La1.7Ca0.3Ni0.75Cu0.25O4-δ-Layered Perovskite as Cathode on La0.9Sr0.1Ga0.8Mg0.2O3or Ce0.8Gd0.2O2Electrolyte for Intermediate Temperature Solid Oxide Fuel Cells

2016 ◽  
Vol 13 (2) ◽  
pp. 269-273 ◽  
Author(s):  
Jae-ha Myung ◽  
Tae Ho Shin ◽  
Xiubing Huang ◽  
Cristian Savaniu ◽  
John Irvine
2012 ◽  
Vol 14 (1) ◽  
pp. 75-77 ◽  
Author(s):  
Chao Jin ◽  
Zhibin Yang ◽  
Honghe Zheng ◽  
Chenghao Yang ◽  
Fanglin Chen

2015 ◽  
Vol 3 (11) ◽  
pp. 6088-6095 ◽  
Author(s):  
Sihyuk Choi ◽  
Seonhye Park ◽  
Jeeyoung Shin ◽  
Guntae Kim

The partial replacement of Sr by Ca in PrBa0.5Sr0.5Co2O5+δ layered perovskite provides a breakthrough for achieving reliable operation of high performance IT-SOFCs.


2018 ◽  
Vol 215 ◽  
pp. 01026
Author(s):  
Adi Subardi ◽  
Yen-Pei Fu

SmBaCo2O5+δ (SBC) was studied as cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFCs). The crystal structure, thermal expansion behavior, and electrochemical performance with long-term operation of SBC were characterized. An orthorhombic layered perovskite structure was observed in SBC cathode by a GSAS program for refinement. The average thermal expansion coefficient (TEC) is 21.6 x 10-6K-1 in the temperature range of 100oC-800oC. For long-term testing, the polarization resistance of SBC cathode increases gradually from 25.77 Ω cm2 for 2 h to 38.77 Ω cm2 for 96 h at 600°C, and an increasing-rate for polarization resistance is around 13,8% h-1. Based on the electrochemical properties, SBC cathode with mixed ionic and electronic conductor (MIEC) behavior is a potential cathode for intermediate temperature solid oxide fuel cells based on a SDC electrolyte.


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