Thermal oxidation studies on methyl grafted natural rubber polymer electrolytes with paraphenylene diamine additive

2012 ◽  
Author(s):  
Ahmad Fairoz Bin Aziz ◽  
Ab Malik Marwan Ali
Keyword(s):  
Natural Rubber ◽  
Thermal Oxidation ◽  
Polymer Electrolytes

Phenothiazine as an Antifatigue Agent for Natural Rubber, Synthetic Polyisoprene and SBR

1965 ◽  
Vol 38 (3) ◽  
pp. 661-665
Author(s):  
Z. N. Tarasova ◽  
I. I. Eitingon ◽  
L. G. Senatorskaya ◽  
T. V. Fedorova ◽  
B. A. Dogadkin
Keyword(s):  
Mechanical Properties ◽  
Synergistic Effect ◽  
Natural Rubber ◽  
Thermal Oxidation ◽  
Fatigue Resistance

Abstract Phenothiazine has no effect on vulcanization of rubber or standard mechanical properties of the vulcanizates. Phenothiazine considerably increases fatigue resistance of vulcanizates of the rubbers studied, under different fatigue conditions. Under the effect of thermal oxidation and repeated deformation phenothiazine or its conversion products combine with the vulcanizate. The phenothiazine does not combine when subjected only to heating. When used with certain inhibitors of oxidation phenothiazine has a synergistic effect.

Study on Dehydration Process of Wet Natural Rubber by Single Screw Dehydrator and Properties of Dry Natural Rubber

2011 ◽  
Vol 418-420 ◽  
pp. 544-547
Author(s):  
Mei Chen ◽  
Fu Quan Zhang ◽  
Yong Zhou Wang ◽  
Mao Fang Huang ◽  
Wei Yong Deng
Keyword(s):  
Natural Rubber ◽  
Thermal Oxidation ◽  
Hammer Mill ◽  
Dehydration Process ◽  
Hot Air Drying ◽  
Single Screw ◽  
Hot Air ◽  
Unit Value ◽  
Better Than ◽  
Dehydration Effect

In this work, one self-invented closed single screw dehydrator was used to dehydrate wet natural rubber, instead of current three opened crepers and one hammer mill at home and abroad. The dehydration technology and the properties of the obtained dry natural rubber were studied. The results show that single screw dehydrator can simplify dehydration process. The water consumption of single screw dehydrator is 20% of current productive technology, meaning a lower wastewater discharge and treatment cost of wastewater. The moisture content of dehydrated natural rubber is lower than 20%, a good dehydration effect. The dry natural rubber dehydrated with single screw dehydrator has an improved thermal-oxidation ageing resistance whether dried by hot-air or microwave. The thermal-oxidation ageing resistance of natural rubber dried by microwave is better than that of hot-air drying, the value of initial plasticity (P0) and plasticity retention index (PRI) are 29.3 unit value and 19.26 unit value greater than that of SCR5 in GB/T 8081, respectively.

Effect of Phenylene Diamine Antioxidant on Physico-Chemical Properties of Methyl Grafted Natural Rubber Polymer Electrolytes

2017 ◽  
Vol 864 ◽  
pp. 48-53
Author(s):  
Ahmad Fairoz Aziz ◽  
Khuzaimah Nazir ◽  
S.F. Ayub ◽  
N.I. Adam ◽  
Muhd Zu Azhan Yahya ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Natural Rubber ◽  
Polymer Electrolytes ◽  
Chemical Properties ◽  
Physico Chemical ◽  
Solution Cast ◽  
Deconvolution Techniques ◽  
Tga And Dsc ◽  
Thermal Stability Of ◽  
Aging Factor

0.5 wt.% of N-(1,3-dimethylbutyl)-N’-phenyl-p-phenylenediamine (6PPD) was introduced into polymer electrolytes based on 30% poly(methyl-methacrylate) grafted natural rubber (MG30) in order to reduce the aging factor of MG30. The polymer electrolyte without 6PPD was used as control. All samples were prepared by using solution cast techniques. The effect of 6PPD in the electrolytes was analysed by using TGA, DSC and FTIR. TGA and DSC results revealed the thermal stability of MG30 electrolytes with 6PPD have higher thermal stability but lower glass transition temperature value. FTIR studies confirmed the existence of LiTF in the sample and prove the occurrence of polymer-salt complexation. Deconvolution techniques analysis on FTIR spectra shows the electrolyte sample with 6PPD display more ion dissociation which reflects to higher ionic conductivity.

Mastication of Elastomers II. Cold Mastication of Natural Rubber

1963 ◽  
Vol 36 (1) ◽  
pp. 102-110 ◽  
Author(s):  
G. M. Bristow
Keyword(s):  
Low Temperature ◽  
Natural Rubber ◽  
Thermal Oxidation ◽  
Chain Scission ◽  
Oxidative Process ◽  
Radical Acceptor

Abstract The cold mastication of natural rubber in oxygen is shown to proceed rather more rapidly than that in air. Reasons for this difference are considered. Mastication under these conditions is considered as a low temperature oxidative process and consistent with this the subsequent reactions of RO2 radicals produced by mechanical shear are shown to lead to some additional chain scission. The thermal oxidation of rubber masticated in oxygen is rather more rapid than that of rubber masticated in nitrogen in the presence of a radical acceptor.

Thermal Degradation Study of Lithium and Potassium Iodide/Epoxidized Natural Rubber Polymer Electrolytes

2013 ◽  
Vol 652-654 ◽  
pp. 757-764
Author(s):  
Tan Wei Leng ◽  
Yuan Xiang Yeoh ◽  
Mohamad Abu Bakar
Keyword(s):  
Thermal Degradation ◽  
Natural Rubber ◽  
Potassium Iodide ◽  
Polymer Electrolytes ◽  
Epoxidized Natural Rubber ◽  
Heating Rates ◽  
Salt Loading ◽  
Higher Ed ◽  
Degradation Activation Energy ◽  
Early Degradation

Lithium iodide/epoxidized natural rubber (LiI/ENR-50) and potassium iodide/epoxized natural rubber (KI/ENR-50) polymer electrolytes (PEs) were prepared via solvent casting. The PEs were characterized using FTIR, DSC and SEM techniques. The observed IR bands shift and the increased in Tg value in both PEs suggest that some interactions may have occurred between the ENR-50 and the respective cations. The appearance of new C=O band at ~1720 cm-1 coupled with the intensification of the OH band in KI/ENR-50 was due to the early degradation of ENR-50 promoted by KI. The kinetic analyses of the thermal degradation of neat ENR-50 and the respective PEs were studied using TG at five different heating rates. Kissinger was employed to obtain the degradation activation energy (Ed). LiI/ENR-50 shows higher Ed as compared to pristine ENR-50 and the Ed increases with increasing LiI loading. The Ed of KI/ENR-50 was observed to be higher than that of pristine ENR-50 when KI is 30 wt %. Thus, LiI retards the degradation of ENR-50 regardless of the wt % LiI added. KI, however, can either retard or catalyzed the degradation of ENR-50 depending on the salt loading.

Polymer electrolytes based on modified natural rubber for use in rechargeable lithium batteries

2001 ◽  
Vol 94 (2) ◽  
pp. 206-211 ◽  
Author(s):  
Razali Idris ◽  
M.D Glasse ◽  
R.J Latham ◽  
R.G Linford ◽  
W.S Schlindwein
Keyword(s):  
Natural Rubber ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Rechargeable Lithium Batteries

Impedance Behavior of Treated Methyl-Grafted Natural Rubber Polymer Electrolytes

2015 ◽  
Vol 1107 ◽  
pp. 217-222 ◽  
Author(s):  
Ahmad Fairoz Aziz ◽  
Khuzaimah Nazir ◽  
Siti Fadzilah Ayub ◽  
Rosnah Zakaria ◽  
Muhd Zu Azhan Yahya ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Dielectric Permittivity ◽  
Natural Rubber ◽  
Polymer Electrolyte ◽  
Polymer Electrolytes ◽  
Dissipation Factor ◽  
Dielectric Modulus ◽  
Aging Properties ◽  
Solution Cast ◽  
Cast Technique

Methyl-grafted natural rubber (MG30) was treated with N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine (6PPD) to enhance it anti-aging properties. The treated MG30 was used as polymer electrolyte by incorporating lithium trifluoromethane sulfonate (LiTF) through solution-cast technique. The impedance behavior of the sample has been carried out by analyzing the dielectric permittivity, dissipation factor, dielectric modulus and ionic conductivity as a function of temperature at different frequencies through impedance spectroscopy. Keywords: Methyl-grafted natural rubber, polymer electrolyte, N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine, ionic conductivity, dielectric.

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