A Novel Energy Model for MANETs based on Graphs with Activation Windows

2005 ◽  
Author(s):  
D.S. Fernandez ◽  
P. Manzoni
Keyword(s):  
Energy Model

Hydrogen Atom Transfer Reaction Free Energy as a Predictor of Abiotic Nitroaromatic Reduction Rate Constants: A Comprehensive Analysis

2019 ◽  
Author(s):  
Dominic Di Toro ◽  
Kevin P. Hickey ◽  
Herbert E. Allen ◽  
Richard F. Carbonaro ◽  
Pei C. Chiu
Keyword(s):  
Free Energy ◽  
Hydrogen Atom ◽  
Hydrogen Atom Transfer ◽  
Energy Model ◽  
Second Order ◽  
Transfer Model ◽  
Atom Transfer ◽  
Order Rate ◽  
Linear Free Energy ◽  
Free Energy Model

<div>A linear free energy model is presented that predicts the second order rate constant for the abiotic reduction of nitroaromatic compounds (NACs). For this situation previously presented models use the one electron reduction potential of the NAC reaction. If such value is not available, it has been has been proposed that it could be computed directly or estimated from the electron affinity (EA). The model proposed herein uses the Gibbs free energy of the hydrogen atom transfer (HAT) as the parameter in the linear free energy model. Both models employ quantum chemical computations for the required thermodynamic parameters. The available and proposed models are compared using second order rate constants obtained from five investigations reported in the literature in which a variety of NACs were exposed to a variety of reductants. A comprehensive analysis utilizing all the NACs and reductants demonstrate that the computed hydrogen atom transfer model and the experimental one electron reduction potential model have similar root mean square errors and residual error probability distributions. In contrast, the model using the computed electron affinity has a more variable residual error distribution with a significant number of outliers. The results suggest that a linear free energy model utilizing computed hydrogen transfer reaction free energy produces a more reliable prediction of the NAC abiotic reduction second order rate constant than previously available methods. The advantages of the proposed hydrogen atom transfer model and its mechanistic implications are discussed as well.</div>

scholarly journals Simulation of Self-Consumption Photovoltaic Installations: Profitability Thresholds

2021 ◽  
Vol 11 (14) ◽  
pp. 6517
Author(s):  
Marta Varo-Martínez ◽  
Luis Manuel Fernández-Ahumada ◽  
Rafael López-Luque ◽  
José Ramírez-Faz
Keyword(s):  
Systematic Study ◽  
Peak Power ◽  
Net Present Value ◽  
Energy Model ◽  
Present Value ◽  
Lower Power ◽  
Design Variables ◽  
Sunshine Hours ◽  
Optimal Value ◽  
Renewable Technology

PV self-consumption can contribute positively to the spread of PV and, therefore, to the progress of renewable energies as a key element in a decarbonized energy model. However, the policies of each country regarding the promotion of this type of renewable technology is fundamental for their growth. Despite the high number of sunshine hours registered in Spain, self-consumption in this country has not been authorized until recently. In this new context, this work presents a systematic study of the profitability limits of a self-consumption PV installation under different conditions of installed peak power, orientation and inclination of the PV panels and level of obstruction of the installation. It was proved that, for the case of study (Córdoba, Spain), the maximum profitability was achieved for PV panels oriented to the south and with an inclination of 15° whereas the most unfavourable conditions are those of PV panels with an orientation and inclination of 180° and 90°, respectively. Furthermore, when the level of obstruction increases the maximum of the Net Present Value of self-consumptions PV installations decreases and this optimal value is achieved for installations with lower power. Finally, empirical adjustment equations have been developed to estimate the profitability parameters of self-consumptions PV installations as a function of their design variables.

A Holistic Energy Model for Drones

2020 ◽  
Author(s):  
Umut Can Cabuk ◽  
Mustafa Tosun ◽  
Rune Hylsberg Jacobsen ◽  
Orhan Dagdeviren
Keyword(s):  
Energy Model

Effectiveness of a conservation energy model for nutrition problems in children with cancer

2021 ◽  
Vol 31 ◽  
pp. S82-S85
Author(s):  
La Saudi ◽  
Allenidekania Allenidekania ◽  
Nur Agustini
Keyword(s):  
Energy Model ◽  
Children With Cancer

scholarly journals Kinetic Modeling of CO2 and H2O Gasification Reactions for Metallurgical Coke Using a Distributed Activation Energy Model

ACS Omega ◽  
2021 ◽  
Vol 6 (17) ◽  
pp. 11436-11446
Author(s):  
Yui Numazawa ◽  
Yuki Hara ◽  
Yoshiya Matsukawa ◽  
Yohsuke Matsushita ◽  
Hideyuki Aoki ◽  
...  
Keyword(s):  
Activation Energy ◽  
Kinetic Modeling ◽  
Energy Model ◽  
Metallurgical Coke ◽  
Distributed Activation Energy Model
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