scholarly journals Cryptic metasomatic agent measured in situ in Variscan mantle rocks: Melt inclusions in garnet of eclogite, Granulitgebirge, Germany

2020 ◽  
Vol 38 (3) ◽  
pp. 207-234 ◽  
Author(s):  
Alessia Borghini ◽  
Silvio Ferrero ◽  
Patrick J. O’Brien ◽  
Oscar Laurent ◽  
Christina Günter ◽  
...  
Keyword(s):  
Melt Inclusions ◽  
Metasomatic Agent

The chlorine-isotopic composition of lunar KREEP from magnesian-suite troctolite 76535

2020 ◽  
Vol 105 (8) ◽  
pp. 1270-1274
Author(s):  
Francis M. McCubbin ◽  
Jessica J. Barnes
Keyword(s):  
Isotopic Composition ◽  
Melt Inclusions ◽  
Melt Inclusion ◽  
Isotopic Fractionation ◽  
Magma Ocean ◽  
Geochemical Composition ◽  
Isotopic Compositions ◽  
Stable Isotopic ◽  
Lunar Samples

Abstract We conducted in situ Cl isotopic measurements of apatite within intercumulus regions and within a holocrystalline olivine-hosted melt inclusion in magnesian-suite troctolite 76535 from Apollo 17. These data were collected to place constraints on the Cl-isotopic composition of the last liquid to crystallize from the lunar magma ocean (i.e., urKREEP, named after its enrichments in incompatible lithophile trace elements like potassium, rare earth elements, and phosphorus). The apatite in the olivine-hosted melt inclusion and within the intercumulus regions of the sample yielded Cl-isotopic compositions of 28.3 ± 0.9‰ (2σ) and 30.3 ± 1.1‰ (2σ), respectively. The concordance of these values from both textural regimes we analyzed indicates that the Cl-isotopic composition of apatites in 76535 likely represents the Cl-isotopic composition of the KREEP-rich magnesian-suite magmas. Based on the age of 76535, these results imply that the KREEP reservoir attained a Cl-isotopic composition of 28–30‰ by at least 4.31 Ga, consistent with the onset of Cl-isotopic fractionation at the time of lunar magma ocean crystallization or shortly thereafter. Moreover, lunar samples that yield Cl-isotopic compositions higher than the value for KREEP are likely affected by secondary processes such as impacts and/or magmatic degassing. The presence of KREEP-rich olivine-hosted melt inclusions within one of the most pristine and ancient KREEP-rich rocks from the Moon provides a new opportunity to characterize the geochemistry of KREEP. In particular, a broader analysis of stable isotopic compositions of highly and moderately volatile elements could provide an unprecedented advancement in our characterization of the geochemical composition of the KREEP reservoir and of volatile-depletion processes during magma ocean crystallization, more broadly.

scholarly journals Hydrogen Isotopic Variations in the Shergottites

Geosciences ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 148 ◽  
Author(s):  
Shuai Wang ◽  
Sen Hu
Keyword(s):  
Melt Inclusions ◽  
Crustal Rock ◽  
Evidence Based ◽  
Mantle Rock ◽  
Future Studies ◽  
Groundmass Glass ◽  
Impact Melt ◽  
Melt Glass ◽  
Isotopic Variations

Hydrogen isotopes in the shergottite Martian meteorites are among the most varied in Mars laboratory samples. By collating results of previous studies on major hydroxyl, deuterium, and H2O bearing phases, we provide a compendium of recent measurements in order to elucidate crustal-rock versus mantle-rock processes on Mars. We summarize recent works on volatile and δD measurements in a range of shergottite phases: from melt inclusions, apatite, merrillite, maskelynite, impact melt glass, groundmass glass, and nominal anhydrous minerals. We interpret these observations using an evidence-based approach, considering two particular scenarios: (1) water-rock crustal interactions versus (2) magmatic-based processes. We consider the implications of these measurements and the scope they have for future studies, paying particular attention to future works on H, S, and Cl isotopes in situ, shedding light on the nature of volatiles in the hydrosphere and lithosphere of Mars.

Glass-bearing felsic nodules from the crystallizing sidewalls of the 1944 Vesuvius magma chamber

2000 ◽  
Vol 64 (3) ◽  
pp. 481-496 ◽  
Author(s):  
P. Fulignati ◽  
P. Marianelli ◽  
A. Sbrana
Keyword(s):  
Magma Chamber ◽  
Melt Inclusions ◽  
Mineral Chemistry ◽  
Glassy Matrix ◽  
Crystal Mush ◽  
Stratigraphic Sequence ◽  
Shallow Magma Chamber ◽  
Mineral Assemblages ◽  
Pressure Crystallization

AbstractIn the 1944 Vesuvius eruption, the shallow magma chamber was disrupted during the highly energetic explosive phases. Abundant cognate xenoliths such as subvolcanic fergusites and cumulates, hornfels, skarns and rare marbles occur in tephra deposits.Mineral chemistry, melt inclusions in minerals and glassy matrix compositions show that fergusites (highly crystalline rocks made of leucite, clinopyroxene, plagioclase, olivine, apatite, oxides and glass) do not correspond to melt compositions but result from combined sidewall accumulation of crystals, formed from K-tephriphonolitic magma resident in the chamber, and in situ crystallization of the intercumulus melt. Very low H2O contents in the intercumulus glass are revealed by FTIR and apatite composition. Whole rock compositions are essentially determined by the bulk mineral assemblages.Glass–bearing fergusites constitute the outer shell of the magma chamber consisting of a highly viscous crystal mush with a melt content in the range 20–50 wt.%. The leucite/(clinopyroxene+olivine) modal ratio, varies with the extraction order of magmas from the chamber, decreasing upwards in the stratigraphic sequence. This reflects a vertical mineralogical zonation of the crystal mush. These data contribute to the interpretation of the subvolcanic low–pressure crystallization processes at the magma chamber sidewalls affecting alkaline potassic magmas.

High-precision in situ analysis of Pb isotopes in melt inclusions by LA-ICP-MS and application of Independent Component Analysis

2018 ◽  
Vol 52 (1) ◽  
pp. 69-74 ◽  
Author(s):  
Morihisa Hamada ◽  
Jun-Ichi Kimura ◽  
Qing Chang ◽  
Takeshi Hanyu ◽  
Takayuki Ushikubo ◽  
...  
Keyword(s):  
Independent Component Analysis ◽  
High Precision ◽  
Melt Inclusions ◽  
Component Analysis ◽  
Independent Component ◽  
Pb Isotopes ◽  
Icp Ms
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