scholarly journals TREATMENT OF RUBBER INDUSTRY WASTEWATER BY USING FENTON REAGENT AND ACTIVATED CARBON

2017 ◽  
Vol 79 (7-2) ◽  
Author(s):  
Tuty Emilia Agustina ◽  
Elon Jefri Sirait ◽  
Herman Silalahi
Keyword(s):  
Activated Carbon ◽  
Reaction Time ◽  
Oxygen Demand ◽  
Quality Standard ◽  
Molar Ratio ◽  
Fenton Reagent ◽  
Activated Carbon Adsorption ◽  
Rubber Industry ◽  
Rubber Wastewater ◽  
The Impact

Rubber industries are sufficiently developed and widely spread countryside as well as in some big cities in Indonesia. An Increasing number of rubber industries have also increased rubber wastewater. However, the rubber industry development should pay attention to the impact on the environment. The rubber wastewater is problematic, because of high Chemical Oxygen Demand (COD) content. So far, the methods that have been used to remove COD in the waste water have been proven to be costly and time consuming. The research objective is to treat the rubber wastewater by using a combination of Fenton reagent and activated carbon adsorption. In this study, effect of molar ratios of Fenton reagent, pH, and reaction time on COD degradation were studied. After treating with Fenton reagent, the wastewater was passed into an adsorption column of 20 cm height of activated carbon granules. The maximum COD degradation of 95% were found by using a combination of Fenton reagent and activated carbon, with a molar ratio of reagent Fenton 1:250 and a reaction time of 45 minutes. The final COD of 71 mg/l, TSS of 70 mg/l, and pH of 7.8 were found which fulfilled the environmental quality standard regulation for industrial wastewater in Indonesia. 

scholarly journals Enhancement of COD Removal from Oilfield Produced Wastewater by Combination of Advanced Oxidation, Adsorption and Ultrafiltration

2019 ◽  
Vol 16 (17) ◽  
pp. 3223 ◽  
Author(s):  
Xiaodong Dai ◽  
Jian Fang ◽  
Lei Li ◽  
Yan Dong ◽  
Jianhua Zhang
Keyword(s):  
Activated Carbon ◽  
High Salinity ◽  
Oxygen Demand ◽  
Suspended Solid ◽  
Fenton Oxidation ◽  
Molar Ratio ◽  
Activated Carbon Adsorption ◽  
Sodium Dodecylbenzenesulfonate ◽  
Operational Conditions ◽  
Carbon Adsorption

The wastewater produced from the oilfield is chemically corrosive due to high salinity in combination with high temperatures. It is also rich in contaminants, such as oil, polyacrylamide, emulsions, suspended solid, etc. The density difference between the oil and water in the wastewater is low, which makes separation via gravity difficult. In this study, a combined pilot treatment is studied, which includes Fenton oxidation, settlement, activated carbon adsorption, and ultrafiltration (UF). The operational conditions of Fenton oxidation are optimized based on alleviating the fouling of the UF membrane. When the Fenton oxidation was operated at the molar ratio of H2O2 to FeSO4 3:1 and pH 2.2–2.5, the UF membrane could operate continuously for 20 h without cleaning. The membrane was fouled by the organics (oil/grease) and polymer, which can be effectively removed by composite cleaning reagent consisting of 0.1% NaOH and 0.1% sodium dodecylbenzenesulfonate (SDBS). With the UF treatment, the chemical oxygen demand (COD) of the effluent was less than 50 mg/L, which could meet the upgraded standard.

scholarly journals Study on Chromaticity Removal from Mineral Processing Wastewater with Salicylic Hydroxamic Acid by Granular Activated Carbon Catalyzed Ozonation

Minerals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 359
Author(s):  
Liping Zhang ◽  
Shengnian Wu ◽  
Nan Zhang ◽  
Ruihan Yao ◽  
Eryong Wu
Keyword(s):  
Activated Carbon ◽  
Reaction Time ◽  
Hydroxamic Acid ◽  
Ph Value ◽  
Oxygen Demand ◽  
Granular Activated Carbon ◽  
Mineral Processing ◽  
Ultraviolet Absorption Spectrum ◽  
Experimental Conditions ◽  
Removal Ratio

Salicylic hydroxamic acid is a novel flotation reagent used in mineral processing. However, it impacts the flotation wastewater leaving behind high chromaticity which limits its reuse and affects discharge for mining enterprises. This study researched ozonation catalyzed by the granular activated carbon (GAC) method to treat the chromaticity of the simulated mineral processing wastewater with salicylic hydroxamic acid. The effects of pH value, ozone (O3) concentration, GAC dosage, and reaction time on chromaticity and chemical oxygen demand (CODCr) removal were discussed. The results of individual ozonation experiments showed that the chromaticity removal ratio reached 79% and the effluent chromaticity exceeded the requirement of reuse and discharge when the optimal experimental conditions were pH value 3, ozone concentration 6 mg/L, and reaction time 40 min. The orthogonal experimental results of catalytic ozonation with GAC on chromaticity removal explained that the chromaticity removal ratio could reach 96.36% and the chromaticity of effluent was only 20 when the optimal level of experimental parameters was pH value 2.87, O3 concentration 6 mg/L, GAC dosage 0.06 g/L, reaction time 60 min respectively. The degradation pathway of salicylic hydroxamic acid by ozonation was also considered based on an analysis with ultraviolet absorption spectrum and high-performance liquid chromatography (HPLC).

Optimization and statistical analysis of sono-Fenton treated wastewater of food industry using reactor by response surface method

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Vijay A. Juwar ◽  
Ajit P. Rathod
Keyword(s):  
Reaction Time ◽  
Response Surface ◽  
Food Industry ◽  
Batch Reactor ◽  
Oxygen Demand ◽  
Volume Ratio ◽  
Cod Removal ◽  
Treated Wastewater ◽  
Experimental Result ◽  
Molar Ratio

Abstract The present study deals with the treatment of complex waste (WW) treated for removal of chemical oxygen demand (COD) of the food industry by a sono-Fenton process using a batch reactor. The response surface methodology (RSM) was employed to investigate the five independent variables, such as reaction time, the molar ratio of H2O2/Fe2+, volume ratio of H2O2/WW, pH of waste, and ultrasonic density on COD removal. The experimental data was optimized. The optimization yields the conditions: Reaction time of 24 min, HP:Fe molar ratio of 2.8, HP:WW volume ratio of 1.9 ml/L, pH of 3.6 and an ultrasonic density of 1.8 W/L. The predicted value of COD was 91% and the experimental result was 90%. The composite desirability value (D) of the predicted percent of COD removal at the optimized level of variables was close to one (D = 0.991).

scholarly journals The Impact of Floating Net Cage (FNC) on Primary Productivity in Cirata Reservoir Waters

2021 ◽  
pp. 35-42
Author(s):  
Sayyid Arrasyid ◽  
Zahidah Hasan ◽  
Izza Mahdiana Apriliani ◽  
Heti Herawati
Keyword(s):  
Water Quality ◽  
Primary Productivity ◽  
Local Community ◽  
Oxygen Demand ◽  
Quality Standard ◽  
Water Volume ◽  
Physical Parameters ◽  
Reservoir Water ◽  
Net Cages ◽  
The Impact

Cirata Reservoir is one of the three cascade reservoirs fed by the Citarum Watershed with an area of ​​62 km2 (6.200 ha) and has a water volume of 1.900 million m3. The great potential of the waters in the Cirata Reservoir is utilized by the local community as a source of livelihood, namely by conducting aquaculture activities using floating net cages (FNC) in excess. FNC is thought to be a source of waste that reduces reservoir water quality. This research aims to determine the impact of FNC cultivation on primary productivity with different FNC densities at each station. The research was conducted in Cianjur Regency by taking on three stations, namely in the areas of Jangari, Maleber, and Patok Beusi on November 6 - December 8, 2019. The method used in the research was purposive sampling then analyzed in detail and quantitatively. The results show that reservoir waters have an average of physical parameters, namely temperature 32.2-32.6oC, transparency 0.59-0.68 meters, pH 7.1-7.3, carbon dioxide 15.4-16.1 mg / l, Dissolved Oxygen 6.9-7.3 mg / l, Biochemical Oxygen Demand 6.1-7.8 mg / l, nitrate 0.208-0.222 mg / l, ammonia 0.002833-0.003056 mg / l, phosphate 0,165-0,167 mg / l and primary productivity 240,36-277,90 mgC/m3/hour. This shows that the water indicator is still classified as good because it does not exceed the water quality standard.

Treatment of landfill leachates by comparing advanced oxidation and coagulation-flocculation processes coupled with activated carbon adsorption

2000 ◽  
Vol 41 (1) ◽  
pp. 231-235 ◽  
Author(s):  
R.M. Ramíirez Zamora ◽  
A. Durán Moreno ◽  
M.T. Ortade Velásquez ◽  
I. Monje Ramírez
Keyword(s):  
Activated Carbon ◽  
Organic Compounds ◽  
Oxygen Demand ◽  
Continuous Reactor ◽  
Landfill Leachates ◽  
Activated Carbon Adsorption ◽  
Colour Removal ◽  
Carbon Adsorption ◽  
The One ◽  
Flocculation Process

This work compares two pre-treatments (coagulation-flocculation process (CF) and the Fenton oxidation Method (FE)) of the activated carbon adsorption process (AC) to optimize the removal of the organic compounds in landfill leachates. The content of organic compounds was measured in terms of three global parameters: colour, chemical oxygen demand (COD) and dissolved organic carbon (DOC). The result obtained in discontinuous reactor conditions showed an increase in colour removal from 1.5 to 2.0 times and a decrease of COD between 0.3 to 0.5 times for the FE-AC treatment, in relation to the CF-AC treatment. On the other hand, the data obtained in continuous reactor conditions (packed columns) showed that the column fed with leachate CF exhibited operation times 1.3 times longer and a better physiochemical quality in the filtrate (COD and colour) than the one fed with the FE leachate. Nevertheless, the adsorption capacities in the colour removal column of COD and DOC were higher for the FE leachate.

Microwave-Ferrous Sulfate Modified Activated Carbon Adsorption Study on Phosphorus Removal

2014 ◽  
Vol 919-921 ◽  
pp. 2149-2152
Author(s):  
Ya Feng Li ◽  
Chun Fei Wei
Keyword(s):  
Activated Carbon ◽  
Reaction Time ◽  
Phosphorus Removal ◽  
Ferrous Sulfate ◽  
Removal Rate ◽  
High Concentration ◽  
Activated Carbon Adsorption ◽  
Modified Activated Carbon ◽  
Carbon Adsorption ◽  
Treated Effluent

Using microwave-ferrous sulfate modified activated carbon adsorption manner to remove the high concentration of phosphorus in wastewater. The power of microwavethe concentration of ferrous sulfate and reaction time on phosphorus removal were studied. When the power of microwave was 425W,the concentration of ferrous sulfate was 0.1mol/L,reaction time was 50 min,the removal rate of TP reaches 95.67%,the treated effluent TP can be dropped to 0.48mg/L,the TP can reaches the first effluent standard of TP in the comprehensive wastewater discharge standard (GB8978-1996).Microwave-ferrous sulfate modified activated carbon is adapted to treat high concentration phosphorus in the wastewater.

scholarly journals The influence of ozonation on the activated carbon adsorption of phenol and humic acid

2007 ◽  
Vol 9 (4) ◽  
pp. 107-110 ◽  
Author(s):  
Bożena Seredyńska-Sobecka ◽  
Maria Tomaszewska
Keyword(s):  
Activated Carbon ◽  
Humic Acid ◽  
Oxygen Demand ◽  
Freundlich Isotherm ◽  
Model Solution ◽  
Activated Carbon Adsorption ◽  
Phenol Adsorption ◽  
Isotherm Equation ◽  
Carbon Adsorption

The influence of ozonation on the activated carbon adsorption of phenol and humic acid To study the influence of ozonation on the activated carbon adsorption, a model solution containing approximately 8 mg/dm3 of humic acid and approximately 1 mg/dm3 of phenol has been ozonated, and then adsorption kintetics and adsorption isotherm experiments have been performed. The applied ozone doses ranged from 1 to 3 mg O3/dm3, and a contact time was 1 min. In the adsorption experiments, the commercial activated carbon CWZ-30 (Gryfskand Sp. z o.o., Hajnówka, Poland) has been used. Phenol adsorption under equilibrium conditions was determined by the Freundlich isotherm equation, and the modified Freudlich isotherm equation has been employed for the determination of humic acid equilibrium adsorption. The applied oxidation conditions resulted in color, chemical oxygen demand (COD), total organic carbon (TOC) and UV254 absorbance removal, by 4 - 13%, 3 - 6%, 3 - 7%, respectively. After ozonation, phenol concentration decreased by 6 - 23%. These changes in the model solution did not affect the humic acid adsorption, however, they deteriorated phenol adsorption.

scholarly journals Treatment of hazardous waste landfill leachate using Fenton oxidation process

2018 ◽  
Vol 34 ◽  
pp. 02034 ◽  
Author(s):  
Pradeep Kumar Singa ◽  
Mohamed Hasnain Isa ◽  
Yeek-Chia Ho ◽  
Jun-Wei Lim
Keyword(s):  
Reaction Time ◽  
Hazardous Waste ◽  
Landfill Leachate ◽  
Molar Ratio ◽  
Oh Radicals ◽  
Fenton Reagent ◽  
Leachate Treatment ◽  
Experimental Conditions ◽  
Waste Landfill ◽  
Hazardous Waste Landfill

The efficiency of Fenton’s oxidation was assessed in this study for hazardous waste landfill leachate treatment. The two major reagents, which are generally employed in Fenton’s process are H2O2 as oxidizing agent and Fe2+ as catalyst. Batch experiments were conducted to determine the effect of experimental conditions viz., reaction time, molar ratio, and Fenton reagent dosages, which are significant parameters that influence the degradation efficiencies of Fenton process were examined. It was found that under the favorable experimental conditions, maximum COD removal was 56.49%. The optimum experimental conditions were pH=3, H2O2/Fe2+ molar ratio = 3 and reaction time = 150 minutes. The optimal amount of hydrogen peroxide and iron were 0.12 mol/L and 0.04 mol/L respectively. High dosages of H2O2 and iron resulted in scavenging effects on OH• radicals and lowered degradation efficiency of organic compounds in the hazardous waste landfill leachate.

Catalytic Synthesis of Isoamyl Acetate Catalyzed by (NH4)6[MnMo9O32]•8H2O Supported Activated Carbon with Waugh Structure

2013 ◽  
Vol 781-784 ◽  
pp. 190-193
Author(s):  
Mei Xu ◽  
Hua Yuan ◽  
Wei Liu ◽  
Jian Wang ◽  
Feng Zhen Yang
Keyword(s):  
Acetic Acid ◽  
Activated Carbon ◽  
Reaction Time ◽  
Conversion Rate ◽  
Isoamyl Alcohol ◽  
Isoamyl Acetate ◽  
Catalytic Synthesis ◽  
Molar Ratio ◽  
Reaction Conditions ◽  
Optimum Reaction

The synthesis of isoamyl acetate with ammonium 9-molybdate manganese heteropolyacid salt supported activated carbon as catalyst was studied. The optimum reaction conditions are obtained as follows: isoamyl alcohol to acetic acid molar ratio = 1.646, the weight of catalyst is 40% of total weigh, m (acidulate catalyst)=0.2g, m (water carrying reagent toluene) = 3ml, reaction time is about 63 minutes. Selectivity is 100% and conversion rate is 89.48%.

scholarly journals Optimization of electro-Fenton oxidation of carbonated soft drink industry wastewater using response surface methodology

2020 ◽  
Vol 39 (2) ◽  
pp. 129
Author(s):  
Reza Davarnejad ◽  
Jamal Azizi ◽  
Amir Joodaki ◽  
Sepideh Mansoori
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Current Density ◽  
Volume Fraction ◽  
Soft Drink ◽  
Oxygen Demand ◽  
Volume Ratio ◽  
Organic Pollution ◽  
Molar Ratio ◽  
The Impact

The immense volume of highly polluted organic wastewater continuously generated in the beverage industry urges the design of new types of wastewater treatment plants. This study aimed to evaluate the applicability of the electro-Fenton (EF) technique to reduce organic pollution of real effluent from a carbonated soft drink factory. The impact of various process variables like pH, time, current density, H2O2/Fe2+ molar ratio, and the volume ratio of H2O2/soft drink wastewater (SDW) was analyzed using response surface methodology (RSM). The observed responses were in good agreement with predicted values obtained through optimization. The optimum conditions showed a chemical oxygen demand (COD) removal efficiency of 73.07 %, pH of 4.14, time of 41.55 min, current density of 46.12 mA/cm2, H2O2/Fe2+ molar ratio of 0.9802, and H2O2/SDW volume fraction of 2.74 ml/l. The EF process was able to effectively diminish the organic pollution, reduce the residence time and, therefore, the operating costs.

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