Kinetics and Mechanism Study on Chlorine Dioxide Generation with Hydrogen Peroxide

2011 ◽  
Author(s):  
Zhu Mingxin ◽  
Huang Hui ◽  
Dong Xian ◽  
Shen Lina ◽  
Xu Yanhua
Keyword(s):  
Hydrogen Peroxide ◽  
Chlorine Dioxide ◽  
Kinetics And Mechanism ◽  
Mechanism Study

Bleaching optimization at WestRock mill in Covington, Virginia

TAPPI Journal ◽  
2016 ◽  
Vol 15 (9) ◽  
pp. 581-586 ◽  
Author(s):  
RICARDO B. SANTOS ◽  
PETER W. HART ◽  
DOUGLAS C. PRYKE ◽  
JOHN VANDERHEIDE
Keyword(s):  
Hydrogen Peroxide ◽  
Sodium Hydroxide ◽  
Chlorine Dioxide ◽  
Capital Expenditures ◽  
Equipment Repair ◽  
Optimization Program ◽  
Hardwood Pulp ◽  
Improved Performance

The WestRock mill in Covington, VA, USA, initiated a long term diagnostic and optimization program for all three of its bleaching lines. Benchmarking studies were used to help identify optimization opportunities. Capital expenditures for mixing improvement, filtrate changes, equipment repair, other equipment changes, and species changes were outside the scope of this work. This focus of this paper is the B line, producing southern hardwood pulp in a D(EP)DD sequence at 88% GE brightness. The benchmarking study and optimization work identified the following opportunities for improved performance: nonoptimal addition of caustic and hydrogen peroxide to the (EP) stage, carryover of D0 filtrate to the (EP) stage, and carryover of (EP) filtrate to the D1 stage. As a result of actions the mill undertook to address these opportunities, D0 kappa factor decreased about 5%, sodium hydroxide consumption in the (EP) stage decreased about 35%, chlorine dioxide consumption in the D1 stage decreased about 25%, and overall bleaching cost decreased about 15%.

scholarly journals Hydrogen peroxide and chlorine dioxide against parasite Ichthyophthirius multifiliis (Protozoa, Ciliophora) in jundiá fingerlings

2017 ◽  
Vol 47 (12) ◽  
Author(s):  
Natalia da Costa Marchiori ◽  
Fabiano Muller Silva ◽  
Maurício Laterça Martins ◽  
Hilton Amaral Junior ◽  
Bruno Corrêa da Silva
Keyword(s):  
Hydrogen Peroxide ◽  
Chlorine Dioxide ◽  
Fish Farming ◽  
Control Group ◽  
Chemical Agent ◽  
Ichthyophthirius Multifiliis ◽  
Larval Phase ◽  
Group Data ◽  
Active Chemical ◽  
Continuous Bath

ABSTRACT: Ichthyophthiriasis is a worldwide fish disease with great financial impact on freshwater fish farming due to its associated high mortality rates. Current study assesses the parasiticidal capacity of hydrogen peroxide (H2O2) and chlorine dioxide (ClO2) against the causative agent, Ichthyophthirius multifiliis, in jundiá. Median lethal concentration (LC50, 96h) of each chemical agent was established, as well as the minimum inhibitory concentration of hydrogen peroxide for the parasite´s infectious larval phase (theront). Products were tested asynchronously in parasitized fingerlings for short and long baths at the following concentrations and exposure times: 1. Hydrogen peroxide: (T1) continuous bath - 30ppm and (T2) 50ppm; (T3) short bath - 150ppm, during 1h and (T4) 250ppm during 1h; control group (without any chemical agent). 2. Chlorine dioxide: (T1) continuous bath - 4ppm and (T2) 20ppm; (T3) short bath - 200ppm, during 1min; (T4) short bath - 400ppm, during 1min and control group. Data analysis demonstrated a concentration of 82.54ppm of the commercial product (or 24.76ppm of the active chemical agent) as LC50, 96h of H2O2 and 38.4ppm product (or 2.68ppm of the active chemical agent) for ClO2. Hydrogen peroxide concentration causing 100% mortality rate of theronts in 1h was 25ppm (product, or 7.5ppm of the active chemical agent). At the end of the fourth day of curative experiment, 98% of the animals died by ichthyophthiriasis. No treatment was effective against the parasite.

Kinetics and Mechanism of the Oxidation of Pentathionate Ion by Chlorine Dioxide in a Slightly Acidic Medium

2014 ◽  
Vol 118 (8) ◽  
pp. 1293-1299 ◽  
Author(s):  
Li Xu ◽  
György Csekő ◽  
Andrea Petz ◽  
Attila K. Horváth
Keyword(s):  
Chlorine Dioxide ◽  
Acidic Medium ◽  
Kinetics And Mechanism

Initiating ECF bleaching sequences of eucalyptus kraft pulps with Z/D and Z/E stages

Holzforschung ◽  
2010 ◽  
Vol 64 (1) ◽  
Author(s):  
Juan C. García ◽  
Francisco López ◽  
Antonio Pérez ◽  
M. Angels Pèlach ◽  
Pere Mutjé ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Chlorine Dioxide ◽  
Ecological Impact ◽  
Substantial Reduction ◽  
Reference Sequence ◽  
Kraft Pulps ◽  
Eucalyptus Kraft Pulp ◽  
The Impact ◽  
Ecf Bleaching ◽  
Ozone Bleaching

Abstract Ozone bleaching is a common practice in pulping, and also of eucalyptus, where it is usually applied in combination with bleaching sequences based on oxygen, hydrogen peroxide, or chlorine dioxide. Ozone has been proven to be a highly efficient and competitive bleaching chemical in terms of delignification efficiency, low costs, and reducing ecological impact. The objective of the present work was to evaluate technology with ozone/alkaline extraction (Z/E) and ozone/chlorine dioxide (Z/D) for bleaching of eucalyptus kraft pulp. Primarily, the impact of these bleaching steps on refinability and quality of pulp should be investigated. As reference, the sequence D*(EP)D (hot chlorine dioxide, extraction in presence of hydrogen peroxide, chlorine dioxide) was selected, which is considered as the state-of-the-art bleaching in elemental chlorine free (ECF) bleaching technology. Various bleaching sequences with ozone in their first step (Z/D(EP)DP, Z/D(EP)DD, Z/EDP, Z/EDD and A*Z/EDP) were found to provide kraft pulps of similar brightness and in similar yield as the reference sequence D*(EP)D. The kappa number, viscosity, and the contents of glucose and xylose, and hexenuronic acid of the pulps were also similar. In addition, the Z sequences resulted in a substantial reduction of the total chlorine dioxide consumption (more than 30.3% in all cases). The A*Z/EDP sequence, which proved to be the most efficient, yielded 87.5% ClO2 reduction. The studied bleaching sequences also resulted in substantially improved brightness reversal with regard to the reference sequence. The sequence A*Z/EDP was also the most efficient as regards the removal or organochlorines (OX) from the pulp and their reduction in the effluents (AOX). Ozone bleaching sequences improved paper strength, especially with the A*Z/EDP sequence.

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