Muscovite dehydration melting: Reaction mechanisms, microstructures, and implications for anatexis

2019 ◽  
Vol 38 (1) ◽  
pp. 29-52 ◽  
Author(s):  
Brendan Dyck ◽  
David J. Waters ◽  
Marc R. St‐Onge ◽  
Mike P. Searle
Keyword(s):  
Reaction Mechanisms ◽  
Dehydration Melting ◽  
Melting Reaction

Partial melting of metapelites in the Gagnon terrane below the high-pressure belt in the Manicouagan area (Grenville Province): pressure–temperature (P–T) and U–Pb age constraints and implications

2006 ◽  
Vol 43 (9) ◽  
pp. 1309-1329 ◽  
Author(s):  
Sherri L Jordan ◽  
Aphrodite Indares ◽  
Greg Dunning
Keyword(s):  
High Pressure ◽  
Partial Melting ◽  
Metamorphic Event ◽  
Dehydration Melting ◽  
Melting Reaction ◽  
Grenville Province ◽  
Thermal Event ◽  
Zircon Crystallization ◽  
Age Constraints ◽  
Comparable Intensity

Metapelites of the parautochthonous Gagnon terrane at the footwall of the high-pressure (high-P) belt in the Manicouagan area (central Grenville Province) preserve an impressive textural record of partial melting reactions, mainly in polymineralic inclusions within garnet. The dominant textures were developed within the pressure–temperature (P–T) field of the continuous dehydration melting reaction biotite + kyanite (or sillimanite) + plagioclase + quartz = garnet + K-feldspar + melt, with sillimanite instead of kyanite in the southern part of the footwall. Inferred P–T paths have a hair-pin form in the range of 750–850 °C and 1000–1500 MPa for the kyanite-bearing rocks. Monazite crystallization ages are consistently late Grenvillian, either 995 or 985 Ma, and one sample contains monazite of both ages. Two of these samples also contain inherited monazite with ages of 1738 ± 5 and 1719 ± 30 Ma, indicative of an earlier metamorphic event. Tonalite and diorite from the same area yield Archean zircon crystallization ages and titanite ages of 961 ± 3 and 956 ± 4 Ma, the youngest in the Manicouagan region. The late Grenvillian metamorphism was of comparable intensity but ~50 Ma younger than in the overlying high-P belt in this area and therefore seems to be unrelated to the emplacement of the latter over the Parautochthonous Belt, as previously suggested. Rather, this younger metamorphism suggests a reactivation of the footwall by underthrusting of the Gagnon terrane during the waning stages of convergence, and a link with a major coeval post-tectonic thermal event farther south in the hinterland.

Analyzing reactions of single mechanoenzyme molecules by light microscopy

1992 ◽  
Vol 50 (1) ◽  
pp. 426-427
Author(s):  
Jeff Gelles
Keyword(s):  
Image Processing ◽  
Reaction Mechanisms ◽  
Transient State ◽  
Nanometer Scale ◽  
Reaction Intermediates ◽  
Enzyme Molecule ◽  
Directed Movement ◽  
Enzyme Molecules ◽  
Individual Enzyme ◽  
Single Reaction

Mechanoenzymes are enzymes which use a chemical reaction to power directed movement along biological polymer. Such enzymes include the cytoskeletal motors (e.g., myosins, dyneins, and kinesins) as well as nucleic acid polymerases and helicases. A single catalytic turnover of a mechanoenzyme moves the enzyme molecule along the polymer a distance on the order of 10−9 m We have developed light microscope and digital image processing methods to detect and measure nanometer-scale motions driven by single mechanoenzyme molecules. These techniques enable one to monitor the occurrence of single reaction steps and to measure the lifetimes of reaction intermediates in individual enzyme molecules. This information can be used to elucidate reaction mechanisms and determine microscopic rate constants. Such an approach circumvents difficulties encountered in the use of traditional transient-state kinetics techniques to examine mechanoenzyme reaction mechanisms.

X-Ray Microanalysis of Nickel and Cobalt Intensified Peroxidase- Antiperoxidase For Verification of Reaction Sites

1985 ◽  
Vol 43 ◽  
pp. 468-469
Author(s):  
A. Angel ◽  
K. Miller ◽  
V. Seybold ◽  
R. Kriebel
Keyword(s):  
Reaction Mechanisms ◽  
Visual Discrimination ◽  
Osmium Tetroxide ◽  
Ultrastructural Level ◽  
Microscopic Level ◽  
Electron Microscopic Level ◽  
Electron Microscopic ◽  
X Ray ◽  
Insoluble Polymer ◽  
Cytochemical Reaction

Localization of specific substances at the ultrastructural level is dependent on the introduction of chemicals which will complex and impart an electron density at specific reaction sites. Peroxidase-antiperoxidase(PAP) methods have been successfully applied at the electron microscopic level. The PAP complex is localized by addition of its substrate, hydrogen peroxide and an electron donor, usually diaminobenzidine(DAB). On oxidation, DAB forms an insoluble polymer which is able to chelate with osmium tetroxide becoming electron dense. Since verification of reactivity is visual, discrimination of reaction product from osmiophillic structures may be difficult. Recently, x-ray microanalysis has been applied to examine cytochemical reaction precipitates, their distribution in tissues, and to study cytochemical reaction mechanisms. For example, immunoreactive sites labelled with gold have been ascertained by means of x-ray microanalysis.

A Paramedic Treatment for Modeling Explicitly Solvated Chemical Reaction Mechanisms

2018 ◽  
Author(s):  
Yasemin Basdogan ◽  
John Keith
Keyword(s):  
Reaction Mechanism ◽  
Chemical Reaction ◽  
Reaction Mechanisms ◽  
Reaction Pathway ◽  
Optimization Procedure ◽  
Cost Effective ◽  
Chemical Reaction Mechanisms ◽  
Solvent Molecules ◽  
Dynamics Simulations ◽  
Mbh Reaction

<div> <div> <div> <p>We report a static quantum chemistry modeling treatment to study how solvent molecules affect chemical reaction mechanisms without dynamics simulations. This modeling scheme uses a global optimization procedure to identify low energy intermediate states with different numbers of explicit solvent molecules and then the growing string method to locate sequential transition states along a reaction pathway. Testing this approach on the acid-catalyzed Morita-Baylis-Hillman (MBH) reaction in methanol, we found a reaction mechanism that is consistent with both recent experiments and computationally intensive dynamics simulations with explicit solvation. In doing so, we explain unphysical pitfalls that obfuscate computational modeling that uses microsolvated reaction intermediates. This new paramedic approach can promisingly capture essential physical chemistry of the complicated and multistep MBH reaction mechanism, and the energy profiles found with this model appear reasonably insensitive to the level of theory used for energy calculations. Thus, it should be a useful and computationally cost-effective approach for modeling solvent mediated reaction mechanisms when dynamics simulations are not possible. </p> </div> </div> </div>

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