Adsorptive Removal of Chemical Oxygen Demand and Color on Sewage Sludge Based Activated Carbon from Biologically Pretreated Coking Wastewater

Author(s):  
Guanhua Meng ◽  
Baohe Liu ◽  
Dongmin Tao ◽  
Pinjun Li ◽  
Jun Zheng
RSC Advances ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 6452-6459 ◽  
Author(s):  
Guangzhi Xin ◽  
Min Wang ◽  
Lin Chen ◽  
Yuzhou Zhang ◽  
Meicheng Wang ◽  
...  

A novel adsorbent zeolite/N-doped porous activated carbon (ZAC) was prepared by the synthesis of zeolite and mesoporous carbon to remove ammonia nitrogen (NH4+–N) and chemical oxygen demand (COD) from aqueous solution.


Author(s):  
Sheng Dong ◽  
Lijun Liu ◽  
Yuxiu Zhang ◽  
Fajun Jiang

In the drinking water industry, a common advanced treatment process is comprised of treatment with ozone, followed by biological-activated carbon (O3/BAC). However, the bacterial community formation and succession procedures associated with activated carbon have rarely been reported. In this study, the dynamics of bacterial communities at three different depths were investigated using a pilot-scale O3/BAC filter. The average chemical oxygen demand (CODMn), turbidity removal and dissolved oxygen (DO) consumption rate of the filter were 26.43%, 16.57% and 16.4% during the operation period, respectively. Bacterial communities dominated by proteobacteria and Bacteroidetes attached on activated carbon were determined by polymerase chain reaction-density gradient gel electrophoresis (PCR-DGGE). Principal component analysis (PCA) revealed that the compositions and structures of bacterial communities in different layers clustered after fluctuation. A redundancy analysis (RDA) indicated that Ramlibacter henchirensis was positively correlated to chemical oxygen demand (CODMn) removal and nitrate-N removal, and Georgfuchsia toluolica also showed a positive correlation with CODMn removal. Aquabacterium parvum and Phaeobacterium nitratireducens were positively-correlated with turbidity removal. Pedobacter glucosidilyticus and Pseudomonas sp. were associated with high dissolved oxygen (DO) consumption. These results provide insight into the succession characteristics of the bacterial community of O3/BAC treatment and the interactions of the bacterial community with filter operation performance.


Water ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2532
Author(s):  
Can He ◽  
Jianbing Wang ◽  
Heng Xu ◽  
Xiangyu Ji ◽  
Weiyi Wang ◽  
...  

In this work, the treatment of bio-treated coking wastewater (BCW) by catalytic ozonation was conducted in semi-batch and continuous flow reactors. The kinetics of chemical oxygen demand (COD) removal were analyzed using BCWs from five coking plants. An integral reactor with catalytic ozonation stacked by ozone absorption (IR) was developed, and its efficiency was studied. The catalyst of MnxCe1-xO2/γ-Al2O3 was efficient in the catalytic ozonation process for the treatment of various BCWs. The chemical oxygen demand (COD) removal efficiencies after 120 min reaction were 64–74%. The overall apparent reaction rate constants were 0.0101–0.0117 min−1, which has no obvious relationship with the initial COD of BCW and pre-treatment biological process. The IR demonstrated the highest efficiency due to the enhancement of mass transfer and the utilization efficiency of ozone. Bypass internal circulation can further improve the reactor efficiency. The optimal results were obtained with the ozone absorption section accounting for 19% of the valid water depth in the reactor and 250% of circulation flow ratio. The long-term and full-scale application of the novel reactor in a continuous mode indicated stable removal of COD and polycyclic aromatic hydrocarbons (PAHs). The results showed that the system of IR is a promising reactor type for tertiary treatment of coking wastewater by catalytic ozonation.


2010 ◽  
Vol 62 (11) ◽  
pp. 2669-2677 ◽  
Author(s):  
Lizhang Wang ◽  
Yuemin Zhao

Experiments were performed to reduce chemical oxygen demand (COD) from 4,4′-diaminostilbene-2,2′-disulfonic (DSD) acid manufacturing wastewater using electrochemical oxidation coupled with adsorption by granular activated carbon. The COD removal is affected by the residence time and applied voltage. When the residence time is increased, lower value of COD effluent could be obtained, however, the average current efficiency (ACE) decreased rapidly, and so does the applied voltage. In addition, aeration could effectively enhance COD removal efficiency and protect anodes from corrosion. Furthermore, the acidic condition is beneficial to the rapid decrease of COD and the values of pH effluent are independent of the initial solution pH. The optimization conditions obtained from these experiments are applied voltage of 4.8 V, residence time of 180 min and air–liquid ratio of 4.2 with the COD effluent of about 690 mg L−1. In these cases, the ACE and energy consumption are 388% and 4.144 kW h kg−1 COD, respectively. These perfect results from the experiments illustrate that the combined process is a considerable alternative for the treatment of industrial wastewater containing high concentration of organic pollutants and salinity.


2020 ◽  
Vol 26 (1) ◽  
Author(s):  
Hee-Jeong Choi

The purpose of this study was to investigate the effects of acidogenic fermentation broth with rice bran (RFFB), tap water (TFFB), or raw fishery by-products (FBs) on sludge reduction and biogas production in an anaerobic co-digestion process. Acidogenic fermentation of FBs with rice bran was faster and produced more volatile fatty acids than that with tap water. Reduction efficiencies for chemical oxygen demand, volatile solids, and total solids were highest in RFFB. In the kinetic analysis, λ (d), which represents the duration of the lag phase, was shortest with RFFB (1.09 d) and highest in sewage sludge (8.86 d). As the loading amount of volatile solids and chemical oxygen demand increased, the amount of cumulative biogas also increased. Amount of produced methane and energy recovery were highest with RFFB (5.71 kWh). Anaerobic co-digestion of FFB and sewage sludge allowed reduced sludge and recovered energy using the discarded waste as an organic carbon source.


2019 ◽  
Vol 8 (4) ◽  
pp. 6750-6755

In wastewater plastic recycling processing plant, commonly contain high chemical oxygen demand (COD) concentration. Coagulation-flocculation, adsorption and foam fractionation are the examples of treatment processes that can reduce COD concentration in wastewater. Steel slag can be used as an alternative to remove COD concentration of wastewater adsorption process. Linz-Donawitz (LD) slag can be obtained from steel manufacturing plant. LD slag also contains alkali oxides, porous characteristic, large surface area and contain an easy solid-liquid separation. This research is to study the percentage reduction of COD in wastewater using LD slag as adsorbent. This research will investigate the effect of particle size, dosage amount and contact time between LD slag and COD reduction. From the experiment, the highest percentage COD removal for particle size is 0.2mm, the dosage amount is 6 gram and the contact time is at 60 min. Comparison of COD removal by using coagulation -flocculation, adsorption using activated carbon and adsorption using LD slag processes was done. LD slag can reduce 2% higher of COD compared to activated carbon. LD slag should be invested more in wastewater treatment process.


Author(s):  
Maria Cristina Rizk ◽  
Rosangela Bergamasco ◽  
Célia Regina Granhen Tavares

Fruit and vegetable wastes are generated in large quantities around the world. This kind of residue constitutes a source of nuisance in municipal landfills because of its high biodegradability. Another residue that is generated in large quantities around the world and also constitutes a source of nuisance is the sewage sludge. Both residues can be treated together by the anaerobic co-digestion process. In this sense, the aim of the present study was to evaluate the anaerobic co-digestion of fruit and vegetable waste and sewage sludge, in order to monitor the waste stabilization time and the biogas generation, among others. The study was conducted in a 70 litter stainless steel anaerobic reactor, with no mixing system, at room temperature (25±5ºC), during a period of 105 days. The fruit and vegetable wastes were collected in a central distribution market for food, and were shredded and blended before the experiment. The seed inoculum was collected in an anaerobic domestic sewage station of treatment. The parameters analyzed were: chemical oxygen demand, C/N and C/N/P ratios, pH, alkalinity, volatile fatty acids, and biogas generation. The results showed that the chemical oxygen demand was reduced around 20%. The parameters, pH, alkalinity and volatile fatty acids were stabilized, but the C/N wasn’t stabilized. The final value obtained for C/N ratio was around 20/1. The biogas generation was around 331 litters and most of the biogas production occurred during the first month of the experiment. The low chemical oxygen demand removal, the high C/N ratio and the biogas generation almost always in the first few days of the experiment probably indicate that this residue, although being organic, presents difficulties in its degradation, maybe because of the high organic load that was applied to the reactor. The fact of the reactor being disproved by a mixing system can also have contributed to the low residue degradation.


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