scholarly journals Beyond theT1Limit: Singlet Nuclear Spin States in Low Magnetic Fields

2004 ◽  
Vol 92 (15) ◽  
Author(s):  
Marina Carravetta ◽  
Ole G. Johannessen ◽  
Malcolm H. Levitt
2019 ◽  
Vol 21 (33) ◽  
pp. 18188-18194
Author(s):  
Ivan V. Zhukov ◽  
Alexey S. Kiryutin ◽  
Alexandra V. Yurkovskaya ◽  
Konstantin L. Ivanov

A study of long-lived spin states in hetero-nuclear spin systems is presented.


2007 ◽  
Vol 16 (4) ◽  
pp. 998-1007 ◽  
Author(s):  
Luo Jun ◽  
Sun Xian-Ping ◽  
Zeng Xi-Zhi ◽  
Zhan Ming-Sheng

Author(s):  
Gerd Kothe ◽  
Michail Lukaschek ◽  
Tomoaki Yago ◽  
Gerhard Link ◽  
Konstantin L. Ivanov ◽  
...  

2016 ◽  
Vol 94 (2) ◽  
Author(s):  
Hannah Clevenson ◽  
Edward H. Chen ◽  
Florian Dolde ◽  
Carson Teale ◽  
Dirk Englund ◽  
...  

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Yonghong Ding ◽  
Alexey S. Kiryutin ◽  
Alexandra V. Yurkovskaya ◽  
Denis V. Sosnovsky ◽  
Renad Z. Sagdeev ◽  
...  

AbstractThe solid-state photo-chemically induced dynamic nuclear polarization (photo-CIDNP) effect generates non-equilibrium nuclear spin polarization in frozen electron-transfer proteins upon illumination and radical-pair formation. The effect can be observed in various natural photosynthetic reaction center proteins using magic-angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy, and in a flavin-binding light-oxygen-voltage (LOV) domain of the blue-light receptor phototropin. In the latter system, a functionally instrumental cysteine has been mutated to interrupt the natural cysteine-involving photochemistry allowing for an electron transfer from a more distant tryptophan to the excited flavin mononucleotide chromophore. We explored the solid-state photo-CIDNP effect and its mechanisms in phototropin-LOV1-C57S from the green alga Chlamydomonas reinhardtii by using field-cycling solution NMR. We observed the 13C and, to our knowledge, for the first time, 15N photo-CIDNP signals from phototropin-LOV1-C57S. Additionally, the 1H photo-CIDNP signals of residual water in the deuterated buffer of the protein were detected. The relative strengths of the photo-CIDNP effect from the three types of nuclei, 1H, 13C and 15N were measured in dependence of the magnetic field, showing their maximum polarizations at different magnetic fields. Theoretical level crossing analysis demonstrates that anisotropic mechanisms play the dominant role at high magnetic fields.


2009 ◽  
Vol 78 (7) ◽  
pp. 075003 ◽  
Author(s):  
Minki Jeong ◽  
Myeonghun Song ◽  
Tomohiro Ueno ◽  
Takao Mizusaki ◽  
Akira Matsubara ◽  
...  

2015 ◽  
Vol 142 (4) ◽  
pp. 044506 ◽  
Author(s):  
Jean-Nicolas Dumez ◽  
Pär Håkansson ◽  
Salvatore Mamone ◽  
Benno Meier ◽  
Gabriele Stevanato ◽  
...  

2015 ◽  
Vol 17 (8) ◽  
pp. 5913-5922 ◽  
Author(s):  
Gabriele Stevanato ◽  
Soumya Singha Roy ◽  
Joe Hill-Cousins ◽  
Ilya Kuprov ◽  
Lynda J. Brown ◽  
...  

Long-lived states exist far from magnetic equivalence when the local geometry is centrosymmetric.


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