Tuning Photoinduced Electron Transfer Efficiency of Fluorogenic BODIPY-α -Tocopherol Analogues

2018 ◽  
Vol 95 (1) ◽  
pp. 192-201 ◽  
Author(s):  
Lana E. Greene ◽  
Richard Lincoln ◽  
Gonzalo Cosa
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Transfer Efficiency

scholarly journals Влияние фотоиндуцированных процессов на поверхности квантовых точек на эффективность переноса электрона в структурах "Наночастицы TiO-=SUB=-2-=/SUB=-/Квантовые Точки"

2019 ◽  
Vol 127 (9) ◽  
pp. 490
Author(s):  
Е.П. Колесова ◽  
Ф.М. Сафин ◽  
В.Г. Маслов ◽  
Ю.К. Гунько ◽  
А.О. Орлова
Keyword(s):  
Quantum Dots ◽  
Electron Transfer ◽  
Tio2 Nanoparticles ◽  
Photoinduced Electron Transfer ◽  
Transfer Efficiency ◽  
Hybrid Structures ◽  
Threefold Increase ◽  
Nonradiative Processes ◽  
Photoinduced Processes

The effect of photoinduced processes on the CdSe/ZnS quantum dots surface on the functionality of TiO2 nanoparticles/quantum dots hybrid structures has been studied. We demonstrate that pre-irradiation of QDs layers allows for a threefold increase in the photoinduced electron transfer efficiency in the structures. It was shown that photoinduced processes affect both the efficiency of nonradiative processes in QDs and electron transfer conditions in hybrid structures.

scholarly journals Modulate Photoinduced Electron Transfer Efficiency of Bipolar Dendritic Systems

2008 ◽  
Vol 10 (15) ◽  
pp. 3211-3214 ◽  
Author(s):  
Yu-Hsien Lin ◽  
Hsu-Hsuan Wu ◽  
Ken-Tsung Wong ◽  
Cheng-Chih Hsieh ◽  
Yi-Chih Lin ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Transfer Efficiency

Photoinduced Electron Transfer between C60-Pendant Calixarene and Captured Electron Donor:  Improvement of Electron-Transfer Efficiency by Applying Host−Guest Chemistry

2002 ◽  
Vol 106 (43) ◽  
pp. 10254-10260 ◽  
Author(s):  
Toshifumi Konishi ◽  
Atsushi Ikeda ◽  
Takanori Kishida ◽  
Brian Schou Rasmussen ◽  
Mamoru Fujitsuka ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electron Donor ◽  
Photoinduced Electron Transfer ◽  
Transfer Efficiency ◽  
Guest Chemistry

scholarly journals Enhancing Photoinduced Electron Transfer Efficiency of Fluorescent pH-Probes with Halogenated Phenols

2014 ◽  
Vol 86 (18) ◽  
pp. 9293-9300 ◽  
Author(s):  
Daniel Aigner ◽  
Stefan A. Freunberger ◽  
Martin Wilkening ◽  
Robert Saf ◽  
Sergey M. Borisov ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Transfer Efficiency ◽  
Halogenated Phenols ◽  
Ph Probes

scholarly journals Методика оценки функциональности многослойных гибридных структур TiO-=SUB=-2-=/SUB=-/квантовая точка по генерации активных форм кислорода

2019 ◽  
Vol 127 (8) ◽  
pp. 325
Author(s):  
Е.П. Колесова ◽  
В.Г. Маслов ◽  
Ю.К. Гунько ◽  
А.О. Орлова
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Transfer Efficiency ◽  
Hybrid Structures ◽  
Ros Generation ◽  
New Approach

A new approach for estimation of photoinduced electron transfer efficiency from CdSe/ZnS QDs to Titania NPs using ROS generation has been introduced. The 26% efficiency electron transfer has been realized in the prepared Titania NPs/QDs multilayered hybrid structures.

Computationally Assisted Design of High Signal-to-Noise Photoinduced Electron Transfer-Based Voltage-Sensitive Dyes

2020 ◽  
Author(s):  
Rishikesh Kulkarni ◽  
Anneliese Gest ◽  
Chun Kei Lam ◽  
Benjamin Raliski ◽  
Feroz James ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Dft Calculations ◽  
Photoinduced Electron Transfer ◽  
Density Functional ◽  
Embryonic Stem ◽  
High Sensitivity ◽  
Md Simulations ◽  
High Signal ◽  
Signal To Noise ◽  
Green Fluorescent

<p>High signal-to-noise optical voltage indicators will enable simultaneous interrogation of membrane potential in large ensembles of neurons. However, design principles for voltage sensors with high sensitivity and brightness remain elusive, limiting the applicability of voltage imaging. In this paper, we use molecular dynamics (MD) simulations and density functional theory (DFT) calculations to guide the design of a bright and sensitive green-fluorescent voltage-sensitive fluorophore, or VoltageFluor (VF dye), that uses photoinduced electron transfer (PeT) as a voltage-sensing mechanism. MD simulations predict an 11% increase in sensitivity due to membrane orientation, while DFT calculations predict an increase in fluorescence quantum yield, but a decrease in sensitivity due to a decrease in rate of PeT. We confirm these predictions by synthesizing a new VF dye and demonstrating that it displays the expected improvements by doubling the brightness and retaining similar sensitivity to prior VF dyes. Combining theoretical predictions and experimental validation has resulted in the synthesis of the highest signal-to-noise green VF dye to date. We use this new voltage indicator to monitor the electrophysiological maturation of human embryonic stem cell-derived medium spiny neurons. </p>

Photoinduced electron transfer in mechanically interlocked suit[3]ane systems

2021 ◽  
Author(s):  
Anton J Stasyuk ◽  
Olga A. Stasyuk ◽  
Miquel Solà ◽  
Alexander Voityuk
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
New Class ◽  
Transfer Processes ◽  
Two Component ◽  
Electron Transfer Processes

Suitanes, a new class of two-component mechanically interlocked systems, have recently been developed. In this work, we report a detailed study of photoinduced electron transfer processes in the suit[3]anes consisting...

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