Innovative Technologies For Managing Oil Field Waste

2003 ◽  
Vol 125 (3) ◽  
pp. 238-248 ◽  
Author(s):  
John A. Veil

Each year, the oil industry generates millions of barrels of wastes that need to be properly managed. For many years, most oil field wastes were disposed of at a significant cost. However, over the past decade, the industry has developed many processes and technologies to minimize the generation of wastes and to more safely and economically dispose of the waste that is generated. Many companies follow a three-tiered waste management approach. First, companies try to minimize waste generation when possible. Next, they try to find ways to reuse or recycle the wastes that are generated. Finally, the wastes that cannot be reused or recycled must be disposed of. Argonne National Laboratory (Argonne) has evaluated the feasibility of various oil field waste management technologies for the U.S. Department of Energy. This paper describes four of the technologies Argonne has reviewed. In the area of waste minimization, the industry has developed synthetic-based drilling muds (SBMs) that have the desired drilling properties of oil-based muds without the accompanying adverse environmental impacts. Use of SBMs avoids significant air pollution from work boats hauling offshore cuttings to shore for disposal and provides more efficient drilling than can be achieved with water-based muds. Downhole oil/water separators have been developed to separate produced water from oil at the bottom of wells. The produced water is directly injected to an underground formation without ever being lifted to the surface, thereby avoiding potential for groundwater or soil contamination. In the area of reuse/recycle, Argonne has worked with Southeastern Louisiana University and industry to develop a process to use treated drill cuttings to restore wetlands in coastal Louisiana. Finally, in an example of treatment and disposal, Argonne has conducted a series of four baseline studies to characterize the use of salt caverns for safe and economic disposal of oil field wastes.

Author(s):  
John A. Veil

Abstract Each year, the oil industry generates millions of barrels of wastes that need to be properly managed. For many years, most oil field wastes were disposed of at a significant cost. However, over the past decade, the industry has developed many processes and technologies to minimize the generation of wastes and to more safely and economically dispose of the waste that is generated. Many companies follow a three-tiered waste management approach. First, companies try to minimize waste generation when possible. Next, they try to find ways to reuse or recycle the wastes that are generated. Finally, the wastes that cannot be reused or recycled must be disposed of. For the past seven years, Argonne National Laboratory has been evaluating the feasibility of various oil field waste management technologies for the U.S. Department of Energy. This paper provides brief overviews of four of the technologies Argonne has reviewed. In the area of waste minimization, the industry has developed synthetic-based drilling muds (SBMs) that have the desired drilling properties of oil-based muds without the accompanying adverse environmental impacts. Use of SBMs avoids significant air pollution from work boats hauling offshore cuttings to shore for disposal. Downhole oil/water separators have been developed to separate produced water from oil at the bottom of wells. The produced water is directly injected to an underground formation without ever being lifted to the surface, thereby avoiding potential for groundwater or soil contamination. In the area of reuse/recycle, Argonne has worked with Southeastern Louisiana University and industry to develop a process to use treated drill cuttings to restore wetlands in coastal Louisiana. Finally, Argonne has conducted a series of four baseline studies to characterize the use of salt cavern for safe and economic disposal of oil field wastes.


Author(s):  
Kun Chen ◽  
Hanchung Tsai ◽  
Bud Fabian ◽  
Yung Liu ◽  
James Shuler

A temperature-monitoring system based on radiofrequency identification (RFID) has been developed for extending the maintenance period of the nuclear material packaging for storage and transportation. The system consists of tags, readers, and application software. The tag, equipped with a temperature sensor, is attached to the exterior of a package. The application software enables remote reading, via radio waves, of the temperature from the sensor in the tag. The system reports any temperature violations immediately via e-mail or text message, and/or posts the alarm on a secure website. The system can monitor thousands of packages and record individual temperature histories in a database. The first type of packaging that will benefit from the RFID technology is Model 9977, which has been certified by the U.S. Department of Energy (DOE) to ship and store fissile materials such as plutonium and uranium. The recorded data can be correlated to the temperature of the containment O-ring seals, based on the decay heat load of the contents. Accelerated aging studies of the Viton® GLT O-rings have shown that temperature is one of the key parameters governing the life of the O-ring seals, which maintain the integrity of the containment boundary of the package. Use of the RFID temperature-monitoring system to verify that the surface temperature remains below a certain threshold will make it possible to extend the leak-test period of the package from one year to up to five years. The longer leak-rate testing interval will yield a cost savings of up to $10,000 per package over five years. This work was conducted by Argonne National Laboratory in support of the DOE Packaging Certification Program, Office of Environmental Management, Office of Packaging and Transportation (EM-63).


2021 ◽  
Author(s):  
Leroy Walston ◽  
Heidi Hartmann

<p>Concomitant with the increase in solar photovoltaic (PV) energy development over the past decade has been the increasing emphasis on land sharing strategies that maximize the land use efficiency of solar energy developments.  Many of these strategies focus on improving the compatibility of solar energy development with other co-located land uses (e.g., agriculture) and by improving several ecosystem services that could have natural, societal, and industrial benefits. One such land opportunity is the restoration and management of native grassland vegetation beneath ground-mounted PV solar energy facilities, which has the potential to restore native habitat to conserve biodiversity and restore previously altered ecosystem services (e.g., natural pollination services). This presentation will discuss various assessment and modeling approaches to evaluate the scale and magnitude of the ecosystem services provided by different vegetation management strategies at solar PV energy development sites. This work demonstrates how multifunctional land uses in energy systems represents a win-win solution for energy and the environment by optimizing energy-food-ecology synergies. This work was conducted by Argonne National Laboratory for the U.S. Department of Energy Solar Energy Technologies Office under Contract No. DE-AC02-06CH11357.</p>


Author(s):  
W. David Pointer ◽  
Tanju Sofu ◽  
David Weber

The issue of energy economy in transportation has grown beyond traditional concerns over environment, safety and health to include new concerns over national and international security. In collaboration with the U.S. Department of Energy Office of FreedomCAR and Vehicle Technologies’ Working Group on Aerodynamic Drag of Heavy Vehicles, Argonne National Laboratory is investigating the accuracy of aerodynamic drag predictions from commercial Computational Fluid Dynamics (CFD) Software. In this validation study, computational predictions from two commercial CFD codes, Star-CD [1] and PowerFLOW [2], will be compared with detailed velocity, pressure and force balance data from experiments completed in the 7 ft. by 10 ft. wind tunnel at NASA Ames [3, 4] using a Generic Conventional Model (GCM) that is representative of typical current-generation tractor-trailer geometries.


Author(s):  
John A. Michelbacher ◽  
Carl E. Baily ◽  
Daniel K. Baird ◽  
S. Paul Henslee ◽  
Collin J. Knight ◽  
...  

The Department of Energy mandated the termination of the Integral Fast Reactor (IFR) Program, effective October 1, 1994. To comply with this decision, Argonne National Laboratory-West (ANL-W) prepared a plan providing detailed requirements to maintain the Experimental Breeder Reactor-II (EBR-II) in a radiologically and industrially safe condition, including removal of all irradiated fuel assemblies from the reactor plant, and removal and stabilization of the primary and secondary sodium, a liquid metal used to transfer heat within the reactor plant. The EBR-II is a pool-type reactor. The primary system contained approximately 325 m3 (86,000 gallons) of sodium and the secondary system contained 50 m3 (13,000 gallons). In order to properly dispose of the sodium in compliance with the Resource Conservation and Recovery Act (RCRA), a facility was built to react the sodium to a solid sodium hydroxide monolith for burial as a low level waste in a land disposal facility. Deactivation of a liquid metal fast breeder reactor (LMFBR) presents unique concerns. Residual amounts of sodium remaining in circuits and components must be passivated, inerted, or removed to preclude future concerns with sodium-air reactions that could generate potentially explosive mixtures of hydrogen and leave corrosive compounds. The passivation process being implemented utilizes a moist carbon dioxide gas that generates a passive layer of sodium carbonate/sodium bicarbonate over any quantities of residual sodium. Tests being conducted will determine the maximum depths of sodium that can be reacted using this method, defining the amount that must be dealt with later to achieve RCRA clean closure. Deactivation of the EBR-II complex is on schedule for a March, 2002, completion. Each system associated with EBR-II has an associated layup plan defining the system end state, as well as instructions for achieving the layup condition. A goal of system-by-system layup is to minimize surveillance and maintenance requirements during the interim period between deactivation and decommissioning. The plans also establish document archival of not only all the closure documents, but also the key plant documents (P&IDs, design bases, characterization data, etc.) in a convenient location to assure the appropriate knowledge base is available for decommissioning, which could occur decades in the future.


Author(s):  
Mary D. McDermott ◽  
Charles D. Griffin ◽  
Daniel K. Baird ◽  
Carl E. Baily ◽  
John A. Michelbacher ◽  
...  

The Experimental Breeder Reactor - II (EBR-II) at Argonne National Laboratory - West (ANL-W) was shutdown in September 1994 as mandated by the United States Department of Energy. Located in eastern Idaho, this sodium-cooled reactor had been in service since 1964, and was a test facility for fuels development, materials irradiation, system and control theory tests, and hardware development. The EBR-II termination activities began in October 1994, with the reactor being maintained in an industrially and radiologically safe condition for decommissioning. With the shutdown of EBR-II, its sodium coolant became a waste necessitating its reaction to a disposal form. A Sodium Process Facility (SPF), designed to convert sodium to 50 wt% sodium hydroxide, existed at the ANL-W site, but had never been operated. The SPF was upgraded to current standards and codes, and then modified in 1998 to convert the sodium to 70 wt% sodium hydroxide, a substance that solidifies at 65°C (150°F) and is acceptable for burial as low level radioactive waste in Idaho. In December 1998, the SPF began operations. Working with sodium and highly concentrated sodium hydroxide presented some unique operating and maintenance conditions. Several lessons were learned throughout the operating period. Processing of the 330 m3 (87,000 gallons) of EBR-II primary sodium, 50 m3 (13,000 gallons) of EBR-II secondary sodium, and 290 m3 (77,000 gallons) of Fermi-1 primary sodium was successfully completed in March 2001, ahead of schedule and within budget.


Author(s):  
A. V. Kuzmin ◽  
A. V. Radkevich ◽  
V. P. Petrushkevich ◽  
N. D. Kuzmina

The aim of the current work is to perform a probabilistic dose assessment to quantify the relative importance of the source data uncertainties contribution towards the uncertainty estimates of collective and maximum individual doses of personnel during decommissioning of a storage facility. A probabilistic approach to the analysis of dose loads, including the analysis of sensitivity and uncertainty with respect to the input parameters of the used calculation models of dose assessment, allows to determine the most sensitive parameters, inaccuracies in the task of which lead to significant uncertainties in the estimates of dose loads on personnel and, therefore, require more accurate determination of conservative boundary values in deterministic analysis and safety justification. The calculations were performed by applying the code RESRAD-BUILD 3.50, developed by the Argonne National Laboratory of the US Department of Energy. The obtained results allow us to rank the parameters of the computational model according to the degree of their influence on the uncertainty of the final estimates of the dose loads on personnel, to develop recommendations for optimizing dose loads when performing radiation-hazardous work during nuclear facilities decommissioning.


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