Characterization of Hygroscopic Swelling Behavior of Mold Compounds and Plastic Packages

2004 ◽  
Vol 27 (3) ◽  
pp. 499-506 ◽  
Author(s):  
E. Stellrecht ◽  
B. Han ◽  
M.G. Pecht
2021 ◽  
pp. 009524432110061
Author(s):  
Bo Yang ◽  
Balakrishnan Nagarajan ◽  
Pierre Mertiny

Polymers may absorb fluids from their surroundings via the natural phenomenon of swelling. Dimensional changes due to swelling can affect the function of polymer components, such as in the case of seals, microfluidic components and electromechanical sensors. An understanding of the swelling behavior of polymers and means for controlling it can improve the design of polymer components, for example, for the previously mentioned applications. Carbon-based fillers have risen in popularity to be used for the property enhancement of resulting polymer composites. The present investigation focuses on the effects of three carbon-based nano-fillers (graphene nano-platelets, carbon black, and graphene nano-scrolls) on the dimensional changes of polydimethylsiloxane composites due to swelling when immersed in certain organic solvents. For this study, a facile and expedient methodology comprised of optical measurements in conjunction with digital image analysis was developed as the primary experimental technique to quantify swelling dimensional changes of the prepared composites. Other experimental techniques assessed polymer cross-linking densities and elastic mechanical properties of the various materials. The study revealed that the addition of certain carbon-based nano-fillers increased the overall swelling of the composites. The extent of swelling further depended on the organic solvent in which the composites were immersed in. Experimental findings are contrasted with published models for swelling prediction, and the role of filler morphology on swelling behavior is discussed.


Author(s):  
Ju-young Park ◽  
Sangho Ha ◽  
Eunju Park ◽  
Daeil Kwon ◽  
Namhun Kim

Selective laser sintering (SLS) printers have been used for rapid prototyping, and the prototypes of part assemblies have been reported to expand or shrink over time. This paper examines the hygroscopic swelling behavior of 3D printed parts from SLS printers. A total of 10 hexahedron samples were produced using nylon-12, which is a common material used for prototyping. Half of the samples were exposed to a high temperature to reduce the moisture content, and the rest were left at a room temperature. In the meantime, 13 dimensions of each sample were measured periodically along with the local weather records including relative humidity in order to track the hygroscopic swelling behavior of the samples. The results showed that the deformation was mostly occurred to the dimensions parallel to the sintering layers. Also, changes in these dimensions were found to have a high correlation with the relative humidity regardless of temperature conditions. These results imply that changes in environmental conditions such as relative humidity result in the deformation of 3D printed parts after production. The high correlation between dimension change and relative humidity also indicates the layup orientation is a decisive factor to predict the deformation of 3D printed parts. Thus, unexpected deformation of 3D printed parts can be avoided by optimizing the parts design considering the layup orientation and by controlling the environmental conditions.


Polymers ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 4402
Author(s):  
Klara Loos ◽  
Vivianne Marie Bruère ◽  
Benedikt Demmel ◽  
Yvonne Ilmberger ◽  
Alexander Lion ◽  
...  

The present study investigates different elastomers with regard to their behavior towards liquids such as moisture, fuels, or fuel components. First, four additively manufactured materials are examined in detail with respect to their swelling in the fuel component toluene as well as in water. The chemical nature of the materials is elucidated by means of infrared spectroscopy. The experimentally derived absorption curves of the materials in the liquids are described mathematically using Fick’s diffusion law. The mechanical behavior is determined by uniaxial tensile tests, which are evaluated on the basis of stress and strain at break. The results of the study allow for deriving valuable recommendations regarding the printing process and postprocessing. Second, this article investigates the swelling behavior of new as well as thermo-oxidatively aged elastomers in synthetic fuels. For this purpose, an analysis routine is presented using sorption experiments combined with gas chromatography and mass spectrometry and is thus capable of analyzing the swelling behavior multifacetted. The transition of elastomer constituents into the surrounding fuel at different aging and sorption times is determined precisely. The change in mechanical properties is quantified using density measurements, micro Shore A hardness measurements, and the parameters stress and strain at break from uniaxial tensile tests.


Sign in / Sign up

Export Citation Format

Share Document