DOE FE Distributed Generation Program

2004 ◽  
Vol 1 (1) ◽  
pp. 18-20 ◽  
Author(s):  
Mark C. Williams ◽  
Bruce R. Utz ◽  
Kevin M. Moore
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Distributed Generation ◽  
High Efficiency ◽  
High Reliability ◽  
National Laboratory ◽  
Pacific Northwest National Laboratory ◽  
Hydrogen Economy ◽  
Wide Range ◽  
The U.S

The U.S. Department of Energy’s (DOE) Office of Fossil Energy’s (FE) National Energy Technology Laboratory (NETL), in partnership with private industries, is leading the development and demonstration of high efficiency solid oxide fuel cells (SOFCs) and fuel cell turbine hybrid power generation systems for near term distributed generation (DG) markets with an emphasis on premium power and high reliability. NETL is partnering with Pacific Northwest National Laboratory (PNNL) in developing new directions in research under the Solid-State Energy Conversion Alliance (SECA) initiative for the development and commercialization of modular, low cost, and fuel flexible SOFC systems. The SECA initiative, through advanced materials, processing and system integration research and development, will bring the fuel cell cost to $400 per kilowatt (kW) for stationary and auxiliary power unit (APU) markets. The President of the U.S. has launched us into a new hydrogen economy. The logic of a hydrogen economy is compelling. The movement to a hydrogen economy will accomplish several strategic goals. The U.S. can use its own domestic resources—solar, wind, hydro, and coal. The U.S. uses 20 percent of the world’s oil but has only 3 percent of resources. Also, the U.S. can reduce green house gas emissions. Clear Skies and Climate Change initiatives aim to reduce carbon dioxide (CO2), nitrogen oxides (NOx), and sulfur dioxide (SO2) emissions. SOFCs have no emissions, so they figure significantly in these DOE strategies. In addition, DG—SOFCs, reforming, energy storage—has significant benefit for enhanced security and reliability. The use of fuel cells in cars is expected to bring about the hydrogen economy. However, commercialization of fuel cells is expected to proceed first through portable and stationary applications. This logic says to develop SOFCs for a wide range of stationary and APU applications, initially for conventional fuels, then switch to hydrogen. Like all fuel cells, the SOFC will operate even better on hydrogen than conventional fuels. The SOFC hybrid is a key part of the FutureGen plants. FutureGen is a major new Presidential initiative to produce hydrogen from coal. The highly efficient SOFC hybrid plant will produce electric power and other parts of the plant could produce hydrogen and sequester CO2. The hydrogen produced can be used in fuel cell cars and for SOFC DG applications.

Active Water Management for Proton Exchange Membrane Fuel Cells Using an Integrated Electroosmotic Pump

2005 ◽  
Author(s):  
Cullen R. Buie ◽  
Jonathan D. Posner ◽  
Tibor Fabian ◽  
Suk-Won Cha ◽  
Fritz B. Prinz ◽  
...  
Keyword(s):  
Water Management ◽  
Fuel Cells ◽  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
High Efficiency ◽  
Proton Exchange ◽  
Flow Rates ◽  
Fuel Cell Performance ◽  
Wide Range ◽  
Exchange Membrane

We have developed proton exchange membrane fuel cells (PEMFC’s) with integrated planar electroosmotic pumping structures that actively remove liquid water from cathode flow channels. Recent experimental and numerical investigations on PEMFC’s emphasize water management as a critical factor in the design of robust, high efficiency fuel cells. Although various passive water management strategies have been proposed, water is still typically removed by pumping air into cathode channels at flow rates significantly larger than those required by fuel cell stoichiometry. This method of water removal is thermodynamically unfavorable and constrains cathode flow channel design. EO pumps can relieve cathode design barriers and simplify water management in fuel cells. EO pumps have no moving parts, scale across a wide range of operation, and result in low parasitic power. We demonstrate and quantify the efficacy of EO water pumping using a single-pass fuel cell test channel. Our results show that removing water from the cathode using integrated EO pumping structures improves fuel cell performance and stability. These pumps enable operation with air flow rates of just two to three times stoichiometric requirements.

scholarly journals Fuel Cell Development for NASA’s Human Exploration Program: Benchmarking With “The Hydrogen Economy”

2009 ◽  
Vol 6 (2) ◽  
Author(s):  
John H. Scott
Keyword(s):  
Fuel Cells ◽  
Life Cycle ◽  
Fuel Cell ◽  
Power Plants ◽  
High Efficiency ◽  
Development Program ◽  
Cell Development ◽  
Plant Design ◽  
Hydrogen Economy ◽  
Human Exploration

The theoretically high efficiency and low temperature operation of hydrogen-oxygen fuel cells have motivated them to be the subject of much study since their invention in the 19th century, but their relatively high life cycle costs have kept them as a “solution in search of a problem” for many years. The first problem for which fuel cells presented a truly cost effective solution was that of providing a power source for NASA’s human spaceflight vehicles in the 1960s. NASA thus invested, and continues to invest, in the development of fuel cell power plants for this application. This development program continues to place its highest priorities on requirements for minimum system mass and maximum durability and reliability. These priorities drive fuel cell power plant design decisions at all levels, even that of catalyst support. However, since the mid-1990s, prospective environmental regulations have driven increased governmental and industrial interest in “green power” and “the hydrogen economy.” This has in turn stimulated greatly increased investment in fuel cell development for a variety of commercial applications. This investment is bringing about notable advances in fuel cell technology, but as these development efforts place their highest priority on requirements for minimum life cycle cost and field safety, these advances are yielding design solutions quite different at almost every level from those needed for spacecraft applications. This environment thus presents both opportunities and challenges for NASA’s Human Exploration program.

scholarly journals A Review of Hydrogen Purification Technologies for Fuel Cell Vehicles

Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 393
Author(s):  
Zhemin Du ◽  
Congmin Liu ◽  
Junxiang Zhai ◽  
Xiuying Guo ◽  
Yalin Xiong ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Carbon Emission ◽  
High Efficiency ◽  
Impurity Content ◽  
Fuel Cell Vehicle ◽  
Research Progress ◽  
Hydrogen Purification ◽  
Fuel Cell Vehicles ◽  
Low Carbon

Nowadays, we face a series of global challenges, including the growing depletion of fossil energy, environmental pollution, and global warming. The replacement of coal, petroleum, and natural gas by secondary energy resources is vital for sustainable development. Hydrogen (H2) energy is considered the ultimate energy in the 21st century because of its diverse sources, cleanliness, low carbon emission, flexibility, and high efficiency. H2 fuel cell vehicles are commonly the end-point application of H2 energy. Owing to their zero carbon emission, they are gradually replacing traditional vehicles powered by fossil fuel. As the H2 fuel cell vehicle industry rapidly develops, H2 fuel supply, especially H2 quality, attracts increasing attention. Compared with H2 for industrial use, the H2 purity requirements for fuel cells are not high. Still, the impurity content is strictly controlled since even a low amount of some impurities may irreversibly damage fuel cells’ performance and running life. This paper reviews different versions of current standards concerning H2 for fuel cell vehicles in China and abroad. Furthermore, we analyze the causes and developing trends for the changes in these standards in detail. On the other hand, according to characteristics of H2 for fuel cell vehicles, standard H2 purification technologies, such as pressure swing adsorption (PSA), membrane separation and metal hydride separation, were analyzed, and the latest research progress was reviewed.

scholarly journals Octane Index Applicability over the Pressure-Temperature Domain

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 607
Author(s):  
Tommy R. Powell ◽  
James P. Szybist ◽  
Flavio Dal Forno Chuahy ◽  
Scott J. Curran ◽  
John Mengwasser ◽  
...  
Keyword(s):  
High Efficiency ◽  
National Laboratory ◽  
Operating Conditions ◽  
Dominant Factor ◽  
Compression Ignition ◽  
Oak Ridge ◽  
Operating Modes ◽  
Wide Range ◽  
Thermodynamic Conditions ◽  
Si Engines

Modern boosted spark-ignition (SI) engines and emerging advanced compression ignition (ACI) engines operate under conditions that deviate substantially from the conditions of conventional autoignition metrics, namely the research and motor octane numbers (RON and MON). The octane index (OI) is an emerging autoignition metric based on RON and MON which was developed to better describe fuel knock resistance over a broader range of engine conditions. Prior research at Oak Ridge National Laboratory (ORNL) identified that OI performs reasonably well under stoichiometric boosted conditions, but inconsistencies exist in the ability of OI to predict autoignition behavior under ACI strategies. Instead, the autoignition behavior under ACI operation was found to correlate more closely to fuel composition, suggesting fuel chemistry differences that are insensitive to the conditions of the RON and MON tests may become the dominant factor under these high efficiency operating conditions. This investigation builds on earlier work to study autoignition behavior over six pressure-temperature (PT) trajectories that correspond to a wide range of operating conditions, including boosted SI operation, partial fuel stratification (PFS), and spark-assisted compression ignition (SACI). A total of 12 different fuels were investigated, including the Co-Optima core fuels and five fuels that represent refinery-relevant blending streams. It was found that, for the ACI operating modes investigated here, the low temperature reactions dominate reactivity, similar to boosted SI operating conditions because their PT trajectories lay close to the RON trajectory. Additionally, the OI metric was found to adequately predict autoignition resistance over the PT domain, for the ACI conditions investigated here, and for fuels from different chemical families. This finding is in contrast with the prior study using a different type of ACI operation with different thermodynamic conditions, specifically a significantly higher temperature at the start of compression, illustrating that fuel response depends highly on the ACI strategy being used.

A Methodology for Assessing Fuel Cell Performance Under a Wide Range of Operational Conditions: Results for Single Cells

2006 ◽  
Vol 3 (3) ◽  
pp. 226-233 ◽  
Author(s):  
Andrea Baratella ◽  
Roberto Bove ◽  
Piero Lunghi
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Single Cells ◽  
Cell Performance ◽  
Effective Parameters ◽  
Test Procedures ◽  
Operational Conditions ◽  
Fuel Cell Performance ◽  
Wide Range ◽  
The University

Testing the performance of fuel cells is an important key for verifying technology improvements and for demonstrating their potential. However, due to the novelty of this technology, there is not a standardized procedure for testing fuel cell performance. In order to fully investigate fuel cell performance, the behavior must be known under a wide range of operational conditions. Furthermore, in order to compare results coming from different test teams, a set of procedures and parameters to evaluate single cell performance should be defined. The research group of the Fuel Cell Laboratory of the University of Perugia is conducting performance tests on single cells, focusing on defining test procedures to find effective parameters to be used to compare tests performed by different teams. This work demonstrates how the testing parameters developed by the team allow one to perform advanced control on test procedures, to understand test results, and to compare them with tests carried out under different operational conditions. The entire analysis is easily conducted by using a single parameter variation hyperspace approach. The experimental results obtained on single fuel cells are reported.

scholarly journals Analysis of Related Technologies Used in Fuel Cell Vehicles

2021 ◽  
Vol 2125 (1) ◽  
pp. 012011
Author(s):  
Ziyi Du ◽  
Hongxu Zhan
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Automotive Industry ◽  
High Efficiency ◽  
Management Strategies ◽  
Production Model ◽  
Hydrogen Energy ◽  
Fuel Cell Vehicles ◽  
Energy Applications ◽  
Different Types

Abstract Nowadays, many types of fuel cells have made significant progress. In 2014, they were applied to the production model Toyota’s FCHV-Adv. With their high efficiency and low pollution, fuel cells have gradually started to replace some traditional technologies in many energy applications and production industries and have become a hot topic of interest in recent years. Depending on the type of fuel, there are various types, and different fuel cells work on different principles, leading to differences in their performance. This paper lists the different fuel cells and their application scenarios in the automotive industry. In addition, the use of hydrogen in fuel cell vehicles is also a major concern. This paper briefly discusses the current hydrogen production and four different types of fuel cell vehicles and their energy management strategies. All the technical advantages of fuel cells and hydrogen energy are ultimately reflected in fuel cell vehicles, and this paper describes the current challenges and future possibilities.

scholarly journals Fuel Cells: The Next Evolution

MRS Bulletin ◽  
2005 ◽  
Vol 30 (8) ◽  
pp. 581-586 ◽  
Author(s):  
Robert W. Lashway
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Internal Combustion Engines ◽  
Materials Science ◽  
Electrical Conductance ◽  
Electrical Energy ◽  
Pure Oxygen ◽  
Combustion Engines ◽  
Hydrogen Fuel ◽  
Wide Range

AbstractThe articles in this issue of MRS Bulletin highlight the enormous potential of fuel cells for generating electricity using multiple fuels and crossing a wide range of applications. Fuel cells convert chemical energy directly into electrical energy, and as a powergeneration module, they can be viewed as a continuously operating battery.They take in air (or pure oxygen, for aerospace or undersea applications) and hydrocarbon or hydrogen fuel to produce direct current at various outputs. The electrical output can be converted and then connected to motors to generate much cleaner and more fuelefficient power than is possible from internal combustion engines, even when combined with electrical generators in today's hybrid engines. The commercialization of these fuel cell technologies is contingent upon additional advances in materials science that will suit the aggressive electrochemical environment of fuel cells (i.e., both reducing an oxidizing) and provide ionic and electrical conductance for thousands of hours of operation.

(Invited) Overview of the U.S. Department of Energy’s National Laboratory Consortia to Improve Fuel Cells for Heavy-Duty Applications

2021 ◽  
Vol MA2021-02 (44) ◽  
pp. 1332-1332
Author(s):  
Gregory Kleen ◽  
Dimitrios Papageorgopoulos ◽  
William T Gibbons ◽  
Donna Ho ◽  
David Peterson ◽  
...  
Keyword(s):  
Fuel Cells ◽  
National Laboratory ◽  
Heavy Duty ◽  
The U.S

The LAJ Cycle: A New Combined-Cycle Fossil Fuel Power System

2002 ◽  
Author(s):  
Roddie R. Judkins ◽  
Timothy R. Armstrong ◽  
Solomon D. Labinov
Keyword(s):  
Fuel Cells ◽  
Natural Gas ◽  
Power System ◽  
Fossil Fuel ◽  
High Efficiency ◽  
National Laboratory ◽  
Combined Cycle ◽  
Mitigation Strategies ◽  
Model Calculations ◽  
Oak Ridge

Oak Ridge National Laboratory (ORNL) has developed a novel system for combined-cycle power generation, called the LAJ cycle. This system could serve as a basis for the development of a new generation of high-efficiency combined cycles. In one of several possible configurations of the new combined-cycle fossil fuel power system, natural gas enters the system at 4.0 MPa and about 300 K, is heated and reformed, and is transferred to a turbine at 4.0 MPa and 1200 K. The gas expands in the turbine to 0.6 MPa and 800 K, and then flows successively to heat exchangers and a condenser-separator, after which it is separated into two gas streams, one containing principally CO with some CH4 and water vapor and the other containing pure H2. The CO and H2 flow to separate fuel cells and undergo electrochemical oxidation with the concomitant production of electricity. Separate streams of water and carbon dioxide (CO2) are produced, making this cycle compatible with carbon mitigation strategies based on sequestration. Model calculations indicate combined-cycle efficiencies greater than 70% based on the lower heating value of natural gas. The high efficiencies realized result from a combination of the high-pressure natural gas reformate expansion and the highly efficient CO and H2 fuel cells. Most of the power derives from the fuel cells in the system.

scholarly journals Effect of Cell Size on the Performance and Temperature Distribution of Molten Carbonate Fuel Cells

Energies ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1361 ◽  
Author(s):  
Jae-Hyeong Yu ◽  
Chang-Whan Lee
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Gas Flow ◽  
High Efficiency ◽  
Cross Flow ◽  
Current Density Distribution ◽  
Maximum Temperature ◽  
Similar Distribution ◽  
Molten Carbonate ◽  
Molten Carbonate Fuel Cells

Molten carbonate fuel cells (MCFCs) are high-operating-temperature fuel cells with high efficiency and fuel diversity. Electrochemical reactions in MCFCs are exothermic. As the size of the fuel cells increases, the amount of the heat from the fuel cells and the temperature of the fuel cells increase. In this work, we investigated the relationship between the fuel cell stack size and performance by applying computational fluid dynamics (CFD). Three flow types, namely co-flow, cross-flow, and counter-flow, were studied. We found that when the size of the fuel cells increased beyond a certain value, the size of the fuel cell no longer affected the cell performance. The maximum fuel cell temperature converged as the size of the fuel cell increased. The temperature and current density distribution with respect to the size showed a very similar distribution. The converged maximum temperature of the fuel cells depended on the gas flow condition. The maximum temperature of the fuel cell decreased as the amount of gas in the cathode size increased.

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