Thermal Conductivity and Compressive Strain of Aerogel Insulation Blankets Under Applied Hydrostatic Pressure

2006 ◽  
Vol 129 (2) ◽  
pp. 232-235 ◽  
Author(s):  
Erik R. Bardy ◽  
Joseph C. Mollendorf ◽  
David R. Pendergast

Aerogel is among the best solid thermal insulators. Aerogel is a silica gel formed by supercritical extraction which results in a porous open cell solid insulation with a thermal conductivity as low as 0.013W∕mK. Aerogels have a wide range of uses such as insulation for windows, vehicles, refrigerators∕freezers, etc. Usage for aerogel can be extended for use where flexibility is needed, such as apparel, by embedding it into a polyester batting blanket. These aerogel blankets, although flexible, have little resistance to compression and experience a residual strain effect upon exposure to elevated pressures. It was suggested, by Aspen Aerogels Inc., that a prototype aerogel blanket would have increased resistance to compression and minimized residual strain upon exposure to elevated pressures. Samples of prototype and normal product-line aerogel insulating blankets were acquired. These materials were separately tested for thermal conductivity and compressive strain at incremental pressure stops up to 1.2MPa. The compressive strain of the prototype aerogel blanket reached a level of 0.25mm∕mm whereas the product-line aerogel blanket compressed to 0.48mm∕mm at 1.2MPa. Before compression, the thermal conductivity of the prototype aerogel blanket was slightly higher than the product-line aerogel blanket. During compression the thermal conductivity increased 46% for the product-line aerogel blanket whereas it increased only 13% for the prototype aerogel blanket at 1.2MPa. The total thermal resistance decreased 64% for the product-line aerogel blanket at 1.2MPa and remained at that value upon decompression to atmospheric pressure. The total thermal resistance of the prototype aerogel blanket decreased 33% at 1.2MPa and returned to within 1% of its initial value upon decompression to atmospheric pressure. It was found that the prototype aerogel blanket has approximately twice as much resistance to hydrostatic compression to a pressure of 1.2MPa and also recovers to its original state upon decompression. The thermal resistance of the prototype aerogel blanket remained 37% higher than the product-line aerogel blanket at 1.2MPa. This resistance to compression and the ability to recover to its original state upon decompression from elevated pressures makes the prototype aerogel blanket suitable for applications where high insulation, resistance to compression, and recovery after a compression cycle is needed.

Open Physics ◽  
2006 ◽  
Vol 4 (2) ◽  
Author(s):  
Oleg Pursky ◽  
Vyacheslav Konstantinov

AbstractThe isochoric thermal conductivity of an orientationally-disordered phase of CCl4 is analysed within a model in which heat is transferred by phonons and above the phonon mobility edge by ”diffusive” modes migrating randomly from site to site. The mobility edge ω0 is found from the condition that the phonon mean-free path cannot become smaller than half the phonon wavelength. The contributions of phonon-phonon, one-, and two-phonon scattering to the total thermal resistance of solid CCl4 are calcualted under the assumption that the different scattering mechanisms contribute additively. An increase in the isochoric thermal conductivity with temperature is explained by suppression of phonon scattering at rotational excitations due to a decrease in correlation in the rotation of neighbouring molecules.


Vestnik MGSU ◽  
2019 ◽  
pp. 1037-1045
Author(s):  
Tatiana A. Musorina, ◽  
Michail R. Petritchenko ◽  
Daria D. Zaborova

Introduction: the article suggests a method for determining a thermal resistance of small and large-sized areas (one-dimensional and multidimensional problems) of wall enclosure. The subject of the study is the thermal resistance of homogeneous scalar medium (homogeneous wall enclosure). The aim is the determination of thermal resistance of a wall structure for areas of arbitrary dimension (by the coordinates xi, where 1 ≤ i ≤ d and d is the area dimension) filled with a scalar (homogeneous and isotropic) heat-conducting medium. Materials and methods: the article used the following physical laws: Fourier law (the value of the heat flow when transferring heat through thermal conductivity) and continuity condition for the heat flow rate leading to the thermal conductivity equation. Results: this method extends the standard definition of thermal resistance. The research proved that the active thermal resistance does not increase with increasing of the area dimension (for example, when switching from a thin shell or plate to a rectangle with length and width of the same order of magnitude). That is the sense of geometric inclusion, i.e., increase of the dimension of an area filled with a homogeneous isotropic medium. Evident expressions are obtained for the determination of active, reactive, and total thermal resistance. It is proved that the total resistance is higher than the active resistance since the reactive resistance is positive, and the wall possesses an ability to suppress the temperature fluctuations and accumulate/give up the heat. Conclusions: the appearance of an additional wall dimension (comparable length-to-thickness ratio) does not increase its active resistance. In the general case, the total thermal resistance exceeds the active thermal resistance no more than four times. Geometric inclusions must be considered in the calculation of wall enclosures that are variant from one-dimensional bodies.


2010 ◽  
Vol 24 (29) ◽  
pp. 5821-5832 ◽  
Author(s):  
O. I. PURSKY ◽  
V. A. KONSTANTINOV

The isobaric thermal conductivity of solid β- SF 6, CCl 4 (Ib) , and C 6 H 6 is investigated by using the Debye thermal conductivity model and taking into account the effect of minimum thermal conductivity. The simulation was carried out in the framework of a model where heat is transferred by phonons and "diffusive" modes with regard to the thermal expansion and phonon–rotation coupling. For this purpose the temperature dependences of the isobaric heat capacity components have been calculated numerically for β- SF 6, CCl 4 (Ib) , and C 6 H 6. The contributions of phonon–phonon and phonon–rotational interactions to the total thermal resistance are discussed.


2005 ◽  
Vol 128 (3) ◽  
pp. 234-239 ◽  
Author(s):  
Choongho Yu ◽  
Sanjoy Saha ◽  
Jianhua Zhou ◽  
Li Shi ◽  
Alan M. Cassell ◽  
...  

We have measured the thermal resistance of a 152‐nm-diameter carbon nanofiber before and after a platinum layer was deposited on the contacts between the nanofiber and the measurement device. The contact resistance was reduced by the platinum coating for about 9–13% of the total thermal resistance of the nanofiber sample before the platinum coating. At a temperature of 300K, the axial thermal conductivity of the carbon nanofiber is about three times smaller than that of graphite fibers grown by pyrolysis of natural gas prior to high-temperature heat treatment, and increases with temperature in the temperature range between 150K and 310K. The phonon mean free path was found to be about 1.5nm and approximately temperature-independent. This feature and the absence of a peak in the thermal conductivity curve indicate that phonon-boundary and phonon-defect scattering dominate over phonon-phonon Umklapp scattering for the temperature range.


2020 ◽  
pp. 174425912098003
Author(s):  
Travis V Moore ◽  
Cynthia A. Cruickshank ◽  
Ian Beausoleil-Morrison ◽  
Michael Lacasse

The purpose of this paper is to investigate the potential for calculation methods to determine the thermal resistance of a wall system containing vacuum insulation panels (VIPs) that has been experimentally characterised using a guarded hot box (GHB) apparatus. The VIPs used in the wall assembly have not been characterised separately to the wall assembly, and therefore exact knowledge of the thermal performance of the VIP including edge effect is not known. The calculations and simulations are completed using methods found in literature as well as manufacturer published values for the VIPs to determine the potential for calculation and simulation methods to predict the thermal resistance of the wall assembly without the exact characterisation of the VIP edge effect. The results demonstrate that disregarding the effect of VIP thermal bridges results in overestimating the thermal resistance of the wall assembly in all calculation and simulation methods, ranging from overestimates of 21% to 58%. Accounting for the VIP thermal bridges using the manufacturer advertised effective thermal conductivity of the VIPs resulted in three methods predicting the thermal resistance of the wall assembly within the uncertainty of the GHB results: the isothermal planes method, modified zone method and the 3D simulation. Of these methods only the 3D simulation can be considered a potential valid method for energy code compliance, as the isothermal planes method requires too drastic an assumption to be valid and the modified zone method requires extrapolating the zone factor beyond values which have been validated. The results of this work demonstrate that 3D simulations do show potential for use in lieu of guarded hot box testing for predicting the thermal resistance of wall assemblies containing both VIPs and steel studs. However, knowledge of the VIP effective thermal conductivity is imperative to achieve reasonable results.


2005 ◽  
Vol 46 (2) ◽  
pp. 148-151 ◽  
Author(s):  
Yibin Xu ◽  
Yoshihisa Tanaka ◽  
Masaharu Murata ◽  
Kazushige Kamihira ◽  
Yukihiro Isoda ◽  
...  

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