Chemical and Mineralogical Mapping of Platinum‐Group Element Ore Samples Using Laser‐Induced Breakdown Spectroscopy and Micro‐XRF

Author(s):  
Nessrine Mohamed ◽  
Kheireddine Rifai ◽  
Samira Selmani ◽  
Marc Constantin ◽  
François R. Doucet ◽  
...  
Minerals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 918
Author(s):  
Kheireddine Rifai ◽  
Marie-Chloé Michaud Paradis ◽  
Zofia Swierczek ◽  
François Doucet ◽  
Lütfü Özcan ◽  
...  

Geochemical and mineralogical characterization studies play an important role in the definition of mineral deposits. Each mineral system has a unique set of minerals with different chemical makeup and physical properties. Platinum-group elements (PGEs), for example, are scarce resources with many applications. The optimization of extraction process efficiency is therefore crucial to prevent resource shortage and increased bulk prices. To improve the mineral liberation process, high throughput sensors must be added alongside the production line as part of fast process analysis implementation. Current analytical methods are either ineffective to assess PGE content, or unusable in the conditions of the processing facilities. This article shows how Laser-induced breakdown spectroscopy (LIBS) technology, developed by ELEMISSION Inc, can circumvent these drawbacks by enabling automated, ultra-fast, and precise quantitative mineral analyses in any working environment. The drill core samples that were used in this study were collected at the Stillwater platinum group element mine in the United States. The data used for the mineralogical database was validated using the TESCAN Integrated Mineral Analyzer (TIMA) instrument.


2020 ◽  
Vol 92 (2) ◽  
pp. 20701
Author(s):  
Bo Li ◽  
Xiaofeng Li ◽  
Zhifeng Zhu ◽  
Qiang Gao

Laser-induced breakdown spectroscopy (LIBS) is a powerful technique for quantitative diagnostics of gases. The spatial resolution of LIBS, however, is limited by the volume of plasma. Here femtosecond-nanosecond dual-pulsed LIBS was demonstrated. Using this method, the breakdown threshold was reduced by 80%, and decay of continuous radiation was shortened. In addition, the volume of the plasma was shrunk by 85% and hence, the spatial resolution of LIBS was significantly improved.


2020 ◽  
Vol 1 (2) ◽  
pp. 5-8
Author(s):  
Komang Gde Suastika, Heri Suyanto, Gunarjo, Sadiana, Darmaji

Abstract - Laser-Induced Breakdown Spectroscopy (LIBS) is one method of atomic emission spectroscopy using laser ablation as an energy source. This method is used to characterize the type of amethysts that originally come from Sukamara, Central Kalimantan. The result of amethyst characterization can be used as a reference for claiming the natural wealth of the amethyst. The amethyst samples are directly taken from the amethyst mining field in the District Gem Amethyst and consist of four color variations: white, black, yellow, and purple. These samples were analyzed by LIBS, using laser energy of 120 mJ, delay time detection of 2 μs and accumulation of 3, with and without cleaning. The purpose of this study is to determine emission spectra characteristics, contained elements, and physical characteristics of each amethyst sample. The spectra show that the amethyst samples contain some elements such as Al, Ca, K, Fe, Gd, Ba, Si, Be, H, O, N, Cl and Pu with various emission intensities. The value of emission intensity corresponds to concentration of element in the sample. Hence, the characteristics of the amethysts are based on their concentration value. The element with the highest concentration in all samples is Si, which is related to the chemical formula of SiO2. The element with the lowest concentration in all samples is Ca that is found in black and yellow amethysts. The emission intensity of Fe element can distinguish between white, purple, and yellow amethyst. If Fe emission intensity is very low, it indicates yellow sample. Thus, we may conclude that LIBS is a method that can be used to characterize the amethyst samples.Key words: amethyst, impurity, laser-induced, breakdown spectroscopy, characteristic, gemstones


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