Grain size effect and microstructure influence on the energy storage properties of fine-grained BaTiO3 -based ceramics

2017 ◽  
Vol 100 (8) ◽  
pp. 3599-3607 ◽  
Author(s):  
Baibo Liu ◽  
Xiaohui Wang ◽  
Ruoxi Zhang ◽  
Longtu Li
2018 ◽  
Vol 08 (06) ◽  
pp. 1830006 ◽  
Author(s):  
Xiaoshuang Qiao ◽  
Xiaoshuai Zhang ◽  
Di Wu ◽  
Xiaolian Chao ◽  
Zupei Yang

Ceramic-based dielectric capacitors are becoming more and more important in electronic devices. The ceramics of 0.93K[Formula: see text]Na[Formula: see text]NbO3–0.07Bix(Mg[Formula: see text]Nb[Formula: see text])O3 (0.93KNN–0.07BixMN) ([Formula: see text], 2/3, 0.75 and 0.95) were successfully fabricated by virtue of the solid reaction process in this work. The results showed that the amount of Bi content has a significant impact on the ceramics of 0.93KNN–0.07BixMN. XRD indicates that all specimens exhibit a pure perovskite structure and existing oxygen vacancy in the specimens. The mean grain size for all specimens belong to submicron scale, and the sample of [Formula: see text] owns the smallest grain size is 0.11[Formula: see text][Formula: see text]m. The maximum dielectric constant increases but the phase transition temperature [Formula: see text] exhibits a contrary tendency at 1[Formula: see text]MHz with increasing Bi concentration. Besides, all ceramics are relaxor ferroelectric. The impedance analysis further revealed that the activation energy of the ceramics increases with Bi content. Eventually, the highest [Formula: see text] of 58.8% and [Formula: see text] of 1.30[Formula: see text]J/cm3 are simultaneously achieved in the sample with [Formula: see text]. Overall, we demonstrate in this work that stoichiometry control of Bi in 0.93KNN–0.07BixMN ceramics is a practical method to obtain the desired structural, dielectric and energy storage properties.


2020 ◽  
Vol 40 (13) ◽  
pp. 4495-4502 ◽  
Author(s):  
Pengrong Ren ◽  
Dong Ren ◽  
Liang Sun ◽  
Fuxue Yan ◽  
Shu Yang ◽  
...  

2014 ◽  
Vol 34 (5) ◽  
pp. 1209-1217 ◽  
Author(s):  
Zhe Song ◽  
Hanxing Liu ◽  
Shujun Zhang ◽  
Zhijian Wang ◽  
Yatong Shi ◽  
...  

1986 ◽  
Vol 6 (4) ◽  
pp. 231-263 ◽  
Author(s):  
T. Leffers ◽  
D. Juul Jensen

We describe a computer procedure which allows us to introduce experimental initial textures as starting conditions for texture simulation (instead of a theoretical random texture). We apply the procedure on two batches of copper with weak initial textures and on fine-grained and coarse-grained aluminium with moderately strong initial textures. In copper the initial texture turns out to be too weak to have any significant effect. In aluminium the initial texture has a very significant effect on the simulated textures—similar to the effect it has on the experimental textures. However, there are differences between the simulated and the experimental aluminium textures that can only be explained as a grain-size effect. Possible future applications of the procedure are discussed.


2021 ◽  
pp. 133584
Author(s):  
Yangfei Gao ◽  
Xiaopei Zhu ◽  
Bian Yang ◽  
Peng Shi ◽  
Ruirui Kang ◽  
...  

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