<p>This work aims to assess the summer PM<sub>1</sub> based on particle size distribution, density and origin. An intensive sampling campaign was conducted in July 2019 at the National Atmospheric Observatory Ko&#353;etice (NAOK) in the Czech Republic.</p><p>5-min integrals of particle number concentration (PNC) and particle number size distribution (PNSD) data were recorded by a Scanning Mobility Particle Sizer (size range 10 &#8211; 800 nm, SMPS, IFT TROPOS, Leipzig, with CPC 3772, TSI USA) and size-resolved PM chemical composition was measured by a Compact Time of Flight Aerosol Mass Spectrometer (C-ToF-AMS, Aerodyne, USA). 1-min PM<sub>1 </sub>black carbon (BC) concentrations by aethalometer (AE33, Magee Scientific, USA) and 4-h PM<sub>2.5 </sub>organic and elemental carbon (OC/EC) concentrations (Sunset Laboratory Inc., USA) were measured.&#160; Also 12-h PM<sub>1</sub> samples by a sequential Leckel LVS-3 (Sven Leckel Ingenieurb&#252;ro, Germany) for a subsequent chemical analysis (water-soluble ions, monosaccharides, anhydrides, and saccharides) were collected. Additionally, 10-min average SO<sub>2</sub>, NO<sub>2</sub>, NO<sub>x</sub> and CO concentrations along with the values of meteorological parameters were recorded. To determine the origin of non-refractory PM<sub>1</sub> (NR-PM<sub>1</sub>) species (Org, NO<sub>3</sub><sup>-</sup>, SO<sub>4</sub><sup>2-</sup>, NH<sub>4</sub><sup>+</sup>) the back trajectories describing the air mass origin were clustered using the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model [1]. Last, but not least, the multi-time factor analysis model [2] with modifications was applied on combined dataset (on-line and off-line measurements) to refine the analysis results with respect to the organic aerosol factors as well as organic aerosol sources and their origin.</p><p>The campaigns was characterized by prevailing westerly winds with average wind speed of 3.0&#177;1.5 m s<sup>-1</sup>, average temperature of 18.5&#177;4.7 &#176;C and negligible precipitation. The average PM<sub>1</sub> (NR-PM<sub>1</sub> and eBC) measured concentration was 8.5&#177;3.5 &#181;g m<sup>-3</sup> (12h PM<sub>1</sub> 10.1&#177;6.4 &#181;g m<sup>-3</sup>). Based on the PNC predominated particles in the size range 25 &#8211; 80 nm (N25 &#8211; 50 and N50 &#8211; 80), also called the Aitken mode, typical for rural background stations and originates from the aging of the particles generated during new particle formation events [3]. NR-PM<sub>1</sub> was composed primarily by organics (58%) and sulphate (22%) in the accumulation mode (Org mode diameter 300 nm and SO<sub>4</sub><sup>2-</sup> mode diameter 385 nm) with average particle density ~ 1.4 g m<sup>-3</sup>. This result in combination with the cluster analysis points to the regional origin of the particles from southeast (Austria-Hungary-Slovakia). Six Org factors (primary organic aerosol (POA) &#8211; fungal origin, biomass burning organic aerosol (BBOA) &#8211; related secondary aerosol (SA), semivolatile aerosol &#8211; nitrate-rich, secondary organic aerosol (SOA) &#8211; oxalate-rich, semivolatile aerosol &#8211; microbial origin, primary traffic and biomass organic aerosol (OA)) based on combined data were resolved by multi-time factor analysis model. Modelling of combined dataset provided insides into processes involved in SOA formation and sources.</p><p>&#160;</p><p>[1] Rolph, G., et al., (2017) Environ. Modell. Software 95, 210&#8211;228.</p><p>[2] Zhou, L., et al., (2004) Atmos. Environ. 38, 4909&#8211;4920.</p><p>[3] Costabile, F., et al., (2009) Atmos. Chem. Phys. 9, 3163&#8211;3195.</p><p>&#160;</p><p>This work was supported by the GACR under grant P209/19/06110Y and by the MEYS of the Czech Republic under grant ACTRIS-CZ LM2018122 and ACTRIS-CZ RI (CZ.02.1.01/0.0/0.0/16_013/0001315).</p>