
Hongsheng Guo ◽  
W. Stuart Neill
Keyword(s):  
Carbon Monoxide ◽  
Strain Rate ◽  
Diffusion Flames ◽  
Numerical Study ◽  
Formation Rate ◽  
Flame Temperature ◽  
No Emission ◽  
No Formation ◽  
Air Diffusion ◽  
Emission Index

A numerical study was carried out to understand the effect of carbon monoxide enrichment on flame temperature and NO formation in counterflow methane/air diffusion flames. Detailed chemistry and complex thermal and transport properties were employed. The results indicate that when carbon monoxide is added to the fuel, both flame temperature and NO formation rate are changed due to the variations in adiabatic flame temperature, fuel Lewis number and chemical reaction. The combination effects of three factors result in the different characteristics of flame temperature and NO formation at various strain rates, when carbon monoxide is added. At a low strain rate, the addition of carbon monoxide causes a monotonic decrease in flame temperature and peak NO concentration. However, NO emission index first slightly increases, and then decreases. When the value of strain rate is moderate, the addition of carbon monoxide has negligible effect on flame temperature and leads to a slight increase in both peak NO concentration and NO emission index, until the fraction of carbon monoxide reaches about 0.7. Then with a further increase in the fraction of added carbon monoxide, all three quantities quickly decrease. When strain rate is increased to a value close to the strain extinction limit of pure methane/air diffusion flame, the addition of carbon monoxide causes increase in flame temperature and NO formation rate, until a critical carbon monoxide fraction is reached. After the critical fraction, the further addition of carbon monoxide leads to decrease in both flame temperature and NO formation rate. The paper also analyzed the variation in the mechanism of NO formation, when carbon monoxide is added.

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