Fuel Efficiency of Ancient Copper Alloys: Theoretical Melting Thermodynamics of Copper, Tin and Arsenical Copper and Timber Conservation in the Bronze Age Levant*

Archaeometry ◽  
2014 ◽  
Vol 57 (6) ◽  
pp. 1009-1024 ◽  
Author(s):  
B. Kaufman ◽  
D. A. Scott
2021 ◽  
Vol 58 (10) ◽  
pp. 620-629
Author(s):  
R. Haubner ◽  
S. Strobl

Abstract Among other materials, fahlores were used in the Bronze Age copper ore smelting process. These contain, apart from sulfur, arsenic and antimony. Therefore, these elements can be found in Bronze Age copper casting ingots or artifacts. In order to study the behavior of Sb more closely, two copper alloys containing 10 and 30 wt. % Sb were melted and subjected to a metallographic examination. On the one hand, microstructures with copper dendrites and homogeneous interdendritic areas primarily composed of intermetallic phase could be found. On the other hand, at higher Sb concentrations, first Cu3Sb precipitated which, in turn, transformed to Cu10Sb3 upon cooling. The crystals in these microstructures were characterized by numerous parallel cracks. No further phases were observed by XRD.


1998 ◽  
Vol 93 ◽  
pp. 91-102 ◽  
Author(s):  
Helen Mangou ◽  
Panayiotis V. Ioannou

110 copper-based objects from various sites on Crete, covering the whole of the Bronze Age, were analysed for their chemical content (12 elements) by Atomic Absorption Spectrometry. The results indicate that during the Early Bronze Age arsenical copper was mainly used while in the Middle Bronze Age copper, arsenical copper, and arsenical bronze were in use with about equal frequency. During the Late Bronze Age normal bronze was used when required. The copper technology in each era was the same at all of the sites examined. Metallographic examination of four triangular daggers of the Early Bronze Age showed that they had been cast. In the case of three Late Bronze Age hydriae, the component sheets had been hammered and annealed.


Author(s):  
William O'Brien

Copper objects first circulated in Britain and Ireland around 2500 BC, thus beginning a short-lived Chalcolithic that ended with the rapid adoption of tin-bronze metallurgy after 2100 BC. Both islands have numerous sources of copper; however, these orebodies are not evenly distributed, nor were they all accessible to the prehistoric miner. This is part of the explanation why certain regions developed a strong tradition of copper mining that lasted well into the Bronze Age. Ireland has long been regarded as a significant producer of metal in the Bronze Age. This reflects the large quantities of Bronze Age metalwork found in a part of Europe with abundant sources of copper. The south-west region of Cork and Kerry was the main centre for early copper production. This began with mining at Ross Island in Killarney, where Beaker culture groups produced arsenical copper during the Chalcolithic and Early Bronze Age (c.2400–1900 BC). Farther south, there are seven copper mines now dated to the Early to Middle Bronze Age (c.1800–1400 BC) in the peninsulas of west Cork. These are known as Mount Gabriel-type mines, the name coming from the single largest concentration of such workings located on the eastern slopes of this mountain in the Mizen Peninsula (O’Brien 1994, 2003). The recent discovery of trench workings at Derrycarhoon continues the story of Bronze Age copper mining in that area to 1300–1100 BC, after which this activity seems to have ceased (O’Brien 2013). The study of these mines began during the late eighteenth/ early nineteenth centuries, when mineral prospecting led to the discovery of primitive workings at several locations in south-west Ireland. Described as ‘Dane’s Workings’ in the antiquarian literature, these mines were associated with the use of firesetting and stone hammers (see quotations from Griffith 1828 and Thomas 1850 (in O’Brien 2003) in Chapter 1). The first systematic research began in the 1930s with the discovery of the Mount Gabriel group by the geologist, Tom Duffy. These were subsequently mapped by another geologist, John Jackson, who brought these mines to wider attention when he obtained a Bronze Age date for charcoal taken from mine spoil on the mountain (Jackson 1968).


Archaeometry ◽  
2015 ◽  
Vol 58 (6) ◽  
pp. 1003-1023 ◽  
Author(s):  
P. Valério ◽  
A. M. M. Soares ◽  
M. F. Araújo ◽  
R. J. C. Silva ◽  
L. Baptista

1999 ◽  
Vol 94 ◽  
pp. 81-100 ◽  
Author(s):  
Helen Mangou ◽  
Panayiotis V. Ioannou

170 copper-based objects from various sites in mainland Greece covering the Late Neolithic period and the whole of the Bronze Age have been analysed for their chemical content (twelve elements) by atomic absorption spectroscopy. The results indicate that at all sites during the Late Neolithic and Early Bronze Age relatively pure copper and arsenical copper were used, while during the Middle and Late Bronze Ages bronze dominated. Bronze objects of the Early Bronze Age were probably imported. Lead was not usually used to help casting. Metallographic examination of eight Late Neolithic, Early and Late Bronze Age hammered objects revealed that they have been cold-worked and annealed, most probably through several cycles.


2016 ◽  
Vol 3 (2) ◽  
Author(s):  
Magdalena Natuniewicz-Sekuła ◽  
Dagmara H. Werra

In the Bronze Age flint was still being used throughout Europe. In the early periods of that age flint continued to play an important role in the economy in many areas, as evidenced by the numerous flint mines in use at the time as well as flint tools. In the Late Bronze and Early Iron Ages, flint still had an important place in the economies of communities living in East Central Europe. At the same time, analysis of late flint industries suggests that some of those had no utilitarian significance. The presence of flint, especially in inhumation graves from the cemetery at Weklice (used by communities of the Wielbark culture during the Roman Period) potentially adds to the debate about its significance. The cemetery at Weklice is the one of the best-known sites from the Roman Period in Poland. The graves are mostly equipped with local finds of metals: gold, silver, copper alloys, iron and amber as well as Roman imports (glass beads, vessels: glass, copper alloys). The collections comprise over of 4000 finds, however this number may change, as excavations in 2012 and 2013 revealed 22 flint artefacts. The presence of flint materials in a Roman Period cemetery admits several possible interpretations: 1) Those may be remnants of older settlements, with graves being dug into older strata and thus some of the specimens of flint could be in their secondary filling on the site; 2) Those may be remains of flint knapping activity by the Wielbark culture community; 3) Those may have been placed in the graves deliberately by the Wielbark culture community as an instance of an older custom involving the placing of flint in graves.


1998 ◽  
Vol 21 (1) ◽  
pp. 1-28
Author(s):  
John A Atkinson ◽  
Camilla Dickson ◽  
Jane Downes ◽  
Paul Robins ◽  
David Sanderson

Summary Two small burnt mounds were excavated as part of the programme to mitigate the impact of motorway construction in the Crawford area. The excavations followed a research strategy designed to address questions of date and function. This paper surveys the various competing theories about burnt mounds and how the archaeological evidence was evaluated against those theories. Both sites produced radiocarbon dates from the Bronze Age and evidence to suggest that they were cooking places. In addition, a short account is presented of two further burnt mounds discovered during the construction of the motorway in Annandale.


2003 ◽  
Vol 25 (2) ◽  
pp. 103-128
Author(s):  
Gavin Macgregor ◽  
Irene Cullen ◽  
Diane Alldritt ◽  
Michael Donnelly ◽  
Jennifer Miller ◽  
...  

Summary A programme of archaeological work was undertaken by Glasgow University Archaeological Research Division (GUARD) at West Flank Road, Drumchapel, in close proximity to the site of the prehistoric cemetery of Knappers. This paper considers the results of excavation of a range of negative features, including earlier Neolithic and Bronze Age pits and postholes. The earlier Neolithic features date to c. 3500–3000 BC and are interpreted as the partial remains of a subrectangular structure. The Bronze Age features may relate to ceremonial activities in the wider area. The significance of these remains is considered in relation to the site of Knappers and wider traditions during the fourth to second millennia BC.


2005 ◽  
Vol 27 (2) ◽  
pp. 193-195
Author(s):  
Brendan O'Connor
Keyword(s):  

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