scholarly journals Bis(2,4-dimethoxyphenyl)(phenyl)phosphine selenide

2010 ◽  
Vol 67 (1) ◽  
pp. o97-o97
Author(s):  
Alfred Muller
Keyword(s):  
Phosphine Selenide

FACILE REDUCTION OF SELENOXIDE WITH PHOSPHINE SELENIDE

1977 ◽  
Vol 6 (8) ◽  
pp. 1003-1004 ◽  
Author(s):  
Keishi Sakaki ◽  
Shigeru Oae
Keyword(s):  
Phosphine Selenide

scholarly journals Tris(4-methoxyphenyl)phosphine selenide

IUCrData ◽  
2016 ◽  
Vol 1 (8) ◽  
Author(s):  
Melina Raymundo ◽  
Clifford W. Padgett ◽  
Will E. Lynch
Keyword(s):  
Bond Length ◽  
Title Compound ◽  
Phenyl Ring ◽  
Phosphine Selenide ◽  
Torsion Angles ◽  
Compound C ◽  
Tetrahedral Environment ◽  
Methoxy Groups ◽  
Phenyl Rings ◽  
Close Contacts

The title compound, C21H21O3PSe, is comprised of a P atom in a distorted tetrahedral environment, attached to the Se atom and three C atoms of the phenyl rings. The P—Se bond length is 2.1214 (12) Å. All three methoxy groups are near coplanar with their respective phenyl rings, with the angles between the phenyl ring and the C—O bond of the methoxy groups being 5.7 (2), 1.5 (4), and 5.7 (3)°. The torsion angles of the phenyl rings relative to the P=Se bond are 35.62 (10), 35.07 (13), and 44.50 (11)°. No strong intermolecular interactions were observed, but that in addition to van der Waals forces, there are C—H...π and C—H...Se close contacts.

scholarly journals Measuring and Leveraging Electrostatic Effects in a Charged Phosphine

2020 ◽  
Author(s):  
Andrew J. McNeece ◽  
Margaret L. Kelty ◽  
Alexander S. Filatov ◽  
John Anderson
Keyword(s):  
Electric Fields ◽  
Phase Reaction ◽  
Reaction Conditions ◽  
Phosphine Selenide ◽  
Molecular Systems ◽  
Common Solution ◽  
Electrostatic Component ◽  
Theoretical Predictions ◽  
Charged Group ◽  
Space Effects

<div>Local electric fields have recently been investigated for optimizing reactivity in synthetic systems. However, disentangling the relative contributions of inductive (through-bond) and electrostatic (through-space) effects in molecular systems has been a long-standing challenge. To understand the interplay of these effects and leverage electrostatic influences for enhanced reactivity, we have synthesized a distally charged phosphine, Ph<sub>2</sub>PCH<sub>2</sub>BF<sub>3</sub><sup>−</sup>, and studied the effect of the charged trifluoroborate group on its donor properties and reactivity. This charged phosphine displays solvent-dependent changes in donor strength as measured by the <i>J</i><sub>P-Se</sub> of the corresponding phosphine selenide. The variation with solvent dielectric illustrates a significant electrostatic component to the donor strength. Computations further support the importance of electrostatic contributions and highlight the effect of charge position and orientation. Finally, this charged group also greatly accelerates C–F oxidative addition reactivity in Ni complexes, experimentally</div><div>verifying recent theoretical predictions. These results show that covalently bound charged functionalities can exert a significant electrostatic influence even under common solution phase reaction conditions.</div>

Reaction of [Pt{Fe(CO)3(NO)}2(PhCN)2] with diphenyl(2-pyridyl)phosphine selenide. Crystal structure of [(CO)3Fe(μ3-Se){Pt(CO)P(2-C5H4N)Ph2}2] and its theoretical study

2002 ◽  
Vol 330 (1) ◽  
pp. 95-102 ◽  
Author(s):  
Claudia Graiff ◽  
Andrea Ienco ◽  
Chiara Massera ◽  
Carlo Mealli ◽  
Giovanni Predieri ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Theoretical Study ◽  
Phosphine Selenide

Coordination studies of the ferrocenyl phosphine selenide ligand FcCON(CH2CH2PPh2Se)2

2014 ◽  
Vol 760 ◽  
pp. 84-88 ◽  
Author(s):  
Silvia Canales ◽  
M. Dolores Villacampa ◽  
Antonio Laguna ◽  
M. Concepción Gimeno
Keyword(s):  
Phosphine Selenide

Phosphine Selenide Arenetellenyliodide Complexes and Telluroselenophosphonium Salts

2008 ◽  
Vol 183 (4) ◽  
pp. 1072-1075 ◽  
Author(s):  
Cristian G. Hrib ◽  
Wolf– W. du Mont ◽  
Jörg Jeske
Keyword(s):  
Phosphine Selenide

Tris(4-fluorophenyl)phosphine selenide

2007 ◽  
Vol 63 (10) ◽  
pp. o4055-o4055 ◽  
Author(s):  
Alfred Muller ◽  
Reinout Meijboom
Keyword(s):  
Phosphine Selenide
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