Mechanical properties of illite‐based ceramics with controlled porosity studied by modern in situ techniques

2019 ◽  
Vol 103 (4) ◽  
pp. 2780-2790
Author(s):  
Michal Knapek ◽  
Jakub Kušnír ◽  
Tomáš Húlan ◽  
Peter Minárik ◽  
Štefan Csáki ◽  
...  
1998 ◽  
Vol 520 ◽  
Author(s):  
Q. Deng ◽  
G. T. Bums ◽  
J. R. Hahn ◽  
C. C. Reese ◽  
J. D. Preston ◽  
...  

ABSTRACTTreated silica xerogels with controlled porosity and surface area were prepared by the in-situ treatment of hydrogels with hexamethyldisiloxane in the presence of isopropyl alcohol. The resulting hydrogels were hydrophobic and readily transferred to organic solvents allowing their isolation. The surface area and porosity of the xerogel were controlled by varying the pH, time and temperature used to aggregate the hydrogel prior to treatment. The treated xerogels were evaluated as reinforcing fillers in silicone rubber formulations. When the bases were crosslinked with peroxides, silicone elastomers with acceptable mechanical properties were obtained. The relationship between the surface area, porosity and the type and degree of surface treatment of the xerogel, and its reinforcing ability was studied. In general, the mechanical properties of the elastomer increased as the filler structure increased; however, xerogels with higher surface areas were more difficult to incorporate and gave higher plasticity bases.


2010 ◽  
Vol 105-106 ◽  
pp. 126-129 ◽  
Author(s):  
Jun Ping Yao ◽  
Sun Zhong ◽  
Lei Zhang ◽  
Huo Ping Zhao

Al–Si alloy-based composites are widely used in automotive, aerospace and mineral processing industries with improved properties. In situ techniques have been developed to fabricate Al–Si alloy-based composites, which can lead to better adhesion at the interface and hence better mechanical properties. Al–Si alloy reinforced with in situ TiB2 particles was synthesized successfully by using salt reaction route. These in situ composites have shown significant improvement in mechanical properties compared with the base alloy. The wear resistance of the alloy is also significantly improved with the addition of TiB2 particles. The hardness, strength and wear resistance are strengthened with increasing TiB2 content of the composites. TiB2 can act not only as a grain refiner for primary Al but also as a modifier of Si in eutectic mixture. Analysis of the worn surface of Al–Si/TiB2 composites tested under loads of 30 and 110N suggests that ploughing is predominant at lower loads and delamination is predominant at higher loads.


2003 ◽  
Vol 778 ◽  
Author(s):  
Rajdip Bandyopadhyaya ◽  
Weizhi Rong ◽  
Yong J. Suh ◽  
Sheldon K. Friedlander

AbstractCarbon black in the form of nanoparticle chains is used as a reinforcing filler in elastomers. However, the dynamics of the filler particles under tension and their role in the improvement of the mechanical properties of rubber are not well understood. We have studied experimentally the dynamics of isolated nanoparticle chain aggregates (NCAs) of carbon made by laser ablation, and also that of carbon black embedded in a polymer film. In situ studies of stretching and contraction of such chains in the transmission electron microscope (TEM) were conducted under different maximum values of strain. Stretching causes initially folded NCA to reorganize into a straight, taut configuration. Further stretching leads to either plastic deformation and breakage (at 37.4% strain) or to a partial elastic behavior of the chain at small strains (e.g. 2.3% strain). For all cases the chains were very flexible under tension. Similar reorientation and stretching was observed for carbon black chains embedded in a polymer film. Such flexible and elastic nature of NCAs point towards a possible mechanism of reinforcement of rubber by carbon black fillers.


2018 ◽  
Vol 60 (12) ◽  
pp. 1221-1224 ◽  
Author(s):  
Balachandran Gobalakrishnan ◽  
P. Ramadoss Lakshminarayanan ◽  
Raju Varahamoorthi

Author(s):  
Pratik Chhapia ◽  
Harshad Patel

: Graphene based co-polymeric Nano-composites explored and trending in various applications as ascribing to its enhanced conductivity and controlled modification with wide specific surface areas. With the number of advantages of co-polymeric coating on Graphene or Graphene sheets and their derivatives, Graphene based co-polymeric Nano-composites fabricated by various techniques (deposition, ink jet, electro spinning, spin coating, in-situ techniques, etc.) and different conducting co-polymers show its exceptional chemical, mechanical, electrical and optical properties. Therefore, in the today’s world with greater quantities of various properties of co-polymer with Graphene based Nano-composites with enhanced stability, selectivity and sensitivity have been formed. In this review paper, we have particularly focused on recent advancing in fabrication of different technologies with the help of Graphene based co-polymeric Nano-composites and its various trending and future applications. Finally, on the personal standpoint; the key challenges of Graphene based co-polymeric Nano-composites are mentioned in hope to shed a light on their potential future prospects.


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