Mechanistic Studies on the Salicylate‐Catalyzed Peroxyoxalate Chemiluminescence in Aqueous Medium

2019 ◽  
Vol 96 (1) ◽  
pp. 28-36 ◽  
Author(s):  
Maidileyvis C. Cabello ◽  
Glalci A. Souza ◽  
Liena V. Bello ◽  
Wilhelm J. Baader
Keyword(s):  
Aqueous Medium ◽  
Mechanistic Studies ◽  
Peroxyoxalate Chemiluminescence

Ruthenium-Promoted Acceptorless and Oxidant-Free Lactone Synthesis in Aqueous Medium

Synlett ◽  
2019 ◽  
Vol 30 (06) ◽  
pp. 721-725 ◽  
Author(s):  
Senthilkumar Muthaiah ◽  
Anita Bhatia ◽  
Muthukumar Kannan
Keyword(s):  
Aqueous Medium ◽  
Ruthenium Complexes ◽  
Water Soluble ◽  
Side Product ◽  
Mechanistic Studies ◽  
Hydrogen Acceptor ◽  
Water As Solvent ◽  
Lactone Synthesis

Ruthenium-catalyzed formation of lactones from diols in aqueous medium has been demonstrated. 1,3,5-Triazaphosphaadamantane (PTA) included water-soluble ruthenium complexes [RuCl2(PPh3)(2,6-Py-(CH2-PTA)2]·2Br and [RuCl2(PPh3)2(2-PyCH2PTA)]·Br in the presence of KOH were found to be efficient for the synthesis of lactones from diols. The reported synthetic protocol is green as it uses water as solvent, avoids the use of any hydrogen acceptor/oxidant, and produces hydrogen as the only side product. Mechanistic studies revealed that lactone formation involved aldehyde intermediate and followed dehydrogenative pathway.

Kinetic studies on 2,6-lutidine catalyzed peroxyoxalate chemiluminescence in organic and aqueous medium: Evidence for general base catalysis

2019 ◽  
Vol 382 ◽  
pp. 111967 ◽  
Author(s):  
Felipe A. Augusto ◽  
Fernando H. Bartoloni ◽  
Maidileyvis C. Cabello ◽  
Ana Paula F. dos Santos ◽  
Wilhelm J. Baader
Keyword(s):  
Aqueous Medium ◽  
Kinetic Studies ◽  
Base Catalysis ◽  
Peroxyoxalate Chemiluminescence ◽  
General Base

Kinetic and mechanistic studies of oxidation of amine-N-polycarboxylates complexes of cobalt(II) by periodate ions in aqueous medium

2007 ◽  
Vol 4 (1) ◽  
pp. 63-71 ◽  
Author(s):  
R. M. Naik ◽  
A. Srivastava ◽  
A. K. Tiwari ◽  
S. B. S. Yadav ◽  
A. K. Verma
Keyword(s):  
Aqueous Medium ◽  
Mechanistic Studies

Retracted Article: Kinetic and mechanistic studies on adsorption of Cu(ii) in aqueous medium onto montmorillonite K10 and its modified derivative

2017 ◽  
Vol 41 (22) ◽  
pp. 13533-13552 ◽  
Author(s):  
Himani Medhi ◽  
Krishna G. Bhattacharyya
Keyword(s):  
Thermal Stability ◽  
Aqueous Medium ◽  
Adsorption Capacity ◽  
Surface Area ◽  
Basal Spacing ◽  
Mechanistic Studies ◽  
Surface Functionality ◽  
Montmorillonite K10 ◽  
Monolayer Adsorption ◽  
Retracted Article

Intercalation of montmorillonite by tetramethylammonium cations significantly increases the basal spacing, surface functionality, surface area, and thermal stability, leading to a significant enhancement in Cu(ii) Langmuir monolayer adsorption capacity (925.93 mg g−1).

scholarly journals Kinetic and Mechanistic Studies on the Reaction of DL-Methionine with in Aqueous Medium at Physiological pH

2009 ◽  
Vol 2009 ◽  
pp. 1-5 ◽  
Author(s):  
Tandra Das ◽  
A. K. Datta ◽  
A. K. Ghosh
Keyword(s):  
Temperature Dependence ◽  
Aqueous Medium ◽  
Equilibrium Constant ◽  
Thermodynamic Parameters ◽  
Activation Parameters ◽  
Outer Sphere ◽  
Ligand Concentration ◽  
Mechanistic Studies ◽  
Association Equilibrium

The reaction has been studied spectrophotometrically; the reaction shows two steps, both of which are dependent on ligand concentration and show a limiting nature. An associative interchange mechanism is proposed. Kinetic and activation parameters ( and ) and (, , , and ) have been calculated. From the temperature dependence of the outer sphere association equilibrium constant, thermodynamic parameters ( and ; and ) have also been calculated.

scholarly journals Retraction: Kinetic and mechanistic studies on adsorption of Cu(ii) in aqueous medium onto montmorillonite K10 and its modified derivative

2020 ◽  
Vol 44 (16) ◽  
pp. 6667-6667
Author(s):  
Andrew Shore
Keyword(s):  
Aqueous Medium ◽  
Mechanistic Studies ◽  
Montmorillonite K10

Retraction of ‘Kinetic and mechanistic studies on adsorption of Cu(ii) in aqueous medium onto montmorillonite K10 and its modified derivative’ by Himani Medhi and Krishna G. Bhattacharyya, New J. Chem., 2017, 41, 13533–13552.

Sign in / Sign up

Export Citation Format

Share Document