Temperature-dependent gyration tensor of LiIO3single crystal using the high-accuracy universal polarimeter

2002 ◽  
Vol 35 (2) ◽  
pp. 228-232 ◽  
Author(s):  
J. Herreros-Cedrés ◽  
C. Hernández-Rodríguez ◽  
R. Guerrero-Lemus
Keyword(s):  
Optical Activity ◽  
High Accuracy ◽  
Multiple Reflections ◽  
Temperature Dependent ◽  
Temperature Range ◽  
High Degree

The gyration tensor of LiIO3has been measured in the temperature range between 293 and 493 K at a wavelength of 632.8 nm. Optical activity and birefringence for the (010) plane were determined by using a high-accuracy universal polarimeter (HAUP). Likewise, optical activity for the (001) plane was studied by using a conventional polarimeter in the same temperature range at 632.8 nm wavelength. In the latter case, a modulation of the optical activity was observed. This effect can be explained by multiple reflections within the slab with a high degree of plane parallelism.

scholarly journals Empirical Model With Excellent Statistical Properties for Describing Temperature-Dependent Developmental Rates of Insects and Mites

2017 ◽  
Vol 110 (3) ◽  
pp. 302-309 ◽  
Author(s):  
David A. Ratkowsky ◽  
Gadi V. P. Reddy
Keyword(s):  
Nonlinear Regression ◽  
Empirical Model ◽  
Minimum Variance ◽  
Statistical Properties ◽  
Parameter Estimates ◽  
Regression Equations ◽  
Temperature Dependent ◽  
Temperature Range ◽  
Least Squares Estimators ◽  
Development Rates

Abstract Previous empirical models for describing the temperature-dependent development rates for insects include the Briére, Lactin, Beta, and Ratkowsky models. Another nonlinear regression model, not previously considered in population entomology, is the Lobry–Rosso–Flandrois model, the shape of which is very close to that of the Ratkowsky model in the suboptimal temperature range, but which has the added advantage that all four of its parameters have biological meaning. A consequence of this is that initial parameter estimates, needed for solving the nonlinear regression equations, are very easy to obtain. In addition, the model has excellent statistical properties, with the estimators of the parameters being “close-to-linear,” which means that the least squares estimators are close to being unbiased, normally distributed, minimum variance estimators. The model describes the pooled development rates very well throughout the entire biokinetic temperature range and deserves to become the empirical model of general use in this area.

Analysis of temperature dependent electrical characteristics of Au/n-GaAs/GaAs structures in a wide temperature range

Vacuum ◽  
2008 ◽  
Vol 83 (2) ◽  
pp. 276-281 ◽  
Author(s):  
A. Bengi ◽  
S. Altındal ◽  
S. Özçelik ◽  
S.T. Agaliyeva ◽  
T.S. Mammadov
Keyword(s):  
Wide Temperature Range ◽  
Electrical Characteristics ◽  
Temperature Dependent ◽  
Temperature Range

Technique and results of experimental determination of the compressibility factor of the natural gas

2021 ◽  
pp. 35-40
Author(s):  
Denis Y. Kutovoy ◽  
Igor A. Yatsenko ◽  
Vladimir B. Yavkin ◽  
Aydar N. Mukhametov ◽  
Petr V. Lovtsov ◽  
...  
Keyword(s):  
Natural Gas ◽  
Equations Of State ◽  
Compressibility Factor ◽  
High Accuracy ◽  
State Equations ◽  
Actual Problem ◽  
Temperature Range ◽  
Relative Value ◽  
Compressibility Coefficient

The actual problem of the possibility of using the equations of state for the gas phase of natural gas at temperatures below 250 K is considered. To solve it, the compressibility coefficients of natural gas obtained experimentally with high accuracy are required. The technique was developed and experimental study was carried out of compressibility factor aiming expanding temperature range of the state equations GERG-2004 and AGA8-DC92. The proposed technique is based on the fact that to assess the applicability of the equation of state, it is sufficient to obtain the relative value of the compressibility coefficient and not to determine its absolute value. The technique does not require complex equipment and provides high accuracy. The technique was tested on nitrogen, argon, air and methane. Uncertainty of determination of the compressibility factor is not greater than 0.1 %. For two different compositions of natural gas, obtained experimental data were demonstrated that the equations of state GERG-2004 and AGA8-92DC provide uncertainty of the calculation of the compressibility coefficient within 0.1 % in the temperature range from 220 K to 250 K and pressure below 5 MPa.

scholarly journals Experimental and computational kinetics investigations for the reactions of Cl atoms with series of unsaturated ketones in gas phase

2017 ◽  
Author(s):  
Siripina Vijayakumar ◽  
Avinash Kumar ◽  
Balla Rajakuma
Keyword(s):  
Gas Phase ◽  
State Theory ◽  
Rate Coefficients ◽  
Gas Phase Reactions ◽  
Temperature Dependent ◽  
Unsaturated Ketones ◽  
Temperature Range ◽  
Computational Calculations ◽  
Temperature Rate ◽  
Cl Atoms

Abstract. Temperature dependent rate coefficients for the gas phase reactions of Cl atoms with 4-hexen-3-one and 5-hexen-2-one were measured over the temperature range of 298–363 K relative to 1-pentene, 1,3-butadiene and isoprene. Gas Chromatography (GC) was used to measure the concentrations of the organics. The derived temperature dependent Arrhenius expressions are k4-hexen-3-one+Cl (298–363 K) = (2.82 ± 1.76)×10−12exp [(1556 ± 438)/T] cm3 molecule−1 s−1 and k5-hexen-2-one+Cl (298–363 K) = (4.6 ± 2.4)×10−11exp[(646 ± 171)/T] cm3 molecule−1 s−1. The corresponding room temperature rate coefficients are (5.54 ± 0.41)×10−10 cm3 molecule−1 s−1 and (4.00 ± 0.37)×10−10 cm3 molecule−1 s−1 for the reactions of Cl atoms with 4-hexen-3-one and 5-hexen-2-one respectively. To understand the mechanism of Cl atom reactions with unsaturated ketones, computational calculations were performed for the reactions of Cl atoms with 4-hexen-3-one, 5-hexen-2-one and 3-penten-2-one over the temperature range of 275–400 K using Canonical Variational Transition state theory (CVT) with Small Curvature Tunneling (SCT) in combination with CCSD(T)/6-31+G(d, p)//MP2/6-311++G(d, p) level of theory. Atmospheric implications, reaction mechanism and feasibility of the title reactions are discussed in this manuscript.

Chlorine nuclear quadrupole resonance lineshape in the cubic antifluorite K2OsCl6

1985 ◽  
Vol 63 (3) ◽  
pp. 350-353 ◽  
Author(s):  
Maximo E. Ramia ◽  
Robin L. Armstrong
Keyword(s):  
Nuclear Quadrupole Resonance ◽  
Point Defects ◽  
Temperature Dependent ◽  
Local Strains ◽  
Temperature Range ◽  
Quadrupole Resonance ◽  
Symmetric Line ◽  
Nuclear Quadrupole

Chlorine nuclear quadrupole resonance lineshapes are reported for the cubic antifluorite K2OsCl6 in the temperature range 70–300 K. For temperatures above 172 K the spectrum consists of a single symmetric line; for temperatures below 172 K an asymmetric line is observed which can be represented as a sum of two symmetric lines. The symmetric lines are temperature dependent mixtures of Lorentzian and Gaussian profiles. The explanation is that the nuclear quadrupole resonance lines observed in K2OSCl6 are inhomogeneously broadened by temperature dependent local strains caused by point defects and dislocations.

scholarly journals Temperature Dependent Seed Germination of Dalbergia nigra Allem (Leguminosae)

2001 ◽  
Vol 44 (4) ◽  
pp. 401-404 ◽  
Author(s):  
Fernanda G. A. Ferraz-Grande ◽  
Massanori Takaki
Keyword(s):  
Seed Germination ◽  
Endangered Species ◽  
High Temperatures ◽  
Broad Temperature Range ◽  
Optimum Temperature ◽  
Temperature Dependent ◽  
Temperature Range ◽  
Dalbergia Nigra ◽  
The Mean ◽  
Kinetics Of

The germination of endangered species Dalbergia nigra was studied and 30.5° C was found as optimum temperature, although the species presented a broad temperature range where germination occurs and light had no effect. The analysis of kinetics of seed germination confirmed the asynchronized germination below and above the optimum temperature. The light insensitive seed and germination also at high temperatures indicated that D. nigra could occur both in understories and gaps where the mean temperature was high.

scholarly journals High accuracy magnetic field sensors with wide operation temperature range

2016 ◽  
Vol 151 ◽  
pp. 012029
Author(s):  
I S Vasil'evskii ◽  
A N Vinichenko ◽  
D I Rubakin ◽  
I A Bolshakova ◽  
N I Kargin
Keyword(s):  
Magnetic Field ◽  
High Accuracy ◽  
Magnetic Field Sensors ◽  
Temperature Range ◽  
Operation Temperature
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