scholarly journals Ultralow effective interfacial tension between miscible molecular fluids

2020 ◽  
Vol 5 (7) ◽  
Author(s):  
Alessandro Carbonaro ◽  
Luca Cipelletti ◽  
Domenico Truzzolillo
Keyword(s):  
Interfacial Tension ◽  
Molecular Fluids

scholarly journals SAFT-γ force field for the simulation of molecular fluids: 8. Hetero-segmented coarse-grained models of perfluoroalkylalkanes assessed with new vapour–liquid interfacial tension data

2016 ◽  
Vol 114 (18) ◽  
pp. 2597-2614 ◽  
Author(s):  
Pedro Morgado ◽  
Olga Lobanova ◽  
Erich A. Müller ◽  
George Jackson ◽  
Miguel Almeida ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Force Field ◽  
Coarse Grained ◽  
Molecular Fluids

Perbandingan Karakteristik Surfaktan Metil Ester Sulfonat dan Sodium Lauril Sulfonat sebagai Bahan Emulsifier

2016 ◽  
Vol 9 (2) ◽  
pp. 167-176
Author(s):  
Eldha Sampepana ◽  
Paluphy Eka Yustini ◽  
Aditya Rinaldi ◽  
Amiroh Amiroh
Keyword(s):  
Fatty Acids ◽  
Surface Tension ◽  
Methyl Ester ◽  
Interfacial Tension ◽  
Palm Oil ◽  
Emulsion Stability ◽  
Raw Material ◽  
Enzymatic Method

Surfactant which is used as raw emulsifier in an industry activity such as Sodium Lauryl Sulfonate is a raw material import, it is petroleum derivative which is not renewable and may cause pollution to the environment, because it is not degraded and are carcinogenic. The purpose of the research is to compare the characteristics of the Quaternary methyl ester sulfonat (MES) and Sodium Lauryl Sulfonat (SLS) as emulsifier. First, make the MES by filtering and eliminating fatty acids of palm oil, then process the MES with enzymatic method become methyl ester, then react it in sulfonation and metanolization process, and also neutralized with NaOH. Next, the MES experiment is compared with SLS and existing MES in the market. The results show that surfactants MES experiment has value hidrofil lipofil balance (HLB) interfacial tension and emulsion stability greater than MES in the market and SLS. And the surface tension of MES experiment is larger than MES in the market, but smaller compared to SLS.ABSTRAKSurfaktan yang digunakan sebagai bahan baku emulsifer dalam aktivitas suatu industri pada saat ini seperti Sodium Lauril Sulfonat  merupakan bahan baku import yang merupakan turunan dari minyak bumi, dengan sifat tidak dapat diperbaharui dan dapat menimbulkan pencemaran terhadap lingkungan karena tidak mudah terdegradasi serta bersifat karsinogenik. Metil ester sulfonat dari bahan minyak sawit merupakan surfaktan dengan sifat mudah terdegradasi yang perlu diketahui karakteristiknya. Penelitian bertujuan untuk membandingkan karakteristik surfaktan metil ester sulfonat (MES) dan Sodium Lauril Sulfonat (SLS) sebagai bahan emulsifier. Mula-mula dilakukan pembuatan MES dengan cara menyaring dan menghilangkan asam lemak minyak sawit terlebih dahulu, kemudian diolah menjadi metil ester secara enzimatis, lalu direaksikan secara sulfonasi dan metanolisis, serta dinetralkan dengan NaOH. Selanjutnya MES hasil percobaan dibandingkan dengan SLS dan MES yang ada dipasaran. Hasil penelitian menunjukkan bahwa surfaktan MES memiliki nilai hidrofil lipofil balance (HLB) tegangan antar muka dan stabilitas emulsi lebih besar apabila dibandingkan dengan MES di pasaran dan SLS, kecuali nilai stabilitas emulsi antara MES dan SLS sama. Dan tegangan permukaan MES hasil percobaan, lebih besar dibandingkan dengan MES dipasaran, dan lebih kecil dibandingkan dengan SLS. Kata kunci :   Metil  ester sulfonat, hidrofil lipofil balance, emulsifier, sodium lauril sulfonat , stabilitas emulsi 

Ultra-Low Interfacial Tension of a Surfactant under a Wide Range of Temperature and Salinity Conditions for Chemical Enhanced Oil Recovery

2018 ◽  
Vol 55 (3) ◽  
pp. 252-257 ◽  
Author(s):  
Derong Xu ◽  
Wanli Kang ◽  
Liming Zhang ◽  
Jiatong Jiang ◽  
Zhe Li ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Wide Range ◽  
Low Interfacial Tension

Phase Inversion in Two-Phase Liquid Systems

1992 ◽  
Vol 57 (7) ◽  
pp. 1419-1423
Author(s):  
Jindřich Weiss
Keyword(s):  
Interfacial Tension ◽  
Phase Inversion ◽  
Continuous Phase ◽  
Considerable Effect ◽  
Weak Dependence ◽  
Dispersed Phase ◽  
Two Phase ◽  
Liquid Systems ◽  
Phase Liquid

New data on critical holdups of dispersed phase were measured at which the phase inversion took place. The systems studied differed in the ratio of phase viscosities and interfacial tension. A weak dependence was found of critical holdups on the impeller revolutions and on the material contactor; on the contrary, a considerable effect of viscosity was found out as far as the viscosity of continuous phase exceeded that of dispersed phase.

Modeling oil-brine interfacial tension at high pressure and high salinity conditions

2019 ◽  
Vol 183 ◽  
pp. 106413 ◽  
Author(s):  
Menad Nait Amar ◽  
Mohammadhadi Shateri ◽  
Abdolhossein Hemmati-Sarapardeh ◽  
Alireza Alamatsaz
Keyword(s):  
High Pressure ◽  
Interfacial Tension ◽  
High Salinity

Critical Raman line shape behavior of fluid nitrogen

2004 ◽  
Vol 76 (1) ◽  
pp. 147-155 ◽  
Author(s):  
M. Musso ◽  
F. Matthai ◽  
D. Keutel ◽  
K.-L. Oehme
Keyword(s):  
Raman Line ◽  
Line Shape ◽  
Line Broadening ◽  
Vibrational Resonance ◽  
Critical Isochore ◽  
Molecular Fluids ◽  
Detection Techniques ◽  
Gas Phases ◽  
Line Shapes ◽  
Band Position

Isotropic Raman line shapes of simple molecular fluids exhibit critical line broadening near their respective liquid-gas critical points. In order to observe this phenomenon, it is essential that the band position of a given vibrational mode is density-dependent, and that vibrational depopulation processes negligibly contribute to line broadening. Special attention was given to the fact that the isotropic (i.e., nonrotationally broadened) line shape of liquid N2 is affected by resonant intermolecular vibrational interactions between identical oscillators. By means of the well-chosen isotopic mixture (14N2).975 - (14N15N).025, the temperature and density dependences of shift, width, and asymmetry of the resonantly coupled 14N2 and, depending on the S/N ratio available, of the resonantly uncoupled 14N15N were determined, with up to milli-Kelvin resolution, in the coexisting liquid and gas phases and along the critical isochore, using a highest-resolution double monochromator and modern charge-coupled device detection techniques. Clear evidence was found that vibrational resonance couplings are present in all dense phases studied.

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