scholarly journals {N,N′-Bis[(E)-3-phenylprop-2-en-1-ylidene]propane-1,3-diamine-κ2N,N′]dichloridocobalt(II)

2009 ◽  
Vol 65 (6) ◽  
pp. m617-m617 ◽  
Author(s):  
Morteza Montazerozohori ◽  
Mohammad Hossein Habibi ◽  
Mehdi Amirnasr ◽  
Keita Ariyoshi ◽  
Takayoshi Suzuki
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Mirror Symmetry ◽  
Schiff Base Complex ◽  
Mirror Plane ◽  
Tetrahedral Geometry ◽  
Base Complex ◽  
Distorted Tetrahedral Geometry ◽  
Cl Atoms

The CoIIatom in the title monomeric Schiff base complex, [CoCl2(C21H22N2)], is bonded to two Cl atoms and to two N atoms of the Schiff base ligandN,N′-bis[(E)-3-phenylprop-2-en-1-ylidene]propane-1,3-diamine in a distorted tetrahedral geometry. The molecule has an idealised mirror symmetry, but is not located on a crystallographic mirror plane.

A new Mo(iv) complex with the pentadentate (N3O2) Schiff-base ligand: the first non-cyanide pentagonal–bipyramidal paramagnetic 4d complex

2017 ◽  
Vol 46 (41) ◽  
pp. 14083-14087 ◽  
Author(s):  
V. S. Mironov ◽  
T. A. Bazhenova ◽  
Yu. V. Manakin ◽  
K. A. Lyssenko ◽  
A. D. Talantsev ◽  
...  
Keyword(s):  
Schiff Base ◽  
Single Molecule ◽  
Schiff Base Ligand ◽  
Schiff Base Complex ◽  
Building Blocks ◽  
Single Molecule Magnets ◽  
Base Complex

Characterized both structurally and magnetically, a new molybdenum(iv) Schiff-base complex represents a novel family of the pentagonal–bipyramidal 4d-metal-based building blocks for construction of advanced single-molecule magnets.

scholarly journals [N,N′-Bis(2,6-diethyl-4-phenylphenyl)butane-2,3-diimine-κ2N,N′]dibromidonickel(II)

2014 ◽  
Vol 70 (3) ◽  
pp. m102-m102
Author(s):  
Jianchao Yuan ◽  
Jingjing Xia ◽  
Weibing Xu ◽  
Yanqiong Mu
Keyword(s):  
Dihedral Angle ◽  
Title Compound ◽  
Mirror Symmetry ◽  
Complex Molecule ◽  
Mirror Plane ◽  
Tetrahedral Geometry ◽  
Distorted Tetrahedral Geometry ◽  
Benzene Rings ◽  
Diimine Ligand

The complex molecule in the title compound, [NiBr2(C36H40N2)], has mirror symmetry. The NiIIatom and two Br atoms are located on the mirror plane. The NiIIatom is four-coordinated by the two Br atoms and two N atoms from anN,N′-bis(2,6-diethyl-4-phenylphenyl)butane-2,3-diimine ligand in a distorted tetrahedral geometry. The dihedral angle formed between the two adjacent benzene rings is 47.1 (1)°.

scholarly journals [N,N′-Bis(2,3,4-trimethoxybenzylidene)ethane-1,2-diamine-κ2N,N′]dibromidomercury(II)

2012 ◽  
Vol 68 (8) ◽  
pp. m1044-m1044
Author(s):  
Aliakbar Dehno Khalaji ◽  
Michal Dušek ◽  
Karla Fejfarová
Keyword(s):  
Schiff Base ◽  
Dihedral Angle ◽  
Schiff Base Ligand ◽  
Title Compound ◽  
Tetrahedral Geometry ◽  
Distorted Tetrahedral Geometry

In the title compound, [HgBr2(C22H28N2O6)], the HgIIion is bonded to two Br−ions and two N atoms of the chelating Schiff base ligand in a distorted tetrahedral geometry. The Schiff base ligand adopts anE,Econformation. The dihedral angle between the planes of the two halves of the centralN,N′-dimethylethylenediamine part of the ligand is 2.3 (11)°. The crystal studied was twinned by pseudomerohedry [twin law (0-10/-100/00-1)]; the contribution of the minor twin component refined to 0.208 (3).

Significant photocytotoxic effect of an iron(iii) complex of a Schiff base ligand derived from vitamin B6and thiosemicarbazide in visible light

RSC Advances ◽  
2015 ◽  
Vol 5 (37) ◽  
pp. 29276-29284 ◽  
Author(s):  
Tukki Sarkar ◽  
Samya Banerjee ◽  
Akhtar Hussain
Keyword(s):  
Schiff Base ◽  
Visible Light ◽  
Cancer Cells ◽  
Schiff Base Ligand ◽  
Schiff Base Complex ◽  
Vitamin B ◽  
Base Complex

An iron(iii)–Schiff base complex derived from vitamin B6and thiosemicarbazide is significantly photocytotoxic to HeLa cancer cells in visible light (400 nm–700 nm) but non-toxic in the absence of light.

A new copper(II) Schiff base complex containing asymmetrical tetradentate N2O2 Schiff base ligand: Synthesis, characterization, crystal structure and DFT study

2015 ◽  
Vol 1082 ◽  
pp. 91-96 ◽  
Author(s):  
Gholamhossein Grivani ◽  
Sara Husseinzadeh Baghan ◽  
Mohammad Vakili ◽  
Aliakbar Dehno Khalaji ◽  
Vida Tahmasebi ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Schiff Base Complex ◽  
Dft Study ◽  
Base Complex ◽  
Ligand Synthesis

{2-[3-(Dimethylammonio)propyliminomethyl]-6-methoxyphenolato}diisothiocyanatozinc(II) chloroform solvate

2007 ◽  
Vol 63 (3) ◽  
pp. m652-m653 ◽  
Author(s):  
Qi-Wei Zhang ◽  
Gui-Xian Wang
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Title Compound ◽  
Tetrahedral Geometry ◽  
Distorted Tetrahedral Geometry

The Zn atom in the title compound, [Zn(NCS)2(C13H20N2O2)]·CHCl3, is coordinated by two N atoms of two isothiocyanate ligands, and an O and an imine N atom from the neutral Schiff base ligand 2-[3-(dimethylammonio)propyliminomethyl]-6-methoxyphenolate, in a distorted tetrahedral geometry.

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