Electrospun Conditions of Poly(vinyl chloride) Nanofibrous Membrane Plasticized with Polyurethane

2014 ◽  
Vol 68 (5) ◽  
Author(s):  
Kritsada Phatcharasit ◽  
Wirach Taweepreda ◽  
Kanoktip Boonkerd ◽  
Jin-Kuk Kim
Keyword(s):  
Electron Microscopy ◽  
Thermal Analysis ◽  
Scanning Electron Microscopy ◽  
Dielectric Constant ◽  
Glass Transition ◽  
Thermal Properties ◽  
Vinyl Chloride ◽  
Poly Vinyl Chloride ◽  
Lcr Meter ◽  
Scanning Electron

Electrospun poly(vinyl chloride) (PVC) nanofibrous were prepared by electrospinning. Various concentration of polyurethane (PU) were added to PVC solution for plasticization of the electrospun nanofibrous. The pristine and plasticized nanofibrous were characterized by field emission scanning electron microscopy (FE-SEM), differencial thermal analysis (DTA), and thermogravimetry analysis (TGA), respectively. Thermal properties form DTA and TGA results indicated that the addition of PU decreased glass transition temperature (Tg) of PVC and increased heat resistance of PVC nanofiber. The dielectric constant of plasticized nanofibrous measured using precision LCR meter indicated that the membrane were dense.  

Electrospun Epoxidized Natural Rubber with Poly(vinyl chloride) (ENR-PVC) Nanofibrous for PEMFC Applications

2013 ◽  
Vol 844 ◽  
pp. 507-510 ◽  
Author(s):  
Kritsada Phatcharasit ◽  
Wirach Taweepreda ◽  
Kanoktip Boonkerd ◽  
Jin Kuk Kim
Keyword(s):  
Electron Microscopy ◽  
Thermal Analysis ◽  
Scanning Electron Microscopy ◽  
Natural Rubber ◽  
Vinyl Chloride ◽  
Epoxidized Natural Rubber ◽  
Electrospinning Technique ◽  
Poly Vinyl Chloride ◽  
Ft Ir ◽  
Scanning Electron

Various electrospun epoxized natural rubber / poly (vinyl chloride) (ENR/PVC) blend nonwoven membranes were prepared by electrospinning technique. Various concentration of epoxidized natural rubber (ENR) solution in N,N-dimethylformamide (DMF) were directly added to PVC solution for plasticization of the electrospun nanofibrous. Differencial thermal analysis (DTA), thermogravimetry analysis (TGA), fourier transfrom infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM) were used to characterize the pristine and plasticized nanofibrous. DTA results indicated that the addition of ENR resulted in the shifting of glass transition temperature (Tg) towards lower temperatures. The blending of PVC with ENR is thermodynamically incompatible.

Preparation and Properties of Electrospun PVC Nanofiber

2013 ◽  
Vol 770 ◽  
pp. 193-196 ◽  
Author(s):  
Kritsada Phatcharasit ◽  
Wirach Taweepreda ◽  
Kanoktip Boonkerd ◽  
Jin Kuk Kim
Keyword(s):  
Thermal Analysis ◽  
Thermal Properties ◽  
Smooth Surface ◽  
Mixed Solvent ◽  
Electric Voltage ◽  
Poly Vinyl Chloride ◽  
Electrospun Membranes ◽  
Lcr Meter ◽  
Solution Parameters ◽  
Scanning Electron

Nanofibrous membranes based on poly (vinyl chloride) (PVC) were prepared by electrospinning. The morphology of nanofibrous was observed under field emission scanning electron microscope (FE-SEM) and effects of instrument parameters including electric voltage, tip to collector distance, and solution parameters such as PVC concentration and mixed solvent of THF and DMF (50:50) were evaluated. The beads on the fiber were formed with low concentration of PVC. The dielectric constant, thermal properties and crystallinity of the electrospun membranes were characterized by precision LCR meter, and differential thermal analysis (DTA), respectively. It was found that smooth surface of electrospun PVC nanofiber had a high ionic conductivity and their thermal properties were improved comparing with PVC sheet.

scholarly journals Valorisation of chicken feather fibres in developing poly (vinyl chloride) biocomposites

2021 ◽  
Author(s):  
Soumia Touatou ◽  
Naima Belhaneche-Bensemra
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Thermogravimetric Analysis ◽  
Vinyl Chloride ◽  
Morphological Properties ◽  
Chicken Feather ◽  
Chicken Feathers ◽  
Poly Vinyl Chloride ◽  
Two Temperatures ◽  
Scanning Electron

Abstract The aim of this paper is the valorisation of fibres obtained from chicken feathers in developing new poly (vinyl chloride) (PVC) biocomposites. Feather fibres were first characterized by thermogravimetric analysis and scanning electron microscopy. Then, semi-rigid and flexible PVC biocomposites were prepared by varying the fibre (5, 10 and 15 wt %) and plasticizer (15, 30, 45, 60 wt %) contents. The density, mechanical, thermal and morphological properties of the composites were investigated. The water absorption was determined at two temperatures (23 and 60°C). The results showed the influence of fibre and plasticizer contents on the considered properties.

Poly(Vinyl Chloride) Containing Gynostemma pentaphyllum as a Photostabilizer

2021 ◽  
Vol 1021 ◽  
pp. 251-259
Author(s):  
Zeyad Fadhil ◽  
Hadeel Adil ◽  
Raghda Alsayed ◽  
Mohammed H. Al-Mashhadani ◽  
Ali H. Jawad ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Vinyl Chloride ◽  
Aging Process ◽  
Uv Light ◽  
Polymeric Films ◽  
Gynostemma Pentaphyllum ◽  
Poly Vinyl Chloride ◽  
Electronic Microscope ◽  
Scanning Electron

Novel extracted natural stabilizer for the polymer was investigated in this study. The natural anti-aging was extracted from plants and it is demonstrated that this type of stabilizers are suitable for biodegradable polymers. Gynostemma pentaphyllum (0.01–0.03 wt%) were extracted and added to the poly(vinyl chloride) blend. The achieved polymeric films were exposed to an accelerated UV light aging process for 300 hours at ambient temperature. The efficiency of tested natural stabilizer was linked to blank PVC films. FTIR spectroscopy, weight loss, electronic microscope and scanning electron microscopy were performed. Using small amount of natural stabilizer is significantly beneficial because it does not influence the PVC properties.

PENINGKATAN LAJU DISOLUSI ACYCLOVIR DENGAN METODE SISTEM DISPERSI PADAT MENGGUNAKAN POLOXAMER 188

2016 ◽  
Vol 5 (1) ◽  
pp. 6
Author(s):  
Budi Setiawan ◽  
Erizal Zaini ◽  
Salman Umar
Keyword(s):  
Electron Microscopy ◽  
Thermal Analysis ◽  
Scanning Electron Microscopy ◽  
Fourier Transform ◽  
Differential Thermal Analysis ◽  
Fourier Transform Infrared ◽  
X Ray Diffraction ◽  
Poloxamer 188 ◽  
X Ray ◽  
Scanning Electron

Sebuah penelitian tentang sistem dispersi padat dari asiklovir dengan poloxamer 188 telah dilakukan formulasi dengan pencampuran secara fisika dengan rasio 1 : 1, 1 : 3, 1 : 5 dan dispersi padat 1 : 1, 1 : 3, 1 : 5 dan penggilingan 1:1 sebagai pembanding. Dispersi padat dibuat menggunakan metode pencairan (fusi), yang digabung dengan poloxamer 188 pada hotplate kemudian asiklovir dimasukkan ke dalam hasil poloxamer 188 lalu di kocok hingga membentuk masa homogen. Semua formula yang terbentuk termasuk asiklovir poloxamer 188 murni dianalisis karakterisasinya dengan Differential Thermal Analysis (DTA), X-ray Diffraction, Scanning Electron Microscopy (SEM), dan Fourier Transform Infrared (FTIR), kemudian pengambilan dilakukan  (penentuan kadar) mengunakan spektrofotometer UV pada panjang gelombang 257,08 nm dan uji laju disolusi dengan aquadest bebas CO2 menggunakan metode dayung. Hasil pengambilan  (penentuan kadar) menunjukkan bahwa semua formula memenuhi persyaratan farmakope Amerika edisi 30 dan farmakope Indonesia edisi 4 yaitu 95-110%. Sedangkan hasil uji laju disolusi untuk campuran fisik 1: 1, dan dispersi padat 1: 1, dan penggilingan 1: 1 menunjukkan peningkatan yang nyata dibandingkan asiklovir murni. Hal ini juga dapat dilihat dari hasil perhitungan statistik  menggunakan analisis varian satu arah  SPSS 17.

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